• Title/Summary/Keyword: Iron compound

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Studies on Antioxidative Activity of Green Tea Extracts in Medilite-Extraction Water (Medilite 침출수에 의한 녹차 추출물의 항산화 활성연구)

  • 차재영;조영수
    • Journal of Life Science
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    • v.13 no.2
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    • pp.168-174
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    • 2003
  • The chemical compositions and antioxidant activity of green tea extracts in medilite-extraction water were compared to that of distilled water(DW). Antioxidant activity was fetermined by the formation of thiobarbituric acid reactive substances (TBARS) in rat liver homogenates and microsomes and the scavenging activity of free radicals by DPPH ($\alpha$, $\alpha$'-diphenyl-$\beta$-picrylhydrazyl). The order of total polyphenolic compounds and extracted yield by extracts was medilite 325 mesh-extraction water, medilite 600 mesh-extraction water and distilled water(DW). The ranges of scavenging activity of green tea extracts in DPPH method were 60.95% - 64.51%. The inhibition ratios of TBARS formation in the rat liver homogenates and microsomal fractions were significantly lower with green tea extracts by DW-extraction than with both medilite 325 mesh and 600 mesh-extraction water. The concentration of iron ion of water containing medilite 325 mesh and green tea extracts and of water containing medilite 600 mesh and green tea extracts were significantly higher compared to DW. Therefore, this result suggested that enhanced concentration of iron ion in green tea extracts by medilite-extraction water containing high iron ion content was associated with enhanced peroxidation of the rat liver microsomal fractions. These results showed that total polyphenolic compounds, the % of yield and mineral compounds of green tea extracts were increased using medilite 325 mesh and 600 mesh-extraction water.

Cellular-protective effects of Nardotidis seu Sulculii Concha Extract against oxidative stress (산화적 스트레스에 대한 석결명의 세포 보호 효과)

  • Kim, Kwang Yeon;Lee, Seung Jin;Jee, Seon Young;Bae, Su Jin;Song, Yu Rim;Yun, Un-Jung;Bak, Seonbeen;Song, Jong Kuk;Son, Tae Jin;Son, Jae-Dong;Kim, Woo Hyun;Yang, Ju Hye;Park, Sun Dong;Kim, Sang Chan;Kim, Young Woo;Park, Kwang-Il
    • Herbal Formula Science
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    • v.29 no.2
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    • pp.71-80
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    • 2021
  • Objectives : This study investigated cellular-protective effects of Nardotidis seu Sulculii Concha water extract (NSCE) against oxidative stress induced by arachidonic acid (AA)+iron or tert-butylhydroperoxide (tBHP). Methods : In vitro, MTT assay was assessed for cell viability, and immunoblotting analysis was performed to detect expression of AMP-activated kinase (AMPK) signaling pathway and autophagy related proteins. In vivo, mice were orally administrated with the aqueous extract of NSCE of 500 mg/kg for 3 days, and then injected with CCl4 0.5 mg/kg body weight to induce acute damage. The level of liver damage was measured by serum aspartate aminotransferase (AST), alanine aminotransferase (ALT) and lactate dehydrogenase (LDH) analysis. Results : Treatment with NSCE inhibited cell death induced by AA+iron and tBHP. NSCE induced the phosphorylation of AMPK, and this compound also induced the phosphorylation of LKB1, an upstream kinase of AMPK, and Acetyl-CoA carboxylase (ACC), a primary downstream target of AMPK. NSCE increased the protein levels of autophagic markers (LC3II and beclin-1) and decreased the phosphorylation of mammalian target of rapamycin (mTOR) and simultaneously increased the phosphorylation of unc-51-like kinase-1 (ULK-1) in time-dependent manner. Conclusions : NSCE has the ability 1) to protect cells against oxidative stress induced by AA+iron or tBHP. NSCE 2) to activate AMP-activated protein kinase (AMPK), and 3) to regulate autophagy, an important regulator in cell survival.

Study in the Mechanisms of Formation of Transfer Film under the Condition of Wear of Steel AISI1020 by Natural Rubber

  • Wang, De-Guo;Zhang, Si-Wei;He, Ren-Yang;Li, Ming-Yuan
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.223-224
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    • 2002
  • The mechanisms of formation of transfer film under the condition of wear of Steel AISI1020 by natural rubber were investigated. The transfer film was observed and the formation mechanisms were clarified. The formation process of transfer film on the worn surface of the steel could be divided into two stages. Firstly, the adhesive layer emerged on the worn surface of the steel by adhesion of natural rubber. in which the macromolecular chains of natural rubber joined to the surface of the steel by Van der Waals' force. And then, the iron atom and metal oxide reacted with the macromolecular of natural rubber in the adhesive layer and produced Fe-polymer compound. As a result, the transfer film was formed on the worn surface of the steel. The transfer film was joined to the worn surface of the steel by the chemical bonds and electrostatic force.

