• Title/Summary/Keyword: Iridium

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Electrical Characteristics of Green Emitting Phosphor $Ir(PPY)_3$ Doped OLEDs

  • Kim, Jun-Ho;Kim, Yun-Myung;Ha, Yun-Kyung;Kim, Young-Kwan;Kim, Jung-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.53-57
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    • 2001
  • The organic light-emitting devices (OLEDs) based on fluorescence have low efficiency due to the requirement of spin-symmetry conservation. By using the phosphorescent material, internal quantum efficiency can reach 100%, compared with 25% in the case of the fluorescent material. Thus, phosphorescent OLEDs have recently been extensively studied and shown higher internal quantum efficiency than the conventional OLEDs. In this study, we investigated the characteristics of the phosphorescent OLEDs with the green emitting phosphor, $Ir(ppy)_3$ (tris(2-phenylpyridine)iridium). The device with a structure of ITO/TPD$Ir(ppy)_3$ doped in BCP/BCP/$Alq_3$/Li:Al/Al was fabricated, and its electrical and optical characteristics were studied. By changing the doping concentration of $Ir(ppy)_3$, we fabricated several devices and investigated their characteristics.

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The Analysis of Interference between the Feeder Links of LEO/MSS and M/W Fixed System (NGSO/MSS 피이더 링크와 M/W 무선국간의 간섭분석)

  • 박영순;강영흥
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 1998.05a
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    • pp.119-125
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    • 1998
  • In recent years there has been a huge increase in demand for new various communication services due to the rapid advances in wireless communication. These new emerging services give rise to the interference with the existed radio system. As the new representative systems NGSO/MSS systems have been developed, using NGSO, especially Low Earth Orbit (LEO), satellites such as Iridium, Globalstar systems to provide the rapid transfer of information and the positioning services for the moving persons whenever they want to communicate, even if wherever they are. In this paper we have analysed on the interference between the feeder link of NGSO/MSS and M/W fixed system, that is the interference from the mobile satellite earth station into M/W station, as well as the interference from M/W station into the mobile satellite earth station, and the coordinated area.

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Re-Ir Coating Effect of WC Core Surface for Aspheric Glass Lens Molding (비구면 Glass 렌즈 성형용 초경합금 코어면 Re-Ir 코팅 효과)

  • Kim, Hyun-Uk;Kim, Sang-Suk;Kim, Hye-Jeong;Kim, Jeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.441-441
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    • 2007
  • As Rhenium-Iridium{Re-Ir) coating possesses such features as, high hardness, high elasticity, abrasion resistance and chemical stability, there have been exerted continuous efforts in research works in a variety of fields, and this technology has also been applied widely to industrial areas. In this research, the optimal grinding condition was identified using Microlens Process Machine in order to contribute to the development of aspheric glass lens for mobile phone module having 3 mega pixel and 2.5X zoom, and molding core(WC) was manufactured having performed ultra-precision machining. Effects of Re-Ir coating on form accuracy (P-V) of molding core and surface roughness(Ra) were measured and evaluated.

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Electrical and Optical Properties of Partially Doped Blue Phosphorescent OLEOs (부분 도핑을 이용한 청색 인광 OLEDs의 전기 및 광학적 특성)

  • Seo, Yu-Seok;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.512-515
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    • 2009
  • We have fabricated blue phosphorescent organic light emitting diodes (PHOLEDs) using a 3,5'-N,N'-dicarbazole-benzene (mCP) host and iridium (III) bis[(4,6-difluorophenyl)-pyridinato-N,$C^{2'}$] picolinate (Flrpic) guest materials, The Flrpic was partially doped into the mCP host layer, for investigating recombination zone, current efficiency, and emission characteristics of the blue PHOLEDs. The recombination of electrons and holes takes place inside the mCP layer adjacent to the mCP/hole blocking layer interface. The best current efficiency was obtained in a device with an emission layer structure of mCP (10 nm)/mCP:Flrpic (20 nm, 10%). The high current efficiency in this device was attributed to the confinement of Ffrpic triplet excitons by the undoped mCP layer with high triplet energy, which blocks diffusion of Ffrpic excitons to the adjacent hole transport layer with a lower triplet energy.

Analysis of the International Conferences on Maritime Radiocommuications and Countermeasures (해상통신분야 국제회의 동향 및 대응방안 분석)

  • Kim, Byung-Ok;Han, Jin-Wook
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2019.05a
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    • pp.89-91
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    • 2019
  • 1998년 도입된 GMDSS 제도의 현대화를 위한 프로젝트가 2012년부터 IMO 주관으로 추진되고 있다. 이와 관련하여 ITU에서는 2016년부터 전파규칙 개정을 위한 논의가 시작되었으며, 올해 11월에 최종 개정안이 확정될 예정이다. NAVDAT 및 VDES 같은 신규 무선설비들의 도입이 검토되고 있으며, Iridium 위성 시스템이 GMDSS 추가 위성시스템으로 승인되어 관련 후속조치가 논의되고 있다. 본 논문에서는 최근 해상통신분야의 국제회의 동향을 분석하고 이에 따른 우리나라의 대응방안을 제시하였다.

