• 제목/요약/키워드: Ir-Sb

검색결과 57건 처리시간 0.028초

산화물 전극을 이용한 Rhodamine B의 탈색

  • 박영식;김동석
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2007년도 춘계 학술발표회 발표논문집
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    • pp.370-374
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    • 2007
  • 난분해성 유기물 처리에 적절한 불용성 전극을 선정하고 성능을 평가하기 위하여 1-3 성분계 전극을 이용하여 양이온 염료인 Rhodamine B (RhB)의 전기분해 처리에서 다음의 결론을 얻었다. 1) 반응 2분 후 RhB 농도를 고찰한 결과 RhB 농도감소는 Ru-Sn-Ti/Ti ${\fallingdotseq}$ Ru-Sn-Sb/Ti > Ir-Sn-Sb/Ti > Sn-Sb/Ti > Ru/Ti > Ir/Ti > Pt/Ti의 순서로 나타나 3성분계 > 2성분계 > 1성분계 전극의 순서로 나타났다. Ru를 사용한 전극이 Ir을 사용한 전극보다 1성분계와 3성분계 모두 성능이 우수한 것으로 나타났다. 기존 전극으로 가장 많이 사용되고 있는 Pt 전극의 성능은 가장 떨어지는 것으로 나타났다. 2) RhB 초기 농도감소 속도는 전극 간격이 좁은 것이 유리한 것으로 나타났으나 최종 농도는 비슷하였다. 전극 간격이 좁을수록 전력 면에서 유리한 것으로 나타났다. 면적이 큰 전극이 초기 반응이 빠르고 나타났고 최종농도도 약간 낮은 것으로 나타났으나 차이는 크지 않았다. 면적이 좁은 경우 반응면적이 적지만 전류밀도가 높기 때문에 성능의 차이는 크지 않으나 면적이 적은 전극의 경우 요구 전력량이 높기 때문에 적절한 크기의 전극이 필요한 것으로 사료되었다.

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뇌졸중 환자의 일상생활 및 인지기능 회복에 대한 의·한의 협진 재활치료의 효과 (Effect of East-West Integrative Rehabilitation on Activities of Daily Living and Cognitive Functional Recovery in Stroke Patients: A Retrospective Study)

  • 문소리;금동호
    • 한방재활의학과학회지
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    • 제30권2호
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    • pp.105-123
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    • 2020
  • Objectives This study was conducted to verify the effectiveness of east-west integrative rehabilitation therapy on activity of daily living and cognitive functional recovery in stroke patients by comparing with integrative rehabilitation therapy group and conventional rehabilitation therapy group in a single institution. Methods The medical records of 106 stroke patients hospitalized in Department of Rehabilitation Medicine, Dongguk University Bundang Oriental Hospital from January 1, 2017 to February 28, 2019 were reviewed. After screening and dividing it into conventional rehabilitation (CR) group and integrative rehabilitation (IR) group, Korean version of Modified Barthel Index (K-MBI), functional independence measure (FIM), clinical dementia rating-sum of boxes (CDR-SB) were statistically analyzed. Results IR group showed significant improvement in K-MBI, FIM, and CDR-SB after treatment (p<0.001) and there was a statistically significant difference in K-MBI and CDR-SB score changes than CR group (p<0.05). And chronic patient of IR group showed significant improvement in K-MBI, FIM, and CDR-SB after treatment (p<0.01) and there was a statistically significant difference in CDR-SB score changes than CR group (p<0.05). In particular, the earlier the treatment initiation time, the more the improvement in function and when the treatment started within 2 years from the onset and patients took acupuncture and pulsed electromagnetic therapy, all scales significantly improved (p<0.001). Conclusions IR showed more improvement on activities of daily life and cognitive functional recovery than CR in this study.

Pulsatilla Saponin D: the Antitumor Principle from Pulsatilla koreana

  • Kim, Yong;Bang, Seong-Cheol;Lee, Ji-Hyun;Ahn, Byung-Zun
    • Archives of Pharmacal Research
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    • 제27권9호
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    • pp.915-918
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    • 2004
  • By bioassay-guided separation, an already known saponin, Pulsatilla saponin D was isolated from the root of Pulsatilla koreana Nakai as a antitumor component when evaluated by in vivo antitumor activity as well as in vitro cytotoxic activity test. It showed potent inhibition rate of tumor growth (IR, 82%) at the dose of 6.4 mg/kg on the BDF1 mice bearing LLC cells.

