• Title/Summary/Keyword: Ionic CNT

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Applicability Assessment of Carbon Nanotube to Slow Sand Filtration for Bacteria Removal (박테리아 제거를 위한 완속 모래여과에서 탄소나노튜브의 적용성 검토)

  • An, Hee-Kyung;Park, Seong-Jik
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.12
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    • pp.873-878
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    • 2014
  • The applicability of carbon nanotube (CNT) to slow sand filtration for the removal of bacteria was studied using scanning electron microscope and column experiments. The morphology of CNT were investigated using scanning electron microscope and the CNT looked like a skein serving bacteria favorable site for adhesion. Column experiments were performed over a range of CNT filter depth, pH, and ionic strength. Bacteria removal efficiency was found to increase from 44.15% to 99.95% as the CNT filter depth increased from 1 cm to 5 cm, and 3 cm of CNT filter depth was required for significant removal of bacteria. pH increase from 5.5 to 8.5 decreased the bacteria removal efficiency, due to the electrostatic repulsion between bacteria and CNT at higher pH. Bacteria removal efficiency decreased from 97.25% to 70.90% as the ionic strength increased from 0 mM to 50 mM. This study demonstrated that the CNT can be applied to slow sand filtration for treating microbially contaminated water.

Improved Properties of Li4Ti5O2 (LTO) by Surface Modification with Carbon Nanotube (CNT) (CNT 첨가를 통해 표면 처리한 LTO의 특성향상에 관한 연구)

  • Park, Soo-Gil;Kim, Cheong;Habazaki, Hiroki
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.191-195
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    • 2016
  • Among the lithium metal oxides for hybrid-capacity, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. However, LTO has a limitation of low ionic and electronic conductivity. To enhance the ionic and electronic properties of $Li_4Ti_5O_{12}(LTO)$, we synthesized the spherical LTO/CNT composite by sol-gel process for hybrid capacitors. CNT interconnection networks between CNT-LTO particles enhanced electronic conductivity and electrochemical charging/discharging properties. All of the LTO samples was observed to show the spinel structure and spherical morphology with the diameter of $5{\sim}10{\mu}m$. Especially, spherical LTO/CNT composite of the CNT-3 wt% showed the enhanced capacity from 110 mAh/g to 140 mAh/g at 10 C.

Fabrication and Straining Model of a CNT/EAP Composite Film (카본나노튜브/도전성폴리머(CNT/EAP) 복합재 필름의 제조 및 특성분석)

  • Zhang, Shuai;Kim, Cheol
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.117-120
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    • 2005
  • The relationship between strain and applied potential was derived for composite actuators consisting single-wall carbon nanotubes (SWNTs) and conductive polymers (CPs). During deriving the relationship, an electrochemical ionic approach is utilized to formulate the electromechanical actuation of the composite film actuator. The results show that the well-aligned SWNTs composite actuator can give good actuation responses and high actuating forces available. The actuation is found to be affected by both SWNTs and CPs components and the actuation of SWNTs component has two kinds of influences on that of the CPs component: reinforcement at the positive voltage and abatement at the negative voltage. CNT/EAP was fabricated successfully using the chemical polymerization method.

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CNT Emitter Coated with Nanoparticles for FED Application

  • Kim, Jong-Ung;Lee, Jung-A;Ryu, Byong-Hwan;Kim, In-Ho;Moon, Hee-Sung;Kim, Jae-Myeong;Choi, Young-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1198-1201
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    • 2006
  • Carbon nanotubes (CNTs) have used as an electron field emitter of the field emission display (FED) due to their characteristics of high-electron emission, rapid response and low power consumption. However, to commercialize the FED with CNT emitter, some fundamental problems regarding life time and emission efficiency have to be solved. In this study, we investigated the metal coated CNT as a field emitter on which metal nanoparticles were coated by chemical modification. Metal nanoparticles, such as Ru, Pd, were synthesized by solution reduction method. The size of the metal nanoparticle has the range of 2 - 5 nm. Surface was modified chemically with the use of ionic surfactant which changed the surface charge of nanoparticles.

