• Title/Summary/Keyword: Ion sensor

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Design and construction of a new ultraviolet sensor using CsI deposition in the ionization chamber

  • Souri, R.;Negarestani, A.;Souri, S.;Farzan, M.;Mahani, M.
    • Nuclear Engineering and Technology
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    • v.50 no.5
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    • pp.751-757
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    • 2018
  • In this article, a UV sensor that is an appropriate tool for fire detection has been designed and constructed. The structure of this UV sensor is an air-filled single-wire detector that is able to operate under normal air condition. A reflective CsI photocathode is installed at the end of the sensor chamber to generate photoelectrons in the ion chamber. An electric current is produced by accelerating photoelectrons to the anode in the electric field. The detector is able to measure the intensity of the incident UV rays whenever the current is sufficiently high. Therefore, the sensitivity coefficient of this sensor is found to be $7.67{\times}10^{-6}V/photons/sec$.

Suggestion for deep learning approach to solve the interference effect of ammonium ion on potassium ion-selective electrode

  • Kim, Min-Yeong;Heo, Jae-Yeong;Oh, Eun Hun;Lee, Joo-Yul;Lee, Kyu Hwan
    • Journal of the Korean institute of surface engineering
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    • v.55 no.3
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    • pp.156-163
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    • 2022
  • An ammonium ion with a size and charge similar to that of potassium can bind to valinomycin, which is used as an ion carrier for potassium, and cause a meaningful interference effect on the detection of potassium ions. Currently, there are few ion sensors that correct the interference effect of ammonium ions, and there are few studies that specifically suggest the mechanism of the interference effect. By fabricating a SPCE-based potassium ion-selective electrode, the electromotive force was measured in the concentration range of potassium in the nutrient solution, and the linear range was measured to be 10-5 to 10-2 M, and the detection limit was 10-5.19 M. And the interference phenomenon of the potassium sensor was investigated in the concentration range of ammonium ions present in the nutrient solution. Therefore, a data-based analysis strategy using deep learning was presented as a method to minimize the interference effect.

Highly sensitive and selective detection of cyanide in aqueous solutions using a surface acoustic wave chemical sensor (표면음향파 화학센서를 이용한 수용액 중 시안화이온의 선택적인 고감도 검출)

  • Lee, Soo Suk
    • The Journal of the Acoustical Society of Korea
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    • v.35 no.6
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    • pp.473-479
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    • 2016
  • We report a highly selective and sensitive 200 MHz Surface Acoustic Wave (SAW) sensor that can detect cyanide ion in aqueous solution using surface immobilized thioester molecules in combination with gold nanoparticles (AuNPs). To construct the sensor device, a monolayer of thioester compound was immobilized on the SAW sensor surface. At the sensor surface, hydrolysis of thioester group by nucleophilic addition of cyanide occurred and the resulting free thiol unit bound to AuNP to form thiol-AuNP conjugate. For the signal enhancement, gold staining signal amplification process was introduced subsequently with gold (III) chloride trihydrate and reducing agent, hydroxylamine hydrochloride. The SAW sensor showed a detection ability of $17.7{\mu}M$ for cyanide in aqueous solution and demonstrated a saturation behavior between the frequency shift and the concentration of cyanide ion. On the other hand, our SAW sensor had no activities for other anions such as fluoride ion, acetate ion and sulfate ion, moreover, no significant interference observed by other anions. Finally, all the experiments were carried out in-house developed sensor and fluidics modules to obtain highly reproducible results.

Fabrication of Disposable pH Sensor with Micro-volume Type (Micro-volume형 일회용 pH 센서 제작)

  • Jung, Ho;Kim, Heung-Rak;Kim, Young-Duk;Jung, Woo-Chul;Kim, Dong-Su;Nam, Hyo-Duk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.950-952
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    • 2003
  • This paper have been studied fabrication and characteristics of disposable pH sensor using MEMS technology. The sensor has two open-well structure, the container for the internal electrolyte and electrode were formed by anisotropically etching a silicon substrate. unlike currently used KCI saturated solution, the structure was introduced hydrogel which take an advantage of miniaturization, bulk product, a low price. PU and CA/TP used to measurement ion detection, one is reference membrane and the other is pH. fabricated sensor is encapsulated entirely with epoxy, finally sensor was estimated various ion sorts and pH ranges.