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Homogeneous Catalysis (VI). Hydride Route with Chloro Ligand Dissociation for the Hydrogenation of Acrylonitrile with trans-Chlorocarbonylbis(triphenylphosphine)iridium(I)

  • Moon, Chi-Jang;Chin, Chong-Shik
    • Bulletin of the Korean Chemical Society
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    • v.4 no.4
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    • pp.180-183
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    • 1983
  • The reaction of $IrClH_2(CO)(Ph_3P)_2$ ($Ph_3P$=triphenylphosphine) with acrylonitrile (AN) produces a stoichiometric amount of propionitrile (PN) at $100^{\circ}C$ under nitrogen, which suggests that the catalytic hydrogenation of AN to PN with $IrCl(CO)(Ph_3P)_2$ proceeds through the hydride route where the formation of the dihydrido complex, $IrClH_2(CO)(Ph_3P)_2$ is the initial step. The rate of the hydrogenation of AN to PN with $IrCl(CO)(Ph_3P)_2$ is decreased by the presence of excess $Cl^-$ in the reaction system, which suggests that $Cl^-$ is the dissociating ligand in the catalytic cycle. It has been also found that the rate of the hydrogenation increases with inercase both in hydrogen pressure and in concentration of free $Ph_3P$, and with decrease in AN concentration in the reaction system.

Development Status of Iridium Catalyst for Hydrazine Decomposition

  • Kim, S.K.;Lee, K.H.;Yu, M.J.;Cho, S.J.;Lee, J.W.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.272-274
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    • 2008
  • A development of hydrazine decomposition catalyst for monopropellant thruster has been performed by Korea Aerospace Research Institute(KARI). The goal of this development is to product a catalyst showing the equivalent performance with space-proven catalysts. Catalyst production and physical/chemical analysis were conducted by Chonnam National University and the analysis result was compared with the result of other catalysts and our own specification. Using the developed prototype catalyst, short firing test was performed in a reactor to verify basic performance of catalyst. After the successful reactor test, hot firing tests were carried out in atmospheric and vacuum condition using 5N thruster to verify durability and safety of catalyst. In this paper, the catalyst development status will be presented.

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Formation CubeSat Constellation, SNIPE mission

  • Lee, Jaejin
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.58.4-59
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    • 2021
  • This presentation introduces Korea's SNIPE (Small scale magNespheric and Ionospheric Plasma Experiment) mission, formation flying CubeSat constellation. Observing particles and waves on a single satellite suffers from inherent space-time ambiguity. To observe spatial and temporal variations of the micro-scale plasma structures on the topside ionosphere, four 6U CubeSats (~ 10 kg) will be launched into a polar orbit of the altitude of ~500 km in 2021. The distances of each satellite will be controlled from 10 km to more than 100 km by formation flying algorithm. The SNIPE mission is equipped with identical scientific instruments, solid-state telescope, magnetometer, and Langmuir probe. All the payloads have a high temporal resolution (sampling rates of about 10 Hz). Iridium modules provide an opportunity to upload changes in operational modes when geomagnetic storms occur. SNIPE's observations of the dimensions, occurrence rates, amplitudes, and spatiotemporal evolution of polar cap patches, field-aligned currents (FAC), radiation belt microbursts, and equatorial and mid-latitude plasma blobs and bubbles will determine their significance to the solar wind-magnetosphere-ionosphere interaction and quantify their impact on space weather.

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The Characteristics of Organic Light-emitting Diodes With a New Blue Phosphorescent Material (새로운 청색의 인광 물질을 어용한 유기 발광 소자의 전기적 특성 및 수명에 대한 연구)

  • Kim, Y.K.;Park, J.H.;Seo, J.H.;Seo, J.H.;Han, J.W.;Im, C.;Han, S.H.;Lee, S.H.
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.1
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    • pp.74-78
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    • 2007
  • A new blue phosphorescent material for organic light emitting diodes (OLEDs), Iridium(III)bis[2-(4-fIuoro-3-benzonitrile)-pyridinato-N,C2'] picolinate (Firpic-CN), was synthesized and studied. We compared characteristics of Firpic-CN and Bis(3,5-Difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium III (FIrpic) which has been used for blue dopant materials frequently. The devices structure were indium tin oxide (ITO) (1000 ${\AA}$)/N,N'-diphenyl-N,N'-(2-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB) (500 ${\AA}$)/4,4'-N,N'-dicarbazole-biphyenyl (CBP) : FIrpic and FIrpic-CN (X wt%)/4,7-diphenyl-1,10-phenanthroline (BPhen) (300 ${\AA}$)/lithum quinolate (Liq) (20 ${\AA}$)/Al (1000 ${\AA}$). 15 wt% FIrpic-CN doped device exhibits a luminance of $1450\;cd/m^2$ at 12.4 V, luminous efficiency of 1.31 cd/A at $3.58mA/cm^2$, and Commission Internationale d'Eclairage $(CIE_{x,y})$ coordinates of (0.15, 0.12) at 12 V which shows a very deep blue emission. We also measured lifetime of devices and was presented definite difference between devices of FIrpic and FIrpic-CN. Device with FIrpic-CN as a dopant presented lower longevity due to chemical effect of CN ligand.

Study on solubilization of sewage sludge using electrolysis techniques (전기분해에 의한 하수슬러지 가용 효과 연구)

  • Lee, Ji-Sun;Chang, In-Soung;Lee, Chul-Ku;Joung, Seun-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.2
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    • pp.979-984
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    • 2011
  • Although sludge production has been increased due to the number of the wastewater treatment plants expanded, needs of the techniques for the sludge reduction and disposal has been issued importantly because the sludge dumping to ocean is prohibited from 2012 by the London Dumping Convention. Therefore, the sludge solubilization using electrolysis as an alternative techniques for the sludge disposal was carried out in this study. Iridium coated titanium based insoluble electrodes were used and 20 volt was applied to the electrolysis reactor using DC power supply. Supernatants of the treated sludge was monitored: The soluble COD, TN, TP of it was increased to 151%, 22% and 6% respectively. And the sludge floc size distribution was changed, that is, the flocs ranged from 0.1 to 1.0 ${\mu}m$ were increased. All of these results indicate that the cells were lysed and the internal matters bursted out of the cell after electrolysis. As well as the reduction of the sludge production, the soluble organic matters from the cells could be used as an external carbon sources in the advanced wastewater treatment plants.