• Title/Summary/Keyword: Ion balance

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A Study on the Performance Evaluation of Double-Layered Catayst MEA (이중촉매 MEA의 성능평가에 관한 연구)

  • Kim Hong-Gun;Kang Sung-Soo;Kwac Lee-Ku;Kang Young-Woo
    • New & Renewable Energy
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    • v.2 no.2 s.6
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    • pp.50-59
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    • 2006
  • An experimental and numerical study is carried out to investigate the performance and the efficiency humidifying Membrane Electrolyte Assembly and having the double-layered catalyst in a fuel cell system which is taken into account the physical and thermal concept. Based on the principals of the problem, the equation of electronic charge conservation equation, gas-phase continuity equation, and mass balance equation are used for the numerical calculation. A unit cell for $200cm^2$ MEA is assembled and measured for finding better operational situation. After finding the optimal condition, 10 cell stacked PEMFC is fabricated. For the performance evaluation, V-I and power curves are examined in detail by changing the condition of humidity, temperature, pressure, thickness of catalyst and oxidant. It is found that the power is maximized around 500W at 80A.

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Improvement of the DAWAST Model (DAWAST 모형의 개선)

  • Lee, Jae-Myun;Kim, Tai-Cheol
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.249-252
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    • 2002
  • This model is the daily streamflow model of the Korean watersheds has been developed to simulate the daily streamflow with the data of daily rainfall and pan evaporation. Parameters of this model are the water balance parameters composed Umax, Lmax, FC, CP, and CE and the routing parameters composed $U_i,\;k_1\;and\;k_2$. Among these parameters, CE value is applied one fixed value during the year and coefficient of initial ion K is empirically determined by 0.2. The object of this research is to improve the DAWAST model by application of the monthly value of CE for evapotranspiration and the revised K value for the initial abstraction.

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Oxidation Resistance and Preferred Orientation of TiAIN Thin Films (TiAIN 박막의 우선방위와 내산화성)

  • Park, Yong-Gwon;Park, Yong-Gwon;Wey, Myeong-Yong
    • Korean Journal of Materials Research
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    • v.12 no.8
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    • pp.676-681
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    • 2002
  • Microstructure, mechanical properties, and oxidation resistance of TiAIN thin films deposited on quenched and tempered STD61 tool steel by arc ion plating were studied using XRD, XPS and micro-balance. The TiAIN film was grown with the (200) orientation. The grain size of TiAIN thin film decreased with increasing Al contents, while chemical binding energy increased with Al contents. When hard coating films were oxidized at $850^{\circ}C$ in air, oxidation resistance of both TiN and TiCN films became relatively lower since the surface of films formed non-protective film such as $TiO_2$. However, oxidation resistance of TiAIN film was excellent because its surface formed protective layer such as $_A12$$O_3$ and $_Al2$$Ti_{7}$$O_{15}$, which suppressed oxygen intrusion.

Knockdown of cytosolic NADP+-dependent isocitrate dehydrogenase enhances MPP+-induced oxidative injury in PC12 cells

  • Yang, Eun-Sun;Park, Jeen-Woo
    • BMB Reports
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    • v.44 no.5
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    • pp.312-316
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    • 2011
  • 1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP) and its toxic metabolite 1-methyl-4-phenylpyridium ion (MPP$^+$) have been shown to induce Parkinson's disease-like symptoms as well as neurotoxicity in humans and animal species. Recently, we reported that maintenance of redox balance and cellular defense against oxidative damage are primary functions of the novel antioxidant enzyme cytosolic NADP$^+$-dependent isocitrate dehydrogenase (IDPc). In this study, we examined the role of IDPc in cellular defense against MPP$^+$-induced oxidative injury using PC12 cells transfected with IDPc small interfering RNA (siRNA). Our results demonstrate that MPP$^+$-mediated disruption of cellular redox status, oxidative damage to cells, and apoptotic cell death were significantly enhanced by knockdown of IDPc.

Quench characteristics of thin film type SFCLs with shunt layers of various thickness (션트박막 두께에 따른 박막형 초전도 한류소자의 ?치특성)

  • 김혜림;이승엽;차상도;최효상;현옥배
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.02a
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    • pp.51-54
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    • 2003
  • We investigated the quench characteristics of thin film type SFCLs with shunt layers of various thickness. The SFCLs ware based on 2 inch diameter YBa$_2$Cu$_3$O$_{7}$ thin films coated in-situ with a gold shunt layer. The shunt layer thickness was varied by Ar ion milling. The limiters were tested with simulated fault currents at various source voltages. The thinner the shunt layer was, the slower was the rise of SFCL temperatures. This means SFCLs of thinner shunt layers had higher voltage ratings. The voltage rating was approximately inversely proportional to the square root of the shunt layer thickness. This result could be understood through the concept of heat balance.e.

