• Title/Summary/Keyword: Ionomer

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Crystallization behaviour and Degradation of Poly(butylene succinate) ionomer (Poly(butylene succinate) ionomer의 결정화 거동과 분해)

  • Han, Sang-Il;Kim, Dong-Kuk;Im, Seung-Soon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.79-82
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    • 2003
  • An ionomer is defined as an ion-containing polymer with a small amount (usually up to 10-15 mol%) of ionic groups along the backbone chains or as pendant groups. Ionomers have been extensively studied because of the significant changes in their physical properties due to the formation of ionic aggregates, such as enhanced mechanical properties, high melt viscosity, and increased thermal properties.$\^$1-5/ Although there have been many studies of ionomers, the crystallization behaviour of degradable ionomers is still not understood. (omitted)

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Biocompatibility and Biodegradation of Poly(butylene succinate) ionomer (Poly(butylene succinate) ionomer (PBSi)의 생체적합성과 생분해에 관한 연구)

  • Han, Sang-Il;Kang, Sun-Woong;Kim, Byung-Soo;Seungsoon Im
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.187-188
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    • 2003
  • In previous study, we examined poly(butylene succinate) ionomer (PBSi) and confirmed that PBSi showed acceptable mechanical and rheological properties to apply in various field, due to the physical cross-linkage formed by ion aggregation. Besides, the incorporation of ionic groups led to the change of surface properties such as the hydrophilicity and surface morphology, which could affect hydrolytic degradation. (omitted)

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Study on Compatibilities between Asphalt and Various Ionomers (아스팔트와 이오노머 (ionomer)의 상용성에 관한 연구)

  • Son, Young-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.9
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    • pp.4267-4273
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    • 2011
  • In order to select the best compatibilizer for PE/asphalts mixtures, compatibilities of poly(ethylene-co-acrylic acid) and poly(ethylene-co-methacrylic acid) based ionomers with asphalts were investigated via optical microscopy, thermal analysis and rheology. By comparing the polarities of ionomers through an ultimate adsorption of moisture, it was observed that the compatibilities of ionomers increase with the increases of the polarities. By rheological investigations, some of ionomer were observed to be not only compatible but also miscible with asphalts.

195Pt NMR Study of the Influence of Nation Ionomer on the Enhanced Local Density of States at the Surface of Carbon-Supported pt Catalysts

  • Han, Kee-Sung;Lee, Moo-Hee
    • Journal of the Korean Magnetic Resonance Society
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    • v.13 no.2
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    • pp.135-142
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    • 2009
  • $^{195}Pt$ NMR measurements were performed to deduce the variation of local density of states at the Fermi energy ($E_F$-LDOS) at the surface of carbonsupported Pt catalysts due to the addition of $Nafion^{(R)}$ ionomer in the metalelectrode-assembly for fuel cells. The results showed that the EF-LDOS at the surface of Pt particles was enhanced by the addition of $Nafion^{(R)}$ ionomers whereas it was uninfluenced in the inner (bulk) part of the Pt particles. This suggests that the effects of ionomers on the electronic states of the Pt particle surface are related to the electrochemical activity of the catalysts.

LONG-TERM EVALUATING OF THE REMINERALIZATION OF INTERPROXIMAL CARIES ADJACENT TO GLASS IONOMER RESTORATIONS: A MICRO-CT STUDY (미세 전산화 단층 촬영을 이용한 글라스 아이오노머 수복물의 인접면우식 재광화 효과에 관한 장기간 연구)

  • Lee, Hyeok-Sang;Kim, Young-Jae;Kim, Jung-Wook;Jang, Ki-Taeg
    • Journal of the korean academy of Pediatric Dentistry
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    • v.33 no.3
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    • pp.498-503
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    • 2006
  • This in vitro study compared the remineralization of incipient interproximal caries in the presence of three glass ionomer cements (highly-filled glass ionomer cement, compomer, resin-modified glass ionomer cement) and a resin composite(control). The long-term changes in remineralization caused by each material were evaluated by microtomography. Proximal restoration was simulated by placing tooth specimens and the various glass ionomer cements in closed containers with artificial saliva at $37^{\circ}C$ and pH 7.0 for 30 days with constant circulation Tomographic images were obtained with a micro CT scanner at 90, 180, and 270 days, and density-measuring software was used to calculate the micro-density of artificial caries lesions in the specimens. The mean density changes were compared between groups in order to evaluate the effects of remineralization. All data were analyzed using one-way ANOVA and the post-HOC Tukey multiple comparison test at p<0.05. While the density of artificial caries lesions increased for all treatments, the increases for the three glass ionomer groups were significantly higher than that for the resin group in each three month period. As time went on, the amount of density increase of the glass ionomer groups decreased, and significant differences were found between the remineralization effects of the glass ionomer groups.

