• 제목/요약/키워드: Ionic condition

검색결과 207건 처리시간 0.028초

Phaffia rhodozyma로부터 천연성 고기능 항산화제 Astaxanthin의 미셀형성을 통한 가용화 및 추출

  • 김영범;이은규;이상윤;임교빈
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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    • pp.198-201
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    • 2000
  • The capacity of micelle formation between astaxanthin and various surfactants was compared. Tween 20 was identified the most suitable surfactant in terms of astaxanthin extraction capacity. The ethylene oxide group of Tween 20 was identified as the most significant factor to increase the HLB value that determined the extraction capacity. The effect of micelle formation condition, such as molar ratio of astaxanthin and Tween 20, pH and ionic strength was also investigated. pH and ionic strength showed no significant effects. Antioxidant activity of astaxanthin was twice of ${\alpha}-tocopherol$ and 4 times of ${\beta} -carotene$. Crude astaxanthin extract from the yeast cell seemed to be less degraded than pure astaxanthin by air and light exposure, probably because of the presence of other carotenoids and lipids. Under the optimal conditions, the molar ratio of micelle formed was found to be 1 : 12 for astaxanthin : Tween 20.

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Protonic Conduction Properties of Nanostructured Gd-doped CeO2 at Low Temperatures

  • Park, Hee Jung;Shin, Jae Soo;Choa, Yong Ho;Song, Han Bok;Lee, Ki Moon;Lee, Kyu Hyoung
    • 한국세라믹학회지
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    • 제52권6호
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    • pp.527-530
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    • 2015
  • The electrical properties of nanostructured Gd-doped $CeO_2$ (n-GDC) as a function of temperature and water partial-pressure were investigated using ac and dc measurements. For n-GDC, protonic conductivity prevails under wet condition and at low temperatures (< $200^{\circ}C$), while oxygen ionic conductivity occurs at high temperatures (> $200^{\circ}C$) under both dry and wet conditions. The grain boundaries in n-GDC were highly selective, being conductive for protonic transport but resistive for oxygen ionic transport. The protonic conductivity reaches about $4{\times}10^{-7}S/cm$ at room temperature (RT).

Prediction of Formic Acid Chromatogram in Gradient Elution Chromatography

  • Won, Hye-Jin;Kim, In-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제6권1호
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    • pp.31-36
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    • 2001
  • Optimal operation in chromatography is needed to save operation time and the solvent used in multiple chromatographic runs. To this end, many simulation studies of chromatography process have been performed. The relationship between the distribution coefficient and the ionic strength is important in gradient elution ion chromatography. Experimental runs and computer simulations were carried out under linear gradient elution condition in order to compare the experiments and the simulation. Experiments were performed with formic acid under isocratic conditions to determine the simulation equation parameters. Computer simulation was based on three equations which related distribution with ionic strength as follows; K=${\alpha}$I(sup)-${\beta}$, K=A+BI+Cl$^2$and K=y(sub)0+A$_1$$.$e(sup)(-I/m$_1$). The effects of gradient slope on the chromatograms are discussed, and good agreement between the experimental and the simulated results is shown.

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[(ZrO2)$_{1-x}$(CeO2)$_x$$_{0.92}$(Y$_2$O$_3$)$_{0.08}$ 고용체의 전기전도도 (Electrical Conductivities of [(ZrO2)$_{1-x}$(CeO2)$_x$]$_{0.92}$(Y$_2$O$_3$)$_{0.08}$ Solid Solution)

  • 이창호;최경만
    • 한국세라믹학회지
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    • 제35권12호
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    • pp.1323-1328
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    • 1998
  • The electrical conductivities of the yttria (8mol%) stabilizedzirconia-ceria solid solutions were measured as a function of oxygen partial between 80$0^{\circ}C$ and 100$0^{\circ}C$ using 4-probe d.c. method Under pure oxygen atmosphere the oxygen ionic conductivity of CeO2-ZrO2 decreased with the concentration of CeO2 Under reducing condition electronic conduction due to the redox equilibrium of Ce ion was observed. Total ionic and electronic conductivities fitted by a defect model enabled to determine the electronic transference number(tei) which increased with the concentration of CeO2 and with the degree of reduction.

