• Title/Summary/Keyword: Ion components

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Determination of lead content in the plastic by ICP and AAS using HI reduction - PbSO4 dissolution method (HI 환원-PbSO4용해법을 이용한 ICP와 AAS에 의한 플라스틱 중의 납 정량 방법)

  • Lee, Hyun-Ja;Kim, Sang-Kyung;Lee, Se-Jin;Lee, Hyun-A
    • Analytical Science and Technology
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    • v.17 no.5
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    • pp.369-374
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    • 2004
  • Plastic was decomposed with nitric acid after being carbonized by sulfuric acid. Then excess sulfuric acid and nitric acid was removed by evaporating and drying. Precipitated $SO{_4}^{-2}$ ion of $PbSO_4$ was resolved itself into $H_2S$ by HI in hydrochloric acid and was volatilized. Then $Pb^{+2}$ was dissolved and was measured by AAS and ICP. The test for reproducibility using PVC-Pb standard material (690-34610mg/kg) was conducted and the accuracy was more than 99.9% compared with the estimated concentration. The precision by AAS was 99.8% and that of ICP was 99.9%.

Comparison of Quality Attributes of Korean Native-Bee Honey and Foreign-Bee Honey by K/Na Ratio (K/Na Ratio를 이용한 토종꿀과 양봉꿀의 품질 특성 비교)

  • 김은선;이종욱
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.4
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    • pp.672-679
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    • 1996
  • In order to examine the quality attributes of native-bee honey, proximate composition and mineral components were analysed by atomic absorption spectrometry, ion chromatography and high performance liquid chromatography. The analytical results showed that native-bee honey is higher in the contents of crude ash, crude protein and diastase activity than those of foreign-bee honey. The principal mineral components of honey were Ca, Mg, Na, K and Cl, which showed that almost all the mineral components were contained higher in the native-bee honey than the foreign-bee honey samples. When we calculated K/Na ratio, we could make a clear distinction between native-bee honey and foreign-bee honey. The K/Na ratio turned out to be more than 10 in 6 samples of native-bee honey, whereas the ratio of foreign-bee honey showed up less than 1.5 in all 3 samples.

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Studies on the Volatile Components of Platycodon grandiflorus (jacquin) A.De Candolle (도라지의 휘발성분에 관한 연구)

  • Sun, Woo-Sun;Kwon, Jae-Sang;Shin, Pyung-Gyun;Cho, Sung-Hwan;Chung, Jin-Hwan
    • Applied Biological Chemistry
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    • v.39 no.6
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    • pp.517-520
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    • 1996
  • To identify the volatiles of Platycodon roots, the three-year-old and the 24-year-old Platycodon roots cultivated in a local farm were extracted with ethyl ether by SDE method. 54.71mg% and 80.01mg% of volatile components were collected in the three-year-old and in 24-year-old Platycodon roots, respectively. As a result of GC/MS(TIC) analysis, 24 and 28 compounds were identified, respectively; The amounts of volatile components such as hexanol, trans-2-hexenol and nonanal in 24-year-old roots were detected above ten times than those in 3-year-old roots. The Volatiles of 24-year-old roots were fractionated by SCC and identified by GC/MS to be 10 hydrocarbons, 8 alcohols, 10 aldehydes, 5 esters, 6 acids and 1 unknown compound as the major components. The species and total amounts of volatile component in 24-year-old Platycodon roots were considered to be higher than those in 3-year-old Platycodon roots. *Abbreviations 1. Platycodon : platycodon grandiflorus (jacquin) A. De Candolle. 2. SDE : Simultaneous Distillation Extraction 3. SCC : Silicagel Column Chromatography 4. GC : gas chromatography 5. GC/MS : Gas Chromatography-Mass Spectrometer 6. TIC : Total Ion Chromatogoraphy

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A New Insight of Salt Stress Signaling in Plant

  • Park, Hee Jin;Kim, Woe-Yeon;Yun, Dae-Jin
    • Molecules and Cells
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    • v.39 no.6
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    • pp.447-459
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    • 2016
  • Many studies have been conducted to understand plant stress responses to salinity because irrigation-dependent salt accumulation compromises crop productivity and also to understand the mechanism through which some plants thrive under saline conditions. As mechanistic understanding has increased during the last decades, discovery-oriented approaches have begun to identify genetic determinants of salt tolerance. In addition to osmolytes, osmoprotectants, radical detoxification, ion transport systems, and changes in hormone levels and hormone-guided communications, the Salt Overly Sensitive (SOS) pathway has emerged to be a major defense mechanism. However, the mechanism by which the components of the SOS pathway are integrated to ultimately orchestrate plant-wide tolerance to salinity stress remains unclear. A higher-level control mechanism has recently emerged as a result of recognizing the involvement of GIGANTEA (GI), a protein involved in maintaining the plant circadian clock and control switch in flowering. The loss of GI function confers high tolerance to salt stress via its interaction with the components of the SOS pathway. The mechanism underlying this observation indicates the association between GI and the SOS pathway and thus, given the key influence of the circadian clock and the pathway on photoperiodic flowering, the association between GI and SOS can regulate growth and stress tolerance. In this review, we will analyze the components of the SOS pathways, with emphasis on the integration of components recognized as hallmarks of a halophytic lifestyle.

