• Title/Summary/Keyword: Iron(III)

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High Efficient Metal-oxide Removing Characteristics as Pulse Repetition Rates in the Atmospheric Arc Discharge (펄스반복율의 가변에 의한 대기압 아크방전중의 고효율 금속산화물 제거 특성)

  • 이윤수;송우정;김수원;정종한;김용철;김희제
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.4
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    • pp.179-184
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    • 2003
  • The pulsed power system is widely used for many industries and environments. Generally, we call the "RUST", the reddish brown surface, that was made on iron surface or some other metals, when they are contacted by water and air the main substance of rust is oxide-ionization. In other words, the chemical symbol of rust on iron surface is iron oxide(III) hydrate Fe203.nH2O. In this study, we have designed and fabricated our system which has a compact pulse generator with switching MOSFET. Also we have studied the metal-oxide removing characteristics using in the atmospheric arc discharge. It has been investigated their removing characteristics by the change of charging voltage and pulse repetition rates. From this result, we can find out that the removal area Is increased from 3.80 to 8.04[$\textrm{cm}^2$], when pulse duration is increased from 100[pps] to 400[pps]. 400[pps].

A Basic Study on the Removal of Iron Ion in Waste Water by the Precipitation Method (침전법에 의한 폐수중의 철이온 제거에 관한 기초 연구)

  • 강동현;김형석;조동성
    • Resources Recycling
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    • v.2 no.2
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    • pp.16-21
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    • 1993
  • This study was carried out to investigate the settling characteristics of Fe(II) and Fe(III) hydroxide precipitates formed by pH adjustment of aqueous solution to remove ferrous and ferric ion in waste water. The results obstained in this study are as fellows : The settling rate was effectively increased with increasing the pH values of aqueous solution regulated by CaO and with increasing the amount of flocculant, on the other hand, application of excess flocculants decreased the settling rate. It is desirable that the concentration of iron ion is kept under $10^{-2}$ mol/ㅣ because the settling rate was decreased with increasing the concentration of iron hydroxide precipitates.

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Effects of Sulfate Ion the Gas Sensing Characteristic of the $\alpha$-Fe$_2$O$_3$ ($\alpha$-Fe$_2$O$_3$의 가스감지특성에 미치는 황산이온의 영향)

  • 양천희
    • Journal of the Korean Society of Safety
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    • v.4 no.1
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    • pp.71-74
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    • 1989
  • The $\alpha$-Fe$_2$O$_3$ gas sensor, prepared by the precipitation of Fe(OH)$_3$ from a solution of iron(III) sulfate and tin (IV) chloride, was composed of fine particles and was superior in sensitivity to other $\alpha$-Fe$_2$O$_3$. The gas sensitivity was found to depend on the amounts of remaining sulfate ion the microstructure and a small amount of iron(II) species generated through the reduction of $\alpha$-Fe$_2$O$_3$. The sensing mechanism of $\alpha$-Fe$_2$O$_3$gas sensor was confirmed to be due to the reduction of $\alpha$-Fe$_2$O$_3$ to the low resistive Fe$_3$-xO$_4$ by combustible gas and to depend on the crystral structure.

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The Change of Paleoenvironment during the Late Holocene in the Neungsan-ri Alluvial Plain, Buyeo-gun, Chungnam-Province, Korea (충남 부여 능산리 충적평야의 홀로세 후기 고환경 변화)

  • Yoon, Soon-Ock;Kim, Yae-sun;Hwang, Sangill
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.3
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    • pp.1-11
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    • 2016
  • This study estimated vegetation environment and agricultural activity during the late Holocene inferred from pollen analysis of peat on floodplain of Wangpo-cheon around Neungsan-ri, Buyeo-gun, South Korea. By result of pollen analysis of 28 horizons from Trench NS 1 and NS 4, vegetation environment during 2,300 to 1,700 yr BP was divided into Pollen Zone I (Quercus-Alnus), Pollen Zone II (Quercus-Alnus-Gramineae) and Pollen Zone III (Pinus-NAP-Gramineae). The pollen analysis suggests that agricultural activity in the Buyeo area was widely spread from the early time of the Pre-Iron Age to the late Samhan Age and buckwheat field seem to be built to substitute paddy field during the early time of the Pre-Iron Age.