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Treatment of Photographic Wastewater by Chemical Oxidation and Biological Treatment process (화학적산화 및 생물학적처리법에 의한 사진폐액의 처리)

  • 정경훈;최형일
    • Journal of Environmental Health Sciences
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    • v.23 no.1
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    • pp.34-42
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    • 1997
  • A laboratory experiments were performed to investigate the treatment of photographic processing wastewater by chemical oxidation and biological treatment system. The effect of reaction conditions such as hydrogen peroxide dosage, ferrous sulfate dosage and pH on the COD removal in Fenton oxidation were investigated. The optimal dosage of hydrogen peroxide was 2.58 M and 3.87 M for the developing and fixing process wastewater, respectively. The Fenton oxidation was most efficient in the pH range of 3-5 and the optimal condition for initial reaction pH was 5 for a developing process wastewater. With iron powder catalyst, the COD for a developing process wastewater was removed in lower pH than with ferrous sulfate catalyst. The removal efficiency of COD for refractory compounds such as Diethyleneglycol, Benzylalcohol, Hydroxylamine Sulfate, Ammonium Thiosulfate, Ammonium Ferric EDTA and Disodium EDTA in the photogaphic wastewater was found than 90% except Potassium Carbonate. When the photographic processing wastewater after pretreatment by Fenton oxidation was treated with batch activated sludge process, the addition of $KH_2PO_4$ as a phosphorous compound improved the removal efficiency of COD. During the continuous biological treatment of developing and fixing process wastewater after pretreatment by Fenton oxidation, the effluent COD concentration less than 100 mg/l was obtained at 0.425 and 0.25 kgCOD/m$^3$.d, respectively.

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Degradation of oxytetracycline by nano zero valent iron under UV-A irradiation: Chemical mechanism and kinetic

  • Hassanzadeh, Parisa;Ganjidoust, Hossein;Ayati, Bita
    • Advances in environmental research
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    • v.3 no.1
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    • pp.29-43
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    • 2014
  • Pharmaceutical wastewater effluents are well known for their difficult elimination by traditional biotreatment methods and their important contribution to environmental pollution due to its fluctuating and recalcitrant nature. OTC is one of the nonbiodegradable antibiotics that makes antibiotic-resistant, so it can make be high risk for environment. NZVI can be a good choice for removal of OTC in aqueous solution. Response surface methodology (RSM) was used to optimize the amounts of NZVI and OTC to be used at pH 3 and under 200 W, UV-A irradiation. The responses were removal percent of absorption at 290 and 348 nm, TOC and COD of OTC. In the optimum condition, Linear model was performed 155 ppm of OTC were removed by 1000 ppm NZVI after 6.5 hours and the removal efficiency of absorption at 290 and 348 nm, TOC and COD were 87, 95, 85 and 89 percent, respectively. In the similar process, there is no organic compound after 14 hours. The parameters ORP, DO and pH were investigated for 6:30 hours to study the type of NZVI reaction in process. In the beginning of reaction, oxidation was the dominant reaction after 3 hours, photocatalytic reaction was remarkable. The mechanism of OTC degradation is proposed by HPLC/ESI-MS and four by products were found. Also the rate constants (first order kinetic chain reaction model) were 0.0099, 0.0021, 0.0010, 0.0049 and $0.0074min^{-1}$, respectively.

Nutrition Survey of Children Attending an Elementary School with a School Lunch Program in Socioeconomically High Apartment Compound of Seoul (서울지역 고소득 아파트단지내 급식 국민학교 아동의 영양실태조사)

  • 유덕인;이윤나;김원경;이수경;정상진;최경숙;권순자;이은화;모수미
    • Journal of Nutrition and Health
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    • v.25 no.1
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    • pp.56-74
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    • 1992
  • To evaluate the nutritional status of the children in socioeconomically high apartment com-pound a nutritional survey of 276 children in the YunJung elementary school was undertaken in July of 1990. Yunjung elementary school is situated in Youido-dong Youngdeungpo-ku of Seoul and offers school lunch program The results were as follows : Anthropometric data of subjects showed higher results than the Korean standards : 11.0% of subjects were proven to be overweight and 21.6% belonged to obese group. Mean urinary the RDA's except for intake of was 10.2$\pm$3.7 Total daily energy and nutrient intake exceeded the RDA's except for intake of iron. Carbohydrate provided 57% of total energy intake; protein accounted to for 17 ; fat provided 27% The between meals provided 27.4% of total energy intake. The survey clarified that school lunch largely contributed to the nutritional balance of these children. Family environment and anthropometric data were positively correlated with nutrient intake. The survey emphasizes the urgent need to improve the nutrition education of these children.