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절연체-금속계면에서 가동이온의 중성화와 이온화 (Neutralization and Ionization of movable ion at insulator-metal interface)

  • 이성길;국상훈
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1988년도 추계학술대회 논문집
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    • pp.33-35
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    • 1988
  • From the study of mechanism of electrical conduction of film which is made from Polyethylene Terephthalate at very high temperature which is larger than low electric field and glass transition point, we find that there is a extraordinary non ohmic region (I∝V$^n$, 0

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1-Butyl-3-Methyl Imidazolium Hydrogen Sulphate Promoted One-Pot Three-Component Synthesis of Amidoalkyl Naphthols

  • Sapkal, Suryakant B.;Shelke, Kiran F.;Madje, Balaji R.;Shingate, Bapurao B.;Shingare, Murlidhar S.
    • Bulletin of the Korean Chemical Society
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    • 제30권12호
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    • pp.2887-2889
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    • 2009
  • An efficient and easy method for one-pot three-component synthesis of amidoalkyl naphthols by the condensation of aromatic/heteroaromatic/aliphatic aldehydes, 2-naphthol and amides or urea under thermal condition at $60^{\circ}C$ in the presence of acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulphate ([bmim]$HSO_4$) has been described.

해수중의 물질 분리 및 분석을 위한 Fl-FFF의 안정화 기법 (Stabilization Methods to Separate and Analyze Materials in Seawaters using Fl-FFF)

  • 최수훈;이상엽;홍승관;문지희
    • 한국물환경학회지
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    • 제25권2호
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    • pp.288-294
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    • 2009
  • Flow field-flow fractionation (Fl-FFF) device has been widely used to verify the size and molecular weight of various colloids and organics. The Fl-FFF, however, generally uses carrier solutions with only low to moderate ionic strengths to exclude the high affinity of materials to the membrane under high ionic strength conditions. Thus, materials existing in seawaters have not been accurately analysed based on the hydrodynamic size and molecular weight using current Fl-FFF techniques. The highest ionic strength tested was up to 0.1 M, while seawater ionic strength is about 0.6 M. The aim of this study is to accurately measure the hydrodynamic size of particles under carrier solutions close to seawater conditions with the Fl-FFF. By employing various operating conditions during the Fl-FFF analyses, it was demonstrated that the flow conditions, the concentration of surfactants, and stabilization times were key factors in acquiring compatible data. Results have shown that the cross flow was more influential factor than the channel flow. The concentration of the surfactant was to be at least 0.05% and the minimum 15 hr of stabilization was needed for accurate and reproducible data acquisition under seawater condition.

이온성분의 환경거동과 기상인자와의 관계: 제주지역을 중심으로 한 유.무기성 이온성분의 대기-해양지화학 (The Behavior of Particulate-Bound logic Components and Their Relationships with Meteorological Parameters: Air-Sea Geochemistry of Inorganic and Organic tons in Cheiu Island)

  • 김기현;이강웅
    • 한국대기환경학회지
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    • 제14권5호
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    • pp.479-490
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    • 1998
  • The concentrations of ten inorganic (sodium, chloride, sulfate, ammonia, etc.) and three organic (acetate, formate, and MSA) ions associated with airborne particulate matter were measured from Cheju Island, Korea during the three field intensive campaigns conducted in (1) Sept./oct. 1997 (fall), (2) Dec. 1997 (winter), and (3) April 1998 (spring). The results of our measurements indicated that the concentration levels of most ionic species were decreasing significantly across the three experimental periods. The patterns of concentration reduction were clear as the sum of all cation and anion species changed dramatically across those periods such as 294> 144 > 65 and 193 >96>74 nequiv/m3, respectively. The changes were best explained in terms of the wind rose patterns of the study site. Since our sampling spot is located on the western-end point of Cheju Island, it is likely to reflect the effects of diverse sources such as natural, marine processes during NW and local non-maritime ones during SE winds. .Hence, the periodical changes in ionic concentrations may be accounted for by the comparable changes in wind direction. To further investigate environmental characteristics of these ionic components, correlation analysis was conducted not only between meteorological and ion data but between different ion-pairs. The results of these analyses confirm that the concentration levels of ionic species are strongly affected by wind speed and temperature and that there are certain patterns between ion species to which such effects apply. In light of the significance of the wind rose patterns in the area, we further extended these analyses into four data groups that were divided on the basis of wind direction. The results of these analyses showed that the strength of correlations between important pairs (e.g.:. between windspeed and most of major inorganic species including sodium and chloride) can be ranked on the distribution of major ions are very diverse, depending on data grouping scheme for such analysis. The results of this study thus suggest that environmental behavior of chemical components be analyzed in various respects, rather than simple standard, especially if measurements are made in complex environmental condition under which both natural and anthropogenic effects are competing each other.