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THE EFFECT OF LIGHT CURED GLASS IONOMER CEMENT ON THE SHEAR BOND STRENGTH OF ORTHODONTIC BRACKETS (광중합형 글래스 아이오노머 시멘트 교정용 브라켓의 전단결합강도에 미치는 영향)

  • Kim, Cheol;Yoon, Young-Jooh;Kim, Kwng-Won
    • The korean journal of orthodontics
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    • v.27 no.2
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    • pp.327-334
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    • 1997
  • The purpose of this study was to evaluate clinical applicability of light cured glass ionomer cement as a othodontic adhesive. The metal brackets and plastic brackets were bonded with light cured glass ionomer cement(Fuji Ortho $LS^{(R)}$) after polishing with a slurry of pumice, surface conditioning with 10% polyacrylic acid and chemically cured resin(Mono-$Lok2^{(R)}$) after acid etching with 38% phosphoric acid on the extracted human bicuspids. The shear bond strength was tested with a universal testing machine(HGS-100A, Shimadzu Co., Japan) after storage in normal saline at $37^{\circ}C$ or 24 hours and 48 hours. The results were as follows: 1. The shear bond strength of light cured glass ionomer cement group polished with a slurry of pumice was significantly lower than that of chemically cured resin group(P<0.01). 2. The shear bond strength of light cured glass ionomer cement group conditioned with 10% polyacrylic acid was significantly lower than that of chemically cured resin group(P<0.01). 3. The shear bond strength of light cued glass ionorner cement group conditioned with 10% polyacrylic acid was slightly higher than that of light cured glass ionomer cement group polished with a slurry of pumice, but there was no significant difference(P>0.05). 4. There was no significant difference between metal bracket group and plastic bracket group irrelevant off enamel conditioning(P>005). In summary, although the shear bond strength of light cured glass lionomer cement was lower than that of chemically cured resin, it night be clinically applicable.

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A COMPARISON OF THE BOND STRENGTHS BETWEEN SOME CEMENTS AND STAINLESS STEEL MATERIAL (Stainless steel crown을 위한 수종 시멘트의 접착력 비교)

  • Kim, Hong-Ryoul;Jeong, Tae-Sung;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.26 no.3
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    • pp.528-537
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    • 1999
  • The purpose of this study was to analyze and compare the bond strengths between stainless steel plate and zinc phosphate cement, polycarboxylate cement and glass ionomer cement, which are frequently used for cementation of stainless steel crowns. Three cementing materials were glued to the poles standing above stainless steel plate, bovine teeth, light cured glass ionomer restorative material and amalgam. And the tensile bond strengths between them were measured with universal testing machine and the results were statistically processed using ANOVA and Student t-test. The obtained results were as follows : 1. On stainless steel plate, glass ionomer cement and polycarboxylate cement showed higher tensile bond strengths compared to zinc phosphate cement, with no significant difference between the former two. 2. On the surface of bovine teeth and glass ionomer restorative material, glass ionomer cement showed highest bond strength, followed by polycarboxylate cement and zinc phosphate cement in order. 3. For amalgam restoration, polycarboxylate cement and glass ionomer cement showed higher tensile bond strengths than zinc phosphate cement, with no significant difference between the former two.

