• Title/Summary/Keyword: Iridium

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Red Electrophosphorescent Organic Light-emitting Diodes Based on New Iridium Complexes. (새로운 이리듐 화합물을 이용한 적색 인광 유기 발광 다이오드)

  • Gong, Doo-Won;Kim, Jun-Ho;Lee, Kum-Hee;Yoon, Seung-Soo;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.73-74
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    • 2006
  • New iridium complexes that have carbonyl group were synthesized and demonstrated various red light emission in organic light-emitting diodes (OLEDs). The maximum luminance of $57000{\sim}15300\;cd/m^2$ at 15 V and the luminance efficiency of 22.8~5.6 cd/A at $20\;mA/cm^2$ were achieved respectively. The peak wavelength of the electroluminescence were at 570~604 nm and the device also showed a stable color chromaticity with various voltages.

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Synthesis and Characterization of properties for Iridium Complexes (Ir 착체의 합성과 특성에 관한 연구)

  • Kim, Dong-Hwan;Kim, Hwa-Seon;Kwak, Ji-Hoon;Lee, Ji-Hoon;An, Ho-Guen;Chung, Min-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.437-438
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    • 2007
  • A Iridium complexes has been synthesised from the reaction of [$lr(ppy)_2Cl_2$] with 5-bromo-2.2'-bipyridine, 5-Ethynyl-2.2'-bipyridine Characterization of the complexes were by FT-IR, $^1H(^{13}C)$-NMR and photo-, electro-chemistry properties were showed by UV-vis, Cyclicvoltammetry, Photoluminescence.

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Origin of Spherule Samples Recovered from Antarctic Ice Sheet-Terrestrial or Extraterrestrial?

  • Sekimoto, Shun;Kobayashi, Takayuki;Takamiya, Koichi;Ebihara, Mitsuru;Shibata, Seiichi
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.293-298
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    • 2016
  • Thirty-eight spherules from the Antarctic ice sheet were analyzed using neutron activation analysis under two different conditions to investigate their origin. In almost all of these spherules, the contents of iron, cobalt, and manganese were determined to be 31% to 88%, 17 mg/kg to 810 mg/kg, and 0.017% to 7%, respectively. A detectable iridium content of 0.84 mg/kg was found in only one spherule, which was judged to be extraterrestrial in origin. A comparison of elemental compositions of the Antarctic spherules analyzed in this study with those of deep-sea sediment spherules and those of terrestrial materials revealed that most of the Antarctic spherules except for the sample in which iridium was detected could not be identified as extraterrestrial in origin.

STIMULATING NEURAL ELECTRODE-A STUDY ON CHARGE INJECTION PROPERTIES OF IRIDIUM OXIDE FILMS

  • Lee, In-Seop;Ray A. Buchanan;Jim M.Williams
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.156-162
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    • 1995
  • For a stimulating neural electrode, the charge density should be as large as possible to provide adequate stimulation of the nervous system while allowing for miniaturization of the electrode. Since iridium oxide is able to produce high charge densities while preventing undesirable reactions due to charge storage, it has become a promising material for neural prostheses. Successful production of stable Ir and Ir oxide films on various substrates now limits the use of this material. Ir was deposited on two differently prepared surface of (mirror finish, passivation) surgical Ti-6AI-4V with several methods. Ion beam mixing of sputter deposited Ir films on passivated Ti-6AI-4V produced stable and good adherent Ir films. It was found that the increase in charge density of pure Ir on continuous cyclingis due to the accumulation of the oxide phase ( associated with a large surface area) in which the valence state of iridium changes and the double-layer capacitance increases. This study also showed that the double layer capacitance is equally or even more responsible for the high charge density of anodically formed Ir oxide.

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Graphene Reconfigurable Antenna for GPS and Iridium Applications

  • Salem GAHGOUH;Ali GHARSALLAH
    • International Journal of Computer Science & Network Security
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    • v.23 no.3
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    • pp.203-207
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    • 2023
  • A frequency reconfigurable antenna based on graphene and used for multi-band wireless communications is presented in this article. The proposed antenna, which consists of two radiating rectangular loops with a graphene extension, is analyzed for Global Positioning System (GPS) and Iridium applications. Its operating frequency is tuned through the implementation of a layer of graphene and thereby adjusting the applied gate bias. Furthermore, the results show a novel use of graphene for microwave frequencies while achieving a frequency reconfiguration with an improvement of the impedance matching and the gain. The results also prove the importance of graphene, with its exceptional properties, for a promising future in nano-electronics.

Study on the Efficient White Organic Light-Emitting Diodes using the Material of Binaphthyl Group (Binaphthyl group 기반의 물질을 이용한 효율적인 White OLED 소자에 대한 연구)

  • Yeo, Hyun-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.459-465
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    • 2012
  • We had synthesized a green dopant material based on the binaphthyl group, 7,7'-(2,2'dimethoxy-1,1'-binaphthyl-3,3'-diyl) bis(4-(thiophen -2-yl) benzo[e][1,2,5] thiadiazole (TBT). We also fabricated the white organic light emitting diode (OLED) with a phosphorescent blue emitter : iridium(III)bis[(4,6-di-fluoropheny)-pyridinato -N,C2]picolinate (FIrpic) doped in N,N'-dicarbazolyl-3,5-benzene (mCP) of hole transport type host material and both TBT and bis(2-phenylquinolinato)- acetylacetonate iridium(III) (Ir(pq)2acac) doped in 1,3,5-tris(N-phenylbenzimidazole -2-yl)benzene (TPBi) of electron transport type host material. As a result, the property of white OLED using TBT, which demonstrated a maximum luminous efficiency and external quantum efficiency of 5.94 cd/A and 3.23 %, respectively. It also showed the pure white emission with Commission Internationale de I'Eclairage (CIE) coordinates of (0.34, 0.36) at 1000 nit.

Tuning Photophysical and Electrochemical Properties of Heteroleptic Cationic Iridium(III) Complexes Containing Substituted 2-Phenylquinoxaline and Biimidazole

  • Sengottuvelan, Nallathambi;Seo, Hoe-Joo;Kang, Sung-Kwon;Kim, Young-Inn
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2309-2314
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    • 2010
  • Design and syntheses of four red phosphorescent heteroleptic cationic iridium(III) complexes containing two substituted phenylquinoxaline (pqx) or benzo[b]thiophen-2-yl-pyridin (btp) main ligands and one 2,2'-biimidazole (H2biim) ancillary ligand are reported: [$(pqx)_2$Ir(biim)]Cl (1), [$(dmpqx)_2$Ir(biim)]Cl (2), [$(dfpqx)_2$Ir(biim)]Cl (3), [$(btp)_2$Ir(biim)]Cl (4). Complex 1 showed a distorted octahedral geometry around the iridium(III) metal ion with cis metallated carbons and trans nitrogen atoms. The absorption, emission and electrochemical properties were systematically evaluated. The complexes exhibited red phosphorescence in the spectral range of 580 to 620 nm with high quantum efficiencies of 0.58 - 0.78 in both solution and solid-state at room temperature depending on the cyclometalated main ligands. The cyclic voltammetry of the complexes (1-3) showed a metal-centered irreversible oxidation in the range of 1.40 to 1.90 V as well as two quasi reversible reduction waves from -1.15 to -1.45 V attributed to the sequential addition of two electrons to the more electron accepting heterocyclic portion of two distinctive cyclometalated main ligands, whereas complex 4 showed a reversible oxidation potential at 1.24 V and irreversible reduction waves at -1.80 V.