• Title/Summary/Keyword: Ion mixing

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Nonlinear Optical Properties of Eosin-Doped Boric Acid Glass (Eosin을 첨가한 Boric-Acid Glass의 비선형 광학적 특성)

  • 유연석
    • Korean Journal of Optics and Photonics
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    • v.2 no.3
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    • pp.133-138
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    • 1991
  • Eosin-doped boric acid glass saturable absorber has a relatively low saturation intensity (700 mW/$\textrm{cm}^2$) and low power optical phase conjugation is achived by the degenerate four-wave mixing (DFWM) experiments. Polarization properties of optical phase conjugation by DFWM have been demonstrated in this materials using a cw argon ion laser at wavelength 488 nm. The dependence of the phase conjugated reflectivity on the intensity and wavelength of the pump beam is examined. The magnitude of the energy exchange by the nondegenerate two-wave mixing (NDTWM) is maximized by frequency difference between the two beams of $\varphi\simeq$ 1100 Hz.

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Management of Spent Ion-Exchange Resins From Nuclear Power Plant by Blending Method

  • Kamaruzaman, Nursaidatul Syafadillah;Kessel, David S.;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.65-82
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    • 2018
  • With the significant increase in spent ion-exchange resin generation, to meet the requirements of Waste Acceptance Criteria (WAC) of the Wolsong disposal facility in Korea, blending is considered as a method for enhancing disposal options for intermediate level waste from nuclear reactors. A mass balance formula approach was used to enable blending process with an appropriate mixing ratio. As a result, it is estimated around 44.3% of high activity spent resins can be blended with the overall volume of low activity spent resins at a 1:7.18 conservative blending ratio. In contrast, the reduction of high activity spent resins is considered a positive solution in reducing the amount of spent resins stored. In an economic study, the blending process has been proven to lower the disposal cost by 10% compared to current APR1400 treatment. Prior to commencing use of this blending method in Korea, coordinated discussion, and safety and health assessment should be undertaken to investigate the feasibility of fitting this blending method to national policy as a means of waste predisposal processing and management in the future.

Adsorption Characteristics of U ranium (VI) Ion on Cryptand Synthetic Resin Adsorbent

  • Kim, Hae-Jin
    • Journal of Integrative Natural Science
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    • v.10 no.4
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    • pp.225-231
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    • 2017
  • Cryptand resins were synthesized by mixing 1-aza-18-crown-6 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 5%, and 10% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > calcium ($Ca^{2+}$) > neodymium ($Nd^{3+}$) ion, adsorbability of the uranium ion was the crosslink in order of 1%, 2%, 5%, and 10% and it was increased with the lower dielectric constant.

The Analysis of Chloride Ion Penetration into a Concrete Structure in Marine Environment (해안환경하에 있는 콘크리트의 염분침투해석)

  • Cho, Sun-Kyu;Jeon, Gui;Shin, Chee-Burm
    • Journal of Ocean Engineering and Technology
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    • v.12 no.3 s.29
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    • pp.68-74
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    • 1998
  • An increase of concrete construction in marine environments as well as an increasing use of marine aggregate at the mixing stage of concrete has provoked an important problem. A high concentration of chloride ion in the vicinity of steel bars in concrete is the principal cause of premature reinforcement corrosion in concrete structures. In this study, the behavior of chloride ions introduced into concrete from concrete surface by marine evironment was analysed. A mathematical model including the diffusion of chloride ion in aqueous phase of pores, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete and the chemical reactions of chloride ions with solid phase was presented. Finite element method was employed to carry out numerical analysis. The results of this study may be used to predict the onset of reinforcement corrosion and to identify the maximum limit of chloride ions contained in concrete admixtures.

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An Experimental Study on the Compressive Strength and Chloride ion penetration resistance of Cement Mortar mixing Anion Exchange Resin (음이온교환수지 혼입 시멘트 모르타르의 압축강도 및 염소이온 침투 저항성에 관한 실험적 연구)

  • Jung, Do-Hyun;Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.23-24
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    • 2018
  • Reinforced concrete is a building material that is generally used in modern society. Also, reinforced concrete structures in high salinity environments have low durability due to corrosion of reinforcing bars due to infiltrated chlorine ions. Anion exchange resins have an ability to immobilize chlorine ions in the resin while releasing their anions. As a material, it has already been shown that it is possible to fix the chloride ion inside the cementitious material through the cement mortar experiment. The purpose of this study is to confirm the compressive strength of cement mortar using powdered anion exchange resin after powdering an anion exchange resin. In order to confirm the chloride ion fixation ability of the powder anion exchange resin, chlorine ion penetration resistance test was carried out.

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A Study on the Effects of Concrete Mixing Properties on Chloride Diffusion Coefficients (콘크리트의 배합특성이 염화물 확산계수에 미치는 영향에 관한 연구)

  • 김도겸;박승범;조광연;이종석;김성욱
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.747-750
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    • 1999
  • Chloride ions are considered to be the major cause of steel corrosion in concrete structures exposed to seashore environments. Thus, estimating chloride ion concentrations by ages is needed to predict service life of seashore structures. Experimentally measured chloride profiles were used in this study for estimating chloride diffusion coefficients, and a relationship between mixing properties and chloride diffusion coefficients is proposed for predicting chloride penetrations.

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