• Title/Summary/Keyword: Ionic Surfactant

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Influence of Interaction of Surface Charges of PET Fiber and $\alpha$-Fe2O3 Particle on Detergency of Particulate Soil (PET섬유와 $\alpha-Fe_2O_3$ 입자의 표면전하간 상호작용이 고형오구의 세척성에 미치는 영향)

  • 강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.8
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    • pp.1132-1140
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    • 1998
  • The adhesion and removal of $\alpha$-Fe2O3 particles on the from PET fabric in NPE solution with different ionic strength were discussed in terms of interaction of surface charge of particle and substrate. The adhesion of $\alpha$-Fe2O3 particles to PET fabric and its removal from PET fabric were carried out by using water bath shaker and Terg-O-Tometer under various solution conditions. The ζ potential of PET fiber and $\alpha$-Fe2O3 particles in the detergent solution were measured by steaming potential and microelectrophoresis methods, respectively. The adhesion and removal amount of $\alpha$-Fe2O3 particles on the from PET fabric increased with increasing time of adhesion and removal, and the rates of adhesion and removal were high at the initial stage of adhesion and removal, and then the rates decreased with passing time. The adhesion and removal amount of $\alpha$-Fe2O3 particles on and from PET fabric increased with increasing pH of solution regardless ionic strength. The tendencies and degree of adhesion and removal were very similar regardless interaction of surface charge of particle and fiber. Therefore, in the presence of a surfactant and electrolyte, the influence of interaction of surface charge of particle and substrate on the detergency of particulate soil was small.

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Solubillzation and Extraction Of Antioxidant Astaxanthin by Micelle Formation from Phaffia rhodozyma Cell Homogenate (Phaffia rhodozyma 세포파쇄액으로부터 항산화제 Astaxanthin의 미셀 형성을 통한 가용화 및 추출)

  • Kim, Young-Beom;Ryu, Kang;Lim, Gio-Bin;Lee, Eun-Kyu
    • KSBB Journal
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    • v.17 no.2
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    • pp.176-181
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    • 2002
  • Astaxanthin (3,3'-dihydroxy-${\beta}$, ${\beta}$-carotene-4-4'-dione), a natural pigment of pink to red color, is widely distributed in nature particularly in the skin layer of salmonoids and the crust of shrimp, lobster, etc. Recently, it was produced from the yeast culture of Phaffia rhodozyma. Because of its high thermal stability and antioxidant functionality, its applications can be extended into food, cosmetics, and pharmaceutical ingredient beyond the traditional feed additive. Because of its very high lipophilicity, astaxanthin has been extracted traditionally by strong organic solvents such as chloroform, petroleum ether, acetone, etc. In this study, we developed a surfactant-based solubillization system for astaxanthin, and used it to extract astaxanthin from disrupted yeast cells. Among Tween 20, Triton X-100 and SDS, Tween 20 was identified as the most suitable surfactant in terms of extraction capacity and safety. The ethylene oxide group of Tween 20 was identified as the most significant factor to increase the HLB value that determined the extraction capacity. The effects of micelle formation condition, such as the molar ratio of astaxanthin and Tween 20, pH, and ionic strength were also investigated. pH and ionic strength showed no significant effects. The optimal molar ratio between astaxanthin and Tween 20 was 1 : 12. Antioxidant activity of astaxanthin was higher than ${\beta}$-carotene and ${\alpha}$-tocopherol. Astaxanthin in the crude extract from the yeast cell was more resistant to air and/or light degradation than pure astaxanthin, probably because of the presence of other carotenoids and lipids.

A Study on the Extraction of Alkaline Protease from Bacillus licheniformis Fermentation Broth using Reverse Micelle (역미셀을 이용한 Bacillus licheniformis 발효액으로 부터 알카리성 단백질 분해효소의 추출에 관한 연구)

  • 권성필;구윤모홍성안
    • KSBB Journal
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    • v.6 no.1
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    • pp.105-109
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    • 1991
  • In separating alkaline protease from the bacteria (Bacillus licheniformis) fermentation broth using reverse micelle, effects of various factors;ionic strength, pH and surfactant concentration, on separation efficiency were studied. KCl controls the ionic strength. The lower KCl concentration was in the feed solution, the more protein and activity was recovered. The higher KCl concentration was in the stripping solution, the more protein and activity was recovered. Using sodium-di-2-ethylhexyl sulfosuccinate(Aerosol-OT or AOT) as a surfactant, the higher AOT concentration in the solvent, the more activity and protein were recovered. 0.1N NaOH and IN HCl were used to adjust pH. Maximum recovery of protein mass and activity were obtained at feed solution of pH 5.3. Maximum activity was recovered at stripping solution of pH 7.5