Qualitative comparison of chemical and green synthesized Fe3O4 nanoparticles

  • Gokila, V.;Perarasu, V.T.;Rufina, R. Delma Jones
    • Advances in nano research
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    • v.10 no.1
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    • pp.71-76
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    • 2021
  • Synthesis of nanoparticles using green technology using plants is gaining significant attention as it is an environmentally friendly substitute to conventional physical and chemical methods. The present study was focused on the chemical and green synthesis of Iron Oxide nanoparticles from ferric chloride. The green synthesis was achieved by utilizing the bio components of Hibiscus rosa-sinensis. The Fe3O4 nanoparticles with the size range of 87-400 nm were synthesized by wet chemical reduction technique which are unstable, prone to aggregation while in green synthesis the phytochemicals present in the leaf extract acts as the capping as well as the reducing agent thus the green synthesized iron (III) oxide nanoparticles were naturally stabilized, spherical shaped and are in the size range of 2-80 nm. The results of both the protocols are compared and presented briefly.

A Study on the Synthesis of Tricyclopentadiene Using Ionic Liquid Catalysts (이온성 액체 촉매를 이용한 Tricyclopentadiene 합성에 관한 연구)

  • Kim, Su-Jung;Han, Jeongsik;Jeon, Jong-Ki;Yim, Jin-Heong
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.593-597
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    • 2015
  • Tricyclopentadiene (TCPD) as a next generation high density fuel was synthesized by Diels-Alder oligomerization reaction of DCPD. TCPD was prepared by ionic liquid (IL) catalysts with combination of cationic and anionic precursors. Two kinds of anionic precursors such as copper(I) chloride (CuCl) and iron(III) chloride ($FeCl_3$) and cationic precursors such as triethylamine hydrochloride (TEAC) and 1-butyl-3-methylimidazolium chloride (BMIC) were used. The preparation of TCPD using IL catalyst was superior to that using Diels-Alder reaction in terms of DCPD conversion and TCPD yield. In addition, TCPD yield was correlated with Lewis acidity by changing the ratio of anionic and cationic precursors. The TCPD yield was higher when using CuCl as anionic precursor than that of using $FeCl_3$. Control of Lewis acidity by changing the molar ratio of anionic and cationic precursors could further improve TCPD yield as well.

Identification of Anaerobic Thermophilic Thermococcus Dominant in Enrichment Cultures from a Hydrothermal Vent Sediment of Tofua Arc (Tofua Arc의 열수구환경으로부터 호열성 혐기성 고세균(Thermococcus)의 농화배양 및 동정)

  • Cha, In-Tae;Kim, So-Jeong;Kim, Jong-Geol;Park, Soo-Je;Jung, Man-Young;Ju, Se-Jong;Kwon, Kae-Kyoung;Rhee, Sung-Keun
    • Korean Journal of Microbiology
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    • v.48 no.1
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    • pp.42-47
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    • 2012
  • Hydrothermal vents (HTV) provide special environments for evolution of lives independent on solar energy. HTV samples were gained from Tofua arc trench in Tonga, South Pacific. We investigated archaeal diversity enriched using combinations of various electron donors (yeast extract and $H_2$) and electron acceptors [Iron (III), elemental sulfur ($S^0$) and nitrate. PCR amplification was performed to detect archaeal 16S rRNA genes after the cultures were incubated $65^{\circ}C$ and $80^{\circ}C$ for 2 weeks. The cultures showing archaeal growth were transferred using the dilution-to-extinction method. 16S rRNA gene PCR-Denaturing Gradient Gel Electrophoresis was used to identify the enriched archaea in the highest dilutions where archaeal growth was observed. Most of cultured archaea belonged to genus of Thermococcus (T. alcaliphilius, T. litoralis, T. celer, T. barossii, T. thoreducens, T. coalescens) with 98-99% 16S rRNA gene similarities. Interestingly, archaeal growth was observed in the cultures with Iron (III) and nitrate as an electron acceptor. It was supposed that archaea might use the elemental sulfur generated from oxidation of the reducing agent, sulfide. To cultivate diverse archaea excluding Thermococcus, it would be required to use other reducing agents instead of sulfide.