나노-펄스 노출에 따른 질소 첨가한 $Ge_2Sb_2Te_5$ 박막의 결정화 속도 평가 (An evaluation on crystallization speed of N doped $Ge_2Sb_2Te_5$ thin films by nano-pulse illumination)

  • 송기호;백승철;김흥수;이현용
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.134-134
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    • 2009
  • In this work, we report that crystallization speed as well as the electrical and optical properties about the N-doped $Ge_2Sb_2Te_5$ thin films. The 200-nm-thick N-doped $Ge_2Sb_2Te_5$ thin film was deposited on p-type (100) Si and glass substrate by RF reactive sputtering at room temperature. The amorphous-to-crystalline phase transformation of N-doped $Ge_2Sb_2Te_5$ thin films investigated by X-ray diffraction (XRD). Changes in the optical transmittance of as-deposited and annealed films were measured using a UV-VIS-IR spectrophotometer and four-point probe was used to measure the sheet resistance of N-doped $Ge_2Sb_2Te_5$ thin films annealed at different temperature. In addition, the surface morphology and roughness of the films were observed by Atomic Force Microscope (AFM). The crystalline speed of amorphous N-doped $Ge_2Sb_2Te_5$ films were measured by using nano-pulse scanner with 658 nm laser diode (power : 1~17 mW, pulse duration: 10~460 ns). It was found that the crystalline speed of thin films are decreased by adding N and the crystalline temperature is higher. This means that N-dopant in $Ge_2Sb_2Te_5$ thin film plays a role to suppress amorphous-to-crystalline phase transformation.

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비구면렌즈 설계를 위한 칼코게나이드 Ge-Sb-Se계 구조적, 광학적 특성 연구 (Structural and Optical Characteristics of ChalcogenideGe_Sb_Se for Basic Aspheric Lens Design)

  • 고준빈;명태식
    • 한국생산제조학회지
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    • 제23권2호
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    • pp.133-137
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    • 2014
  • The recent development of electro-optic devices and anticorrosion media has made it necessary investigate infrared optical systems with solid-solid interfaces of materials with amorphous characteristics. One of the most promising classes of materials for these purposes seems to be chalcogenide glasses, which are based on the Ge_Sb_Se system, have drawn much attention because of their use in preparing optical lenses and fibers that are transparent in the range of 3-12 um. In this study, a standard melt-quenching technique was used to prepare amorphous Ge_Sb_Sechalcogenideto be used in the design and manufacture of infrared optical products. The results of structural, optical, and surface roughness analyses of high purity Ge_Sb_Sechalcogenide glasses after various annealing processes reported.

비구면렌즈 설계를 위한 칼코게나이드 Ge-Sb-Se 광학계 및 결정화 특성 연구 (Chalcogenide Ge-Sb-Se Optical and Crystallization Characteristics for Basic a Planning Aspheric Lens)

  • 명태식;고준빈
    • 한국재료학회지
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    • 제26권11호
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    • pp.598-603
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    • 2016
  • The recent development of electro-optic devices and anticorrosion media has led to the necessity to investigate infrared optical systems with solid-solid interfaces of materials that often have the characteristic of amorphousness. One of the most promising classes of materials for those purposes seems to be the chalcogenide glasses. Chalcogenide glasses, based on the Ge-Sb-Se system, have drawn a great deal of attention because of their use in preparing optical lenses and transparent fibers in the range of 3~12 um. In this study, amorphous Ge-Sb-Se chalcogenide for application in an infrared optical product design and manufacture was prepared by a standard melt-quenching technique. The results of the structural, optical and surface roughness analysis of high purity Ge-Sb-Se chalcogenide glasses are reported after various annealing processes.

NH3-SCR에서 Sb 첨가에 따른 V/W/TiO2 촉매의 Phosphorous 피독 영향 연구 (The Study on the Effect of Phosphorous Poisoning of V/W/TiO2 Catalyst According to the Addition of Sb in NH3-SCR)

  • 정민기;신중훈;이연진;홍성창
    • 공업화학
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    • 제32권5호
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    • pp.516-523
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    • 2021
  • 본 연구는 대기 중 대표적인 미세먼지 2차 유발물질인 질소산화물 제어에 있어 암모니아를 환원제로 사용하는 선택적 촉매 환원법(Selective Catalytic Reduction; SCR)을 이용한 연구를 수행하였다. NH3-SCR 실험은 상용촉매인 V/W/TiO2와 Sb를 첨가한 V/W-Sb/TiO2 촉매를 사용하였으며 phosphorous에 의한 내피독성을 확인하였다. NH3-SCR 실험 결과, Sb의 첨가는 P에 대한 내구성을 갖는 것으로 확인되었다. 또한 이에 대한 원인을 확인하기 위하여 BET, XPS, H2-TPR, NH3-TPD, FT-IR 분석을 통해 물리·화학적 특성을 비교분석하였다. 분석 결과 V/W/TiO2 촉매에 Sb 첨가 시 P가 첨가됨에 따라 SbPO4 결합을 형성하고 VOPO4의 생성을 억제하였으며, P 첨가 전 촉매의 redox 특성을 유지함으로써 P에 대한 내피독성을 확인하였다.