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A Study on Fire-proof Characteristics of Ultra High Strength Concrete Using Polyamide Fiber (폴리아미드섬유를 사용한 초고강도 콘크리트의 내화성능에 관한 연구)

  • Lee, Soo-Choul;Jeon, Joong-Kyu;Jeon, Chan-Ki
    • Journal of the Society of Disaster Information
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    • v.7 no.4
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    • pp.286-293
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    • 2011
  • Accordingly architectural structure is getting high-rise and bigger, a use of high strength and high performance concrete has been increased. High performance concrete has cons of explosion in a fire. This explosion in the fire can cause the loss of the sheath on a concrete surface, therefore it effects that increasing a rate of heat transmission between the steel bar and inner concrete. Preventing this explosion of high performance concrete in the fire, many kinds of researches are now in progressing. Typically, researches with using polypropylene-fiber and steel-fiber can prove controling the explosion, but the reduction of mobility was posed as a problem of workability. Consequently, to solve the problem as mentioned above, concrete cans secure fire resisting capacity through the using of coating liquid, including Ester-lubricant and non-ionic characteristic surfactant. This research has been drawn a ideal condition in compressive strength areas of concrete by an experiment. When applying 13mm of polyamide fiber, proper fiber mixing volume by compressive strength areas of concrete more than 2.5kg in 160MPa. These amount of a compound can control the explosion.

Influence of Surfactants on Enhancing Transport of Bacteria in Geological Materials (지질매질체내에서 계면활성제가 박테리아 이동 증진에 미치는 영향)

  • Choi, Nag-Choul;Park, Seong-Jik;Kim, Song-Bae;Kim, Dong-Ju;Lee, Seong-Jae
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.1017-1023
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    • 2010
  • This study investigated the effect of surfactants (nonionic surfactant (Tween 20), biosurfactant) on enhancing transport of bacteria (Bacillus subtilis ATCC 6633) in geological materials. Column experiments were performed under various surfactant conditions with columns packed with quartz sand (particle size distribution: 0.5~2.0 mm, mean diameter: 1.0 mm). Bacterial mass recovery, sticking efficiency, and other parameters were quantified from breakthrough curves. Results indicate that bacterial attachment to sand surfaces increased considerably in the presence of mineral salt medium (MSM), especially at the inlet, which was due to the increase of ionic strength by MSM. It was observed that bacterial transport in sand columns was enhanced in the presence of surfactant. Results also show that simultaneous injection of both surfactant and MSM or pre-injection of surfactant was more effective in bacterial transport enhancement than after-injection of surfactant. This study suggests that transport of bacteria in geological materials could be influenced by surfactants and their injection methods.

Study on the Solubilization of 4-ethylaniline in the aqueous solutions of mixed surfactants (혼합계면활성제의 수용액에서 4-ethylaniline의 가용화에 관한 연구)

  • Lee, Dong-Cheol;Lee, Byung-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.3
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    • pp.438-447
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    • 2020
  • The critical micelle concentration (CMC) values of the mixed surfactant systems and the solubilization conatant (Ks) values of 4-ethylaniline in those solutions were measured and analyzed by the UV-Vis method. As a result, the mixed surfactant systems of TTAB/LSB and TTAB/TX-100 did not deviate significantly from ideal mixed micellization. However, the mixed systems of SDS/LSB and SDS/TX-100 showed great negative deviations from ideal mixed model. These differences showed that the intensity of the interaction between two components in the mixed micelle was different for each mixed system and that these differences greatly influenced the solubilization of 4-ethylaniline by a mixed surfactant system. Among pure surfactants, an anionic surfactant such as SDS showed a greater Ks value than other ionic surfactants, and the Ks value by each surfactant system decreased in the order of SDS≫TTAB≧LSB>TX-100. In addition, the Ks values of all the mixed surfactant systems were higher than those of the pure surfactants constituting the mixed systems.

