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http://dx.doi.org/10.5012/jkcs.2002.46.6.502

Luminescence Intensity Change Using N-Carbamoylglycine, N-Salicylideneaniline and Metal ions  

Kim, Ji Ung (Department of Applied Chemistry, Seokyeong University)
Kim, Yeong Hae (Department of Applied Chemistry, Seokyeong University)
Publication Information
Journal of the Korean Chemical Society / v.46, no.6, 2002 , pp. 502-508 More about this Journal
Abstract
We have used PET chemosensors in the determination of N-carbamoylglycine. When N-carbam-oylglycine reacts with complex already made by the fluorophore and metal ion, the luminescence intensity can be changed and this phenomenon can be utilized in quantification. We used three metal ions, $Zn^{2+}$, $Ni^{2+}$, $Cu^{2+}$ and in order to investigate selectivity an acetic acid was used. $Ni^{2+}$ ion showed change in the eT mechanism by the anions. $Cu^{2+}$ ion showed the ability to distinguish N-carbamoylglycine from an acetic acid and it is noteworthy that $Zn^{2+}$ ion can change luminescence sensitively according to concentration.
Keywords
N-carbamoylglycine; PET sensor; N-carbamoylglycine; PET sensor; Luminescence;
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