FT/RAman을 이용한 도공액과 도공지의 도공층 내의 SB Latex 정량분석 (The Quantitative Analysis of SB Latex Contents in Coating Color and Coating Layer of Coated Paper Using FT/Raman Spectroscopy)

  • 이복진;정순기;윤동호;마금자
    • 펄프종이기술
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    • 제31권4호
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    • pp.16-22
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    • 1999
  • The quantitative analysis of SB latex contents in coating color and coated paper was investigated with FT/Raman spectroscopy. From the measured FT/IR and FT/Ramon spectra, the peaks of coating color were compared with those of each compoents . Calibration curves were obtained by the area of latex peaks and PLS method of QuantIR program. The relation of predicted values in PLS method and actual values in coating mixtures and coating layer was examined. The components of coating layer in coated paper were investigated by EDS , X-mapping and SEM, The contents of latex in z-direction were calculated in the coating layer of unknown coated paper. The latex concentration measurements of Top layer and Pre layer in double coated paper show that each layer has different value. In single coated paper, it is clear that the latex concentration is highest at the surface and decreases with an increase of depth. From those results it is indicated that the latex migrates to the coated surface. The result of this study may be applied to the binder migration study and the quality control in paper mill.

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Evaluations of Sb20Se80-xGex (x = 10, 15, 20, and 25) Glass Stability from Thermal, Structural and Optical Properties for IR Lens Application

  • Jung, Gun-Hong;Kong, Heon;Yeo, Jong-Bin;Lee, Hyun-Yong
    • 한국세라믹학회지
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    • 제54권6호
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    • pp.484-491
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    • 2017
  • Chalcogenide glasses have been investigated in their thermodynamic, structural, and optical properties for application in various opto-electronic devices. In this study, the $Sb_{20}Se_{80-x}Ge_x$ with x = 10, 15, 20, and 25 were selected to investigate the glass stability according to germanium ratios. The thermal, structural, and optical properties of these glasses were measured by differential scanning calorimetry (DSC), X-ray diffraction (XRD), and UV-Vis-IR Spectrophotometry, respectively. The DSC results revealed that $Ge_{20}Sb_{20}Se_{60}$ composition showing the best glass stability theoretically results due to a lower glass transition activation energy of 230 kJ/mol and higher crystallization activation energy of 260 kJ/mol. The structural and optical analyses of annealed thin films were carried out. The XRD analysis reveals obvious results associated with glass stabilities. The values of slope U, derived from optical analysis, offered information on the atomic and electronic configuration in Urbach tails, associated with the glass stability.

PRAM을 위한 Au 첨가 $Ge_2Sb_2T2_5$ 박막의 상변환 특성 (Phase Change Characteristics of Au-added $Ge_2Sb_2T2_5$ Thin Films for PRAM)

  • 신재호;이성갑;이현용
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.52-52
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    • 2010
  • 상변화 재료로 가장 널리 이용되고 있는 $Ge^2Sb^2Te^5$ 박막에 전기전도성이 높은 Au를 첨가하여 상변환 특성을 연구하였다. ($Au)_x(Ge^2Sb^2Te^5)_{1-x}$ (X = 0, 0.05, 0.1) 박막은 Si 와 Glass 위에 Au 타켓과 $Ge^2Sb^2Te^5$ 타겟을 Co Sputtering 하여 만들었다. 증착된 박막은 Nanopulse Scanner 를 사용하여 결정화 속도를 측정하였다. 또한 $100^{\circ}C{\sim}400^{\circ}C$까지 $25^{\circ}C$간격으로 열처리 후 4 point prove를 이용하여 열처리 온도에 따른 저항의 차이를 측정하였으며 비정질 - 결정질 천이의 구조를 확인하기 위하여 XRD를 측정하였다. UV-VIS/IR 장비를 사용하여 비정질 박막과 결정화된 박막의 물성과 전기적 특성을 분석하였다.

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