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Rheology and Morphology of PP/ionomer/clay Nancomposites Depending on Selective Dispersion of Organoclays (유기클레이의 선택적 분산에 의한 폴리프로필렌/아이오노머/클레이 나노복합체의 유변학 및 형태학적 특성 연구)

  • Kim, Doohyun;Ock, Hyun Geun;Ahn, Kyung Hyun;Lee, Seung Jong
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.709-716
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    • 2015
  • In this study, structural developments of polypropylene / ionomer / clay ternary composites were investigated depending on the dispersion and localization of clay. The changes in physical properties were observed adding organoclays 1~10wt% to 90% polypropylene and 10% ionomer blends. The organoclays were localized inside of the dispersed phase under the composition of 3wt%, however, over that composition, clay particles formed stiff network structure in the dispersed phase and additional clays were localized at the interface between two phases. According to the developments of microstructure, the interaction of ternary composites changed from polypropylene-ionomer to polypropylene-ionomer and ionomer-clay which affected rheological properties. The storage modulus (G') of the composites was similar to the blends when clays were localized inside of dispersed phase but increased when clays were localized at interface. Also, the fractured morphology of the composites showed phase boundary and growing radius of dispersed phase depending on addition of fillers when clays were found inside. However, when fillers found at the interface between blends, the radius of the dispersed phase decreased and compatibilized morphology were observed. The interfacial interaction of the ternary composite was quantified depending on the structural development of dispersed phase and localization of clay particles by the rheological properties. The interaction of composites at solid state which was measured through peel adhesion strength increased by growth of interfacial interaction of each component. Furthermore, the crystallinity of the composites was decreased when the clay particles were localized at the interface.

TEMPERATURE CHANGES IN THE PULP ACCORDING TO VAR10US RESTORATIVE MATERIALS AND BASES DURING POLISHING PROCEDURE (연마시 여러 가지 수복재와 이장재의 사용에 따른 치수내 온도변화)

  • Baik, Byeong-Ju;Lee, Doo-Cheol;Kim, Mi-Ra;Kim, Jae-Gon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.27 no.3
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    • pp.410-418
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    • 2000
  • An in vitro study was performed to evaluate the effect of four variables on the temperature rise produced by polishing of restorations. The four variables were : restorative material, base, thickness of remaining dentin, continuous polishing or intermittent polishing. Class V cavities were cut on extracted molar and restored with composite resin, resin-modified glass ionomer cement, compomer, amalgam on the various bases (glass ionomer cement, zinc oxide eugenol cement, zinc phosphate cement) Dentin thickness under the restoration was 0.5mm, 1.5mm. Polishing was done with an aluminum oxide-coated disc. Polishing time was continuous or intermittent for up to 1 minute. Intra-pulpal temperature increased almost linearly in all cases. Amalgam produced highest temperature rises at the pulp, while the composite resin, resin-modified glass ionomer cement and compomer were not different for each other. The rate and extent of temperature rising of amalgam restoration was reduced by presence of a cement base. Zinc oxide eugenol cement bases showed the highest temperature rise, while glass ionomer cement, zinc phosphate cement were not different to the untreated tooth Thickness of remaining dentin was only significant for the amalgam restoration. Continuous polishing produced higher temperature rise than intermittent polishing.

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A STUDY ON THE EFFECT OF DENTIN ADHESIVE TO FLUORIDE RELEASE OF COMPOMER (상아질 결합제가 컴포머의 불소유리에 미치는 영향에 관한 연구)

  • Yoon, Yeo-Sang;Kim, Jong-Soo;Kwon, Soon-Won;Kim, Yong-Kee
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.2
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    • pp.228-237
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    • 2001
  • It is well known that glass-ionomer cement and compomer can release fluoride which can inhibit the progression of dental caries. The purposes of this study were to evaluate whether the fluoride from fluoride-containing filling materials can penetrate the dentin bonding adhesive and the dentin bonding adhesive can increase the bond strength of resin-modified glass ionomer. The amount of fluoride release from resin-modified glass ionomer and compomer was measured during 28 days of period and statistically analyzed by t-test. The bond strength of each material with/without dentin bonding adhesive was measured and also statistically analyzed by t-test. The distribution of fluoride from each material into the tooth was explored by electron probe microanalysis system(EPMA). The experimental teeth used were second primary molars about to exfoliate. The amount of fluoride release from each material was diminished by dentin bonding adhesive during 28 days(p<0.05) and the bond strength was not increased by dentin adhesive in resin-modified glass ionomer. The bond strength of group VI was not detectable. The distribution of fluoride from each material into teeth was according to dentino-enamel junction and dispersed into pulp from pulpal floor. The widest distribution was shown in resin-modified glass ionomer cement filled without the application of dentin bonding adhesive.

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