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Electronic Structure Studies on $Ba(Fe_{1-x}Ru_x)_2As_2$ by Photoemission (광전자 분석 실험을 이용한 $Ba(Fe_{1-x}Ru_x)_2As_2$ 물질의 전자구조분석)

  • Jung, W.S.;Kim, Y.K.;Kim, B.Y.;Matsunami, M.;Kimura, S.;Eom, M.J.;Kim, J.S.;Kim, C.
    • Progress in Superconductivity
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    • v.12 no.2
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    • pp.99-103
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    • 2011
  • We performed angle resolved photoelectron spectroscopy (ARPES) studies on Ru doped $BaFe_2As_2$ with various Ru contents. Ru, which is doped into a parent compound $BaFe_2As_2$ and substitute Fe, does not donate or accept electrons. However, it induces superconductivity. From ARPES data along the high symmetry cuts and Fermi surface maps, we investigate the electron correlation and carrier density at the Fermi level. We observe that the Fermi velocity increases with Ru doping, suggesting reduction in electron correlation. In addition, we address issues on local vs. itinerant pictures for the magnetism in $BaFe_2As_2$.

High alloyed new stainless steel shielding material for gamma and fast neutron radiation

  • Aygun, Bunyamin
    • Nuclear Engineering and Technology
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    • v.52 no.3
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    • pp.647-653
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    • 2020
  • Stainless steel is used commonly in nuclear applications for shielding radiation, so in this study, three different types of new stainless steel samples were designed and developed. New stainless steel compound ratios were determined by using Monte Carlo Simulation program Geant 4 code. In the sample production, iron (Fe), nickel (Ni), chromium (Cr), silicium (Si), sulphur (S), carbon (C), molybdenum (Mo), manganese (Mn), wolfram (W), rhenium (Re), titanium (Ti) and vanadium (V), powder materials were used with powder metallurgy method. Total macroscopic cross sections, mean free path and transmission number were calculated for the fast neutron radiation shielding by using (Geant 4) code. In addition to neutron shielding, the gamma absorption parameters such as mass attenuation coefficients (MACs) and half value layer (HVL) were calculated using Win-XCOM software. Sulfuric acid abrasion and compressive strength tests were carried out and all samples showed good resistance to acid wear and pressure force. The neutron equivalent dose was measured using an average 4.5 MeV energy fast neutron source. Results were compared to 316LN type stainless steel, which commonly used in shielding radiation. New stainless steel samples were found to absorb neutron better than 316LN stainless steel at both low and high temperatures.

The Effect of Sursulf Treating Time and Traveling Speed during Induction Hardening on Hardness and Wear Characteristics of Low Carbon Steel Combined-Heat-Treated (Sursulf 처리후 고주파 표면경화된 저탄소강의 경도 및 마모특성에 미치는 Sursulf 처리시간 및 고주파 경화 이송속도의 영향)

  • No, Y.S.;Kim, Y.H.;Lee, P.H.;Shin, H.K.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.2 no.2
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    • pp.17-26
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    • 1989
  • This study has been performed to investigate into some effects of the Sursulf treatment time and the traveling speed of surface hardening treatment on the hardness and the wear characteristics by applying the combined heat treating techniques of Sursulf process followed by induction hardening treatment to mild steel. It has been shown that increasing the Sursulf treatment time increases the case depth, but both hardness and wear resistance are not considerably improved. When the combined heat treating technique of high frequency induction heating after Sursulf treatment is applied, an improvement in case depth as well as wear resistance is obtained. In particular, the hardness in diffusion zone is greatly increased due mainly to the formation of martensite and possibly lower bainite. Iron oxides formed during induction heating and subsequent water spray cooling in the outermost part of compound layer may be considered to cause some increases in hardness and wear resistance.

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Fabrication details of Ba1-xKxFe2As2 films by pulsed laser deposition technique

  • Lee, Nam Hoon;Jung, Soon-Gil;Ranot, Mahipal;Kang, Won Nam
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.3
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    • pp.4-6
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    • 2014
  • Among Fe-based superconductors, potassium doped $BaFe_2As_2$ is favorable for applications because of its relatively high transition temperature and low anisotropy. To study the superconducting properties and the applicable aspects, high quality thin films of potassium doped $BaFe_2As_2$ should be fabricate. However, the high volatility of potassium makes it difficult to fabricate thin films of this compound. In this paper, we discuss the details of the experimental conditions used to fabricate $Ba_{1-x}K_xFe_2As_2$ films by ex situ PLD method. In the first set of samples, barium ratio in the target was controlled to make films with various potassium doping rate. However, in the second set of samples, the amount of potassium was controlled to find out optimal conditions for making high quality $Ba_{1-x}K_xFe_2As_2$ films.