Effect of the Physicochemical Properties of Soil on the Arsenic Bioaccessibility (비소용출에 대한 토양의 물리화학적 특성 영향)

  • Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.7
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    • pp.731-737
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    • 2006
  • Four well-characterized soils collected from A- and B-horizon in the Department of Energy Oak Ridge Reservation in USA, mainly distributed with Inceptisol(Inc) and Ultisol(Ult) soils, were used in this work. The bioaccessibility of arsenic as well as oxidation phenomena of As(III) was investigated with soils spiked with As(III) and As(V) using a physiologically based extraction test(PBET) at pH 1.5 and 1:100 soil to solution ratio. Also effect of aging time on the bioaccessibility of arsenic was investigated over the 6 months. After 48 hours(fresh) contacting As(V) solution with soils, all soils rapidly and strongly sequestrated As(V), especially Ult-B. However, little sequestration was observed after 3-months. When As(III) was spiked on the same soils, a great portion of As(III) was oxidized to As(V) after 48 hrs, especially Inc-A and Ult-A soils, which is strongly related with Mn content in soils. By using As(III)-spiked soils, much reduced bioaccessibility as total arsenic was observed from Inc-B and Ult-B soils over the 6 months aging time compared to that from Inc-A and Ult-A soils. This result can be explained by the continuous sequestration of As(V), produced from oxidation of As(III), onto Inc-B and Ult-B soils having much amount of iron. The trend of As(III) sequestration over six months aging time was quite similar with that of As(V) sequestration.

Structural Relaxation of Semiconducting Vanadate and IR-Transmitting Gallate Glasses Containing Iron

  • Nishida, Tetsuaki
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.9-14
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    • 2000
  • Glass transition temperature (T/sub g/) is proportional to the quadrupole splitting(Δ) of Fe(III) obtained from the /sup 57/Fe Mossbauer spectra (T/sub g/-Δ rule (1990)). The values of Δ reflect the distortion of Fe(III) atoms, which occupy the sites of network-forming atoms. Heat treatment of potassium vanadate and calcium gallate glasses at around the individual T/sub g/ causes a structural relaxation, accompanying a linear decrease of T/sub g/ and Δ values. These experimental results prove that T/sub g/ decreases with a decrease in the distortion of VO₄, GaO₄, and FeO₄tetrahedra, as the T/sub g/-Δ rule predicted.

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A Study on a different Substance Detection system of Conveyer Belt by AE Sensor(III) -Development of Intelligent Conveyer Belt Defect Detection system- (AE센서를 이용한 콘베이어 벨트 이물질 감지 장치에 관한 연구(III) -지능형 콘베이어 벨트 손상 검출 시스템 개발-)

  • 정양희;김이곤;배영철;김경민;유일현;이보희;강성준
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.4 no.4
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    • pp.803-808
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    • 2000
  • This paper presents development of a different substance monitoring system base reliable detection between the conveyer belt and hopper used for materials transport line of steel company. Conventional detection method of a piece of iron separation system is losed the confidence, because of the place with bad surroundings of measurement so much that materials production line are completely exposed to dust, moisture and vibration. For the solution of this problem, we developed a different substance detection system using the acoustic emittion sensor and one chip microprocessor which is available for bad surroundings and inexpensive. The reliability of the system was estimated by experiment.

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