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Ion-Based Micro Vibration Sensor for Ultra-High Frequency Vibration Detection (초고주파수 진동 감지를 위한 이온 질량기반 진동센서)

  • Kim, Kwang-Ho;Seo, Young-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.9
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    • pp.728-732
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    • 2008
  • This paper presents ion-based micro vibration sensor for the ultra-high frequency vibration detection. Presented sensor uses the motion of anion and cation in an electrolyte. Electrolyte vibration sensors have the high shock survival characteristics and a simple read-out circuit because of the small mass and own charges of ions. Presented sensor measures the induced electric potential by the mechanical-electrical coupling. It consist of electrolyte chamber and detection electrode. Electrolyte chamber was fabricated by PDMS molding. Detection electrode was made of gold evaporation on pyrex glass. Size of electrolyte chamber was designed as $600{\times}600{\times}100um$. Detection electrode had 200nm-thick and 42um-gap. In the experimental study, 5.8M sodium Chloride (NaCl) solution was used as electrolyte in 36nl-chamber. Mechanical vibration was measured from 2kHz to 4MHz.

Development of active discharge tester for high capacity lithium-ion battery (대용량 리튬 이온 배터리용 Active 방전시험기의 개발)

  • Park, Joon-Hyung;Yunana, Gani Dogara;Park, Chan Won
    • Journal of Industrial Technology
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    • v.40 no.1
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    • pp.13-18
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    • 2020
  • Lithium-ion batteries have a small volume, light weight and high energy density, maximizing the utilization of mobile devices. It is widely used for various purposes such as electric bicycles and scooters (e-Mobility), mass energy storage (ESS), and electric and hybrid vehicles. To date, lithium-ion batteries have grown to focus on increasing energy density and reducing production costs in line with the required capacity. However, the research and development level of lithium-ion batteries seems to have reached the limit in terms of energy density. In addition, the charging time is an important factor for using lithium-ion batteries. Therefore, it was urgent to develop a high-speed charger to shorten the charging time. In this thesis, a discharger was fabricated to evaluate the capacity and characteristics of Li-ion battery pack which can be used for e-mobility. To achieve this, a smart discharger is designed with a combination of active load, current sensor, and temperature sensor. To carry out this thesis, an active load switching using sensor control circuit, signal processing circuit, and FET was designed and manufactured as hardware with the characteristics of active discharger. And as software for controlling the hardware of the active discharger, a Raspberry Pi control device and a touch screen program were designed. The developed discharger is designed to change the 600W capacity battery in the form of active load.

Novel Silver(I) Ion Selective PVC Membrane Electrode Based on the Schiff Base (N2E,N2'E)-N2,N2'-Bis(Thiophen-2-ylmethylene)-1,1'-Binaphthyl-2,2'-Diamine

  • Jeong, Eunseon;Ahmed, Mohammad Shamsuddin;Jeong, Hae-Sang;Lee, Eun-Hee;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.800-804
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    • 2011
  • A potentiometric sensor based on the Schiff base $(N^2E,N^{2'}E)-N^2,N^{2'}$-bis(thiophen-2-ylmethylene)-1,1'-binaphthl-2,2'-diamine has been synthesized and explored as an ionophore PVC-based membrane sensor selective for the silver ($Ag^+$) ion. Potentiometric investigations indicate a high affinity of this receptor for the silver ion. Seven membranes have been fabricated with different compositions, with the best performance shown by the membrane with an ionophore composition (w/w) of: 1.0 mg, PVC: 33.0 mg, DOA: 66.0 mg in 1.0 mL THF. The sensor worked well within a wide concentration range of $1.0{\times}10^{-2}$ to $1.0{\times}10^{-7}$ M, at pH 5, at room temperature (slope 57.4 mV/dec.), and with a rapid response time of 9 s; the sensor also showed good selectivity towards the silver ion over a huge number of interfering cations, with the highest selectivity coefficient for $Hg^{2+}$ at -3.7. Thus far, the best lower detection limit was $4.0{\times}10^{-8}$ M.