Stabilization Methods to Separate and Analyze Materials in Seawaters using Fl-FFF (해수중의 물질 분리 및 분석을 위한 Fl-FFF의 안정화 기법)

  • Choi, Soohoon;Lee, Sangyoup;Hong, Seungkwan;Moon, Jihee
    • Journal of Korean Society on Water Environment
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    • v.25 no.2
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    • pp.288-294
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    • 2009
  • Flow field-flow fractionation (Fl-FFF) device has been widely used to verify the size and molecular weight of various colloids and organics. The Fl-FFF, however, generally uses carrier solutions with only low to moderate ionic strengths to exclude the high affinity of materials to the membrane under high ionic strength conditions. Thus, materials existing in seawaters have not been accurately analysed based on the hydrodynamic size and molecular weight using current Fl-FFF techniques. The highest ionic strength tested was up to 0.1 M, while seawater ionic strength is about 0.6 M. The aim of this study is to accurately measure the hydrodynamic size of particles under carrier solutions close to seawater conditions with the Fl-FFF. By employing various operating conditions during the Fl-FFF analyses, it was demonstrated that the flow conditions, the concentration of surfactants, and stabilization times were key factors in acquiring compatible data. Results have shown that the cross flow was more influential factor than the channel flow. The concentration of the surfactant was to be at least 0.05% and the minimum 15 hr of stabilization was needed for accurate and reproducible data acquisition under seawater condition.

Improvement in Fungicidal Activity of Ethaboxam by a Non-ionic Surfactant, Polyoxyethylene Cetyl Ether

  • Shin Kwang-Hoon;Kim Dal-Soo;Chun Sam-Jae;Park Eun-Woo
    • The Plant Pathology Journal
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    • v.22 no.3
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    • pp.303-308
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    • 2006
  • Ethaboxam is a fungicide controlling plant diseases caused by Oomycetes. Efforts were made to improve its fungicidal activity applying formulation technology. Fungicidal activity of ethaboxam against cucumber downy mildew caused by Pseudoperonospora cubensis was improved by incorporating polyoxyethylene cetyl ether (PCE) in a wettable powder formulation. It was found that the optimum combination ratio of PCE and ethaboxam was 3:1, and a tank-mix of $150{\mu}g/ml$ of ethaboxam and $450{\mu}g/ml$ of PCE would be as good as the standard 25 % WP formulation diluted to $250{\mu}g/ml$ ethaboxam without PCE in controlling cucumber downy mildew. Based on this results, a wettable powder (WP) co-formulation containing 15% of ethaboxam and 45% of PCE was developed in this study, and tested for its performance in the fields. This co-formulation showed significant improvement in persistence of fungicidal activity and curative efficacy of ethaboxam against cucumber downy mildew. The improved control efficacy was also confirmed for control of grape downy mildew caused by Plasmopara viticola and potato late blight caused by Phytophthora infestans in the field tests.

Stability of concentrated Colloidal Liquid Aphrons containing a quaternary ammonium salt in the continuous phase (사차 암모늄 염을 함유하는 농축된 콜로이드 액상 에이프런의 연속상에서의 안정성)

  • Hahm, Hyung Chul;Hong, Won Hi;Lee, Choul Ho
    • Clean Technology
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    • v.7 no.4
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    • pp.291-297
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    • 2001
  • In this study, the stability of concentrated colloidal liquid aphrons (CLAs) containing Aliquat 336 was measured. CLAs in the continuous phase are stabilized by water-soluble surfactant and oil-soluble surfactant. To compare the stability of CLAs, half-life was introduced. According to the change of state of solution, the rate of break-up of concentrated CLAs changed rigorously at critical coagulation concentration. Critical coagulation concentration was measured with changing pH. The effects of ionic strength and concentration of Sodium Dodecyl Benzene Sulfonate (SDBS) on the stability of concentrated CLAs in the continuous phase were also investigated.

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Feasibility Study on Soil Flushing for Railway Soil Contaminated with Lubricant Oil and Zinc (토양세정 기술을 활용한 윤활유와 아연 복합오염 철도토양의 정화 연구)

  • Park, Sung-Woo;Cho, Jung-Min;Lee, Jae-Young;Park, Joon-Kyu;Baek, Ki-Tae
    • Journal of Soil and Groundwater Environment
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    • v.16 no.4
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    • pp.31-37
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    • 2011
  • The feasibility study of soil flushing was investigated to remediate lubricant oil and zinc contaminated railway soil. In this study, mixed washing agents of surfactant and inorganic acid/base were used for the simultaneous removal. The mixed washing agent of non-ionic surfactant and HCl removed 15% of the lubricant oil and 40% of zinc, respectively. Alkaline-enhanced soil washing process increased the removal of lubricant oil up to 40%. This is because alkaline solution reduced the interfacial tension between water phase and lubricant oil phase due to the soap formation reaction. To simulate in-situ soil flushing for the remediation of railroad-related contamination, two dimensional soil flushing was carried out based on the results of batch soil washing. In the soil flushing, the removal efficiencies of lubricant oil and zinc were 34% and 16%, respectively. Even though the removal efficiency was low, the mixed washing agent can remove metal and lubricant oil simultaneously.