Rancidity Analysis of Rapeseed Oil under Different Storage Conditions Using Mass Spectrometry-based Electronic Nose (질량분석기 기반-전자코를 이용한 저장중 유채유의 산패 분석)

  • Hong, Eun-Jeung;Lim, Chae-Lan;Son, Hee-Jin;Choi, Jin-Young;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.42 no.6
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    • pp.699-704
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    • 2010
  • Rapeseed oil was stored under different conditions such as in the dark, with UV treatment, and with prooxidantscytochrome C and copper ion. The rapeseed oils stored at different temperatures were analyzed by a mass spectrometrybased electronic nose and discriminant function analysis (DFA). Volatile components in the rapeseed oil increased with storage time, and the discriminant function first score (DF1) moved from a positive position to a negative position as storage time increased. Changes in DF1 were higher under UV treatment than under the dark condition (DF1: $r^2$=0.9481, F=307.03). The different DF1 values (F1) under the dark condition were 0.099, 0.187, and 0.278 as storage temperature increased. The different values under UV treatment were 0.554, 0.588, and 0.542, as storage temperature increased from 4 to $26^{\circ}C$. As concentrations of prooxidants copper ion and cytochrome C increased, amounts of volatile components also increased. These were confirmed by DFA. Furthermore, changes in responses at each ion fragment agreed with reported results for GC/MS, which formed after rancidity of the oil, including pentane, pentanal, 1-pentanol, hexanal, n-octane, 2-hexenal, heptanal, 2-heptenal, decane, 2-octenal, undecane, and dodecane.

Simultaneous Analyses for Trace Multi-Odorous and Volatile Organic Compounds in Gas using a Triple-bed Adsorbent Tube (Triple-bed Adsorbent Tube를 이용한 가스상 극미량 복합 악취 및 휘발성 유기화합물의 동시 분석)

  • Seo, Yong Soo;Lee, Jea Keun
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.244-252
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    • 2010
  • The objective of this study is to assess feasibility of simultaneous analysis for trace multi-components odorous and volatile organic compounds using a Triple-bed adsorbent tube with a thermal desorber and GC-MS. Triple-bed adsorbent tube is 3 bed packed Tenax-TA with small amount of Carbopack B and Carbosieve SIII in order of adsorption strength in a tube. The operating conditions of GC-MS was possibly able to and effectively detect high volatile and low molecular weight compounds at the mass range of 20~350 m/z using a below impurity 1ppm of Helium carrier gas, of which quantitatively analyzed by target ion extracts. According to the experiment, $C_1{\sim}C_5$ of 14 components; sulfur containing compounds(2), ketones(2), alcohols(4) and aldehydes(6) were simultaneously analyzed with recoveries of 99%, and good repeatability and linearity. High volatile and low molecular weight compounds such as methyl alcohol and acetaldehyde can be safely quantified with high recovery at a condition of 50mL/min of flow rate, below 2L of adsorption volume, and 45% of relative humidity. Target ion extract can also simultaneously quantify multicomponents with odorous and volatile organic compounds in an occasion of piled up two peaks.

Modeling of the Thermal Behavior of a Lithium-Ion Battery Pack (리튬 이온 전지 팩의 열적 거동 모델링)

  • Yi, Jae-Shin
    • Journal of Energy Engineering
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    • v.20 no.1
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    • pp.1-7
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    • 2011
  • The performance and life-cycle costs of electric vehicle(EV) and hybrid electric vehicle(HEV) depend inherently on battery packs. Temperature uniformity in a pack is an important factor for obtaining optimum performance for an EV or HEV battery pack, because uneven temperature distribution in a pack leads to electrically unbalanced battery cells and reduced pack performance. In this work, a three-dimensional modeling was carried out to investigate the effects of operating conditions on the thermal behavior of a lithium-ion battery pack for an EV or HEV application. Thermal conductivities of various compartments of the battery were estimated based on the equivalent network of parallel/series thermal resistances of battery components. Heat generation rate in a cell was calculated using the modeling results of the potential and current density distributions of a battery cell.