Luminescence Intensity Change Using N-Carbamoylglycine, N-Salicylideneaniline and Metal ions (N-Carbamoylglycine 및 N-Salicylideneaniline과 Metal ions들에 의한 발광 세기의 변화)

  • Kim, Ji Ung;Kim, Yeong Hae
    • Journal of the Korean Chemical Society
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    • v.46 no.6
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    • pp.502-508
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    • 2002
  • We have used PET chemosensors in the determination of N-carbamoylglycine. When N-carbam-oylglycine reacts with complex already made by the fluorophore and metal ion, the luminescence intensity can be changed and this phenomenon can be utilized in quantification. We used three metal ions, $Zn^{2+}$, $Ni^{2+}$, $Cu^{2+}$ and in order to investigate selectivity an acetic acid was used. $Ni^{2+}$ ion showed change in the eT mechanism by the anions. $Cu^{2+}$ ion showed the ability to distinguish N-carbamoylglycine from an acetic acid and it is noteworthy that $Zn^{2+}$ ion can change luminescence sensitively according to concentration.

Optical Probe for Determination of Chromium(III) Ion in Aqueous Solution Based on Sol-Gel-Entrapped Lucigenin Chemiluminescence

  • Li, Ming;Kwak, Jun-Hee;Kim, Chang-Jin;Lee, Sang-Hak
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.103-108
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    • 2003
  • A method to determine chromium(III) ion in aqueous solution by chemiluminescence method using a lucigenin entrapped silica sol-gel film has been studied. An optical probe for chromium(III) ion has been prepared by entrapping lucigenin into silica sol-gel film coated on a glass support by dip coating. The chromium(III) optical sensor is based on the catalytic effect of chromium(IIII) ion on the reaction between lucigenin and hydrogen peroxide in basic solutions. The effects of Nafion, DMF and Triton X-100 were investigated to find the optimum condition to minimize cracking and leaching from the probe. The effects of pH and concentrations of lucigenin and hydrogen peroxide on the chemiluminescence intensity were investigated. The chemiluminescence intensity was increased linearly with increasing chromium(III) concentration from $2.5{\times}10^{-4}$M to $8.0{\times}10^{-7}$M and the detection limit was $4.0{\times}10^{-7}$M.

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Development of a New Copper(II) Ion-selective Poly(vinyl chloride) Membrane Electrode Based on 2-Mercaptobenzoxazole

  • Akhond, Morteza;Ghaedi, Mehrorang;Tashkhourian, Javad
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.882-886
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    • 2005
  • Copper(II) ion-selective PVC membrane electrode based on 2-mercaptobenzoxazole as a new ionophore and o-nitrophenyl octyl ether (o-NPOE) as plasticizer is proposed. This electrode revealed good selectivity for $Cu^{2+}$ over a wide variety of other metal ions. Effects of experimental parameters such as membrane composition, nature and amount of plasticizer, and concentration of internal solution on the potential response of $Cu^{2+}$ sensor were investigated. The electrode exhibits good response for $Cu^{2+}$ in a wide linear range of 5.0 ${\times}$ 10−.6-1.6 ${\times}$ $10^{-2}$ mol/L with a slope of 29.2 ${\pm}$ 2.0 mV/decade. The response time of the sensor is less than 10 s, and the detection limit is 2.0 ${\times}$ $10^{-6}$ mol/L. The electrode response was stable in pH range of 4-6. The lifetime of the electrode was about 2 months. The electrode revealed comparatively good selectivities with respect to many alkali, alkaline earth, and transition metal ions.