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Improvement of Mechanical Properties of IPMC through Developing a Degree of Dispersion of SWCNT/Nafion Composite (SWCNT/Nafion 복합체의 분산능 향상을 통한 IPMC의 기계적 특성 향상)

  • Kwon, Hui-June;Kim, Ha-Na;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.5
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    • pp.131-136
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    • 2011
  • Many researchers are recently studying about Electroactive polymer(EAP). But it has a physical limitation, because of property of material. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. This study focuses on the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. To come up with mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we dispersed Single-walled carbon nanotubes(SWCNTs). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. We fabricated a disperse SWCNT/Nafion composite uniformly. Through the use of the E-beam evaporator to form an uniform electrode layer, we consummated the IPMC actuator. This result shows improving 1.5 times mechanical properties about driving force in IPMC.

Fabrication of Electro-active Polymer Actuator Based on Transparent Graphene Electrode

  • Park, Yunjae;Choi, Hyonkwang;Im, Kihong;Kim, Seonpil;Jeon, Minhyon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.386.1-386.1
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    • 2014
  • The ionic polymer-metal composite (IPMC), a type of electro-active polymer material, has received enormous interest in various fields such as robotics, medical sensors, artificial muscles because it has many advantages of flexibility, light weight, high displacement, and low voltage activation, compare to traditional mechanical actuators. Mostly noble metal materials such as gold or platinum were used to form the electrode of an IPMC by using electroless plating process. Furthermore, carbon-based materials, which are carbon nanotube (CNT) and reduced graphene-CNT composite, were used to alter the electrode of IPMC. To form the electrode of IPMC, we employ the synthesized graphene on copper foil by chemical vapor deposition method and use the transfer process by using a support of PET/silicone film. The properties of graphene were evaluated by Raman spectroscopy, UV/Vis spectroscopy, and 4-point probe. The structure and surface of IPMC were analyzed via field emission scanning electron microscope. The fabricated IPMC performance such as displacement and operating frequency was measured in underwater.

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Multiwalled Carbon Nanotubes Functionalized with PS via Emulsion Polymerization

  • Park, In-Cheol;Park, Min;Kim, Jun-Kyung;Lee, Hyun-Jung;Lee, Moo-Sung
    • Macromolecular Research
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    • v.15 no.6
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    • pp.498-505
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    • 2007
  • This study demonstrated the in-situ functionalization with polymers of multi-walled carbon nanotubes (MWNTs) via emulsion polymerization. Polystyrene-functionalized MWNTs were prepared in an aqueous solution containing styrene monomer, non-ionic surfactant and a cationic coupling agent ([2-(methacryloyloxy)ethyl]trime-thylammonium chloride (MATMAC)). This process produced an interesting morphology in which the MWNTs, consisting of bead-string shapes or MWNTs embedded in the beads, when polymer beads were sufficiently large, produced nanohybrid material. This morphology was attributed to the interaction between the cationic coupling agent and the nanotube surface which induced polymerization within the hemimicellar or hemicylindrical structures of surfactant micelles on the surface of the nanotubes. In a solution containing MATMAC alone without surfactant, carbon nanotubes (CNTs) were not well-dispersed, and in a solution containing only surfactant without MATMAC, polymeric beads were synthesized in isolation from CNTs and continued to exist separately. The incorporation of MATMAC and surfactant together enabled large amounts of CNTs (> 0.05 wt%) to be well-dispersed in water and very effectively encapsulated by polymer chains. This method could be applied to other well-dispersed CNT solutions containing amphiphilic molecules, regardless of the type (i.e., anionic, cationic or nonionic). In this way, the solubility and dispersion of nanotubes could be increased in a solvent or polymer matrix. By enhancing the interfacial adhesion, this method might also contribute to the improved dispersion of nanotubes in a polymer matrix and thus the creation of superior polymer nanocomposites.