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Advanced Tenderization of Brine Injected Pork Loin as Affected by Ionic Strength and High Pressure

  • Kim, Honggyun;Ramachandraiah, Karna;Yun, Young Chan;Kwon, In Suk;Park, Ha Neul;Kim, Hack-Youn;Lee, Eun-Jung;Hong, Geun-Pyo
    • 한국축산식품학회지
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    • 제40권6호
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    • pp.1055-1065
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    • 2020
  • This study investigated the effects of brine injection and high hydrostatic pressure (HHP) on the quality characteristics of pork loin. Brine with ionic strength conditions (0.7% vs 1.5% NaCl, w/v) were injected into pork loins, and the meat was pressurized up to 500 MPa for 3 min. As a quality indicator, moisture content, color, cooking loss and texture profile analysis (TPA) of pork loins were estimated. Based on the results, brine with low ionic strength (0.7% NaCl) resulted in low injection efficiency and high cooking loss, although, it improved tenderness of pork loin at moderate pressure level (~200 MPa). While high ionic strength condition (1.5% NaCl injection) lowered the hardness of pork loins at relatively high HHP level (400-500 MPa), it also caused high cooking loss. To commercialize the brine injected pork loins, it was necessary to regulate brine compositions, which was not evaluated in this study. Nevertheless, the present study demonstrated that brine injection followed by moderate pressure (200 MPa) could improve the tenderness of pork loins without causing other major quality losses.

연소 전 조건에서 음이온이 Sulfite계인 이온성 액체의 CO2 흡수 특성 (Absorption characteristic of carbon dioxide in Ionic Liquids based sulfite anion in the pre-combustion condition)

  • 백근호;장현태;차왕석
    • 한국산학기술학회논문지
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    • 제22권3호
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    • pp.763-769
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    • 2021
  • 본 연구는 지구 온난화 현상의 주원인인 이산화탄소의 제거를 목적으로 최근에 주목 받고 있는 물질인 이온성액체를 실험실 규모로 제조하였다. 음이온이 Sulfite계인 이온성 액체의 이산화탄소 흡수능, 초기흡수속도 그리고 재생성을 조사하기 위하여 기-액 흡수평형장치를 이용하여 연구하였다. 그 결과 음이온이 Sulfite계인 이온성액체 중 높은 흡수능을 갖는 이온성액체는 음이온이 ethyl sulfite인 경우이며, 특히 [beim] ethyl sulfite의 경우 흡수평형압력이 22 bar인 조건에서의 흡수력은 1.1 mol CO2/mol IL로 가장 높은 흡수력을 나타냈다. 재생성 연구에서 음이온이 Sulfite계인 이온성액체는 모두 재생후의 흡수력이 약 7%정도 감소하였으며, 이로부터 재생성이 우수함을 알 수 있다. 점도 감소를 목적으로 두 종류의 희석제를 첨가하였을 때 희석제는 단지 이온성액체의 흡수력을 감소시키는 희석효과로 작용하였으며 희석제 첨가에 따른 흡수력의 증가는 없었다. 흡수실험에 따른 점도변화의 정도를 조사하기 위해 흡수반응 전과 흡수 실험 후 재생한 시료의 점도를 측정하였으며, 실험결과 흡수실험 후 시료의 점도가 흡수실험 전보다 약 8% 정도 감소하는 경향을 보였다. 그러나 흡수제 합성은 1단계에서 이루어지며 사용되는 원료물질 또한 저렴한 장점이 있으며 흡수능에서는 우수한 재생성과 높은 안정성을 가지고 있음을 알 수 있었다.