Studies on the Diuretic Action of Oryeongsan and Kami-Oryeongsan (오령산(五笭散) 및 가미오령산(加味五笭散)이 가토이뇨작용(家兎利尿作用)에 미치는 영향(影響))

  • Lee, Sang-In
    • Korean Journal of Pharmacognosy
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    • v.12 no.1
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    • pp.31-43
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    • 1981
  • In order to determine the effect of Oryeongsan reputed to have diuretic action since Han Dynasty and possible synergetic action of Dianthi Semen, Polygonum avicularis Herba, Kochiae Fructus and Akebiae Lignum, herbs with similar reputation, when added to the above prescription, their decoction powders were solved into distilled water and injected into rabbits through the ear vein. Upon the treatment, the excretion of sodium, potassium and chloride ion together with urine volume was kinetically determined. At the same time the clearance of plasma creatinine and sodium ion was determined and the following results were obtained. Every experimental group demonstrated diuretic action, though feable, of relatively long duration. The diuretic mechanism in the case of Oryeongsan made up by mixing the seperate extracts of individual components and Oryeongsan(A) plus Dianthi Semen was found to be inhibitory effect of renal tubular reabsorption in contrast to the case of Oryeongsan(A) plus Polygonum avicularis Herba, Kochiae Fructus or Akebiae Lignum in which case the diuretic mechanism was found to be glomerular vascular dilatation. The urinary excretion of potassium ion was increased in the case of Oryeongsan(A) plus Dianthi Semen, Kochiae Fructus of Akebiae Lignum whereas in the other cases no similar change was registered. The diuretic action was most remarkable in the case of Oryeongsan(A) plus Polygonum avicularis Herba followed by Oryeongsan(A) plus Kochiae Fructus, Oryeongsan(A) plus Dianthi Semen, extract mixture of individual component of Oryeongsan, Oryeongsan(A) and Oryeongsan(A) plus Akebiae Lignum decreasing order. The duration of diuretic action was found to be 90 minutes in the case of Oryeongsan and mixture of individual component of Oryeongsan, and 60 minutes in the case of Oryeongsan(A) plus Dianthi Semen, Kochiae Fructus or Akebiae Lignum in contrast to the case of Oryeongsan(A) plus Polygonum avicularis Herba which lasted up to 120 minutes.

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Fabrication and Ion Irradiation Characteristics of SiC-Based Ceramics for Advanced Nuclear Energy Systems (차세대 원자력 시스템용 탄화규소계 세라믹스의 제조와 이온조사 특성 평가)

  • Kim, Weon-Ju;Kang, Seok-Min;Park, Kyeong-Hwan;Kohyama Akira;Ryu, Woo-Seog;Park, Ji-Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.575-581
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    • 2005
  • SiC-based ceramics are considered as candidate materials for the advanced nuclear energy systems such as the generation IV reactors and the fusion reactors due to their excellent high-temperature strength and irradiation resistance. The advanced nuclear energy systems and their main components adopting ceramic composites were briefly reviewed. A novel fabrication method of $SiC_f/SiC$ composites by introducing SiC whiskers was also described. In addition, the charged-particle irradiation ($Si^{2+}$ and $H^{+}$ ion) into CVD SiC was carried out to simulate the severe environments of the advanced nuclear reactors. SiC whiskers grown in the fiber preform increased the matrix infiltration rate by more than $60\%$ compared to the conventional CVI process. The highly crystalline and pure SiC showed little degradation in hardness and elastic modulus up to a damage level of 10 dpa at $1000^{\circ}C$.

Research Trend of Electrolyte Materials for Lithium Rechargeable Batteries (리튬 2차전지용 전해질 소재의 개발 동향)

  • Lee, Young-Gi;Kim, Kwang-Man
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.242-255
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    • 2008
  • In lithium-ion batteries(LIB), the development of electrolytes had mainly focused on the characteristics of lithium cobalt oxide($LiCoO_2$) cathode and graphite anode materials since the commercialization in 1991. Various studies on compatibility between electrode and electrolytes had been actively developed on their interface. Since then, as they try to adopt silicon and tin as anode materials and three components(Ni, Mn, Co), spinel, olivine as cathode materials for advanced lithium batteries, conventional electrolyte materials are facing a lot of challenges. In particular, requirements for electrolytes performance become harsh and complicated as safety problems are seriously emphasized. In this report, we summarized the research trend of electrolyte materials for the electrode materials of lithium rechargeable batteries.