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Quench characteristics of thin film type SFCLs with shunt layers of various thickness (션트박막 두께에 따른 박막형 초전도 한류소자의 ?치특성)

  • 김혜림;이승엽;차상도;최효상;현옥배
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.02a
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    • pp.242-245
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    • 2003
  • We investigated the quench characteristics of thin film type SFCLs with shunt layers of various thickness. The SFCLs ware based on 2 inch diameter YBa$_2$Cu$_3$3O$_{7}$ thin films coated in-situ with a gold shunt layer. The shunt layer thickness was varied by Ar ion milling. The limiters were tested with simulated fault currents at various source voltages. The thinner the shunt layer was, the slower was the rise of SFCL temperatures. This means SFCLs of thinner shunt layers had higher voltage ratings. The voltage rating was approximately inversely proportional to the square root of the shunt layer thickness. This result could be understood through the concept of heat balance.e.

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Study on the Coordination Polymers of Metal (II) Ions with 2,5-Diamine 1,4-Dihydroxybenzene (2,5-Diamine 1,4-Dihydroxybenzene과 금속 (II) 이온이 만드는 Coordination Polymer에 관하여)

  • Joon Suk Oh;Kyun Ok Cho
    • Journal of the Korean Chemical Society
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    • v.13 no.4
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    • pp.309-312
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    • 1969
  • A series of metal ion-2, 5-diamine 1, 4-dihydroxybenzene polymers containing copper(II), nickel(II) or cobalt (II) have been prepared. The structure was postulated on the basis of elementary analysis of polymers. It was found that copper polymer is most likely the coordination polymers by X-ray powder pattern studies. The thermal stability of the polymers was also studied by a simple method, utilizing a thermogravimetric balance. The order of thermal stabilities is Cu(II) > Ni(II) > Co(II). The polymers start to decompose at a relatively low temperature.

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Characteristics of Son Concentrations of PM2.5 Measured at Gosan: Measurement Data between 1998 and 2002 (고산에서 측정한 PM2.5 이온 농도 특성: 1998~2002년 측정자료)

  • 김나경;김용표;강창희;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.3
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    • pp.333-343
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    • 2003
  • The aerosol ionic composition of P $M_{2.5}$ measured at Gosan, Jeju Island, Korea, for 4 years between March 1998 and February 2002 are presented and discussed. The annual mean concentration of non- sea-salt sulfate (nss -S $O_4$$^{2-}$) and ammonium (N $H_4$$^{+}$) ions are high (0.094 $\mu$eq/㎥, and 0.085 $\mu$eq/㎥, respectively). Also, nss-S $O_4$$^{2-}$ and N $H_4$$^{+}$ show high correlation (0.892). The concentrations of most ions are high in springtime. As the result of factor analysis, Gosan area mainly affected by sea-salt, anthropogenic species, and crustal species.ies.

Estimation of the Groundwater Recharge Rate during a Rainy Season at a Headwater Catchment in Gwangneung, Korea (광릉 원두부 소유역에서의 우기 중 지하수 함양률 평가)

  • Choi, In-Hyuk;Woo, Nam-Chil;Kim, Su-Jin;Moon, Sang-Ki;Kim, Joon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.2
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    • pp.75-87
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    • 2007
  • Groundwater recharge rates were estimated and compared in a headwater catchment at the Gwangneung Supersite using three different methods: water-table fluctuation (WTF), mass balance, and hydrograph separation techniques. Data were obtained during the rainy season from June to September 2005. Two different WTF methods estimated the groundwater recharge rate as 25.9% and 23.6%. The mass balance calculation of chloride ions indicated recharge rates of 13.4% on average. Baseflow separation using chloride ion as a tracer from six storm hydrographs produced a 14.0% net baseflow rate on average. Because of the implicit assumption of a long-term steady state without storage change, recharge rates calculated by mass balance and hydrograph separation were smaller than those done with WTF methods, which include the amount of increased storage due to the water-level rise. Subsequently, the WTF method is superior to others in the estimation of groundwater recharge rate to comprehend the dynamic characteristics of the hydrologic cycle.

Chemical Composition of Rainwater in Suwon and Ansung Area (수원과 안성지역 빗물의 화학성분 조성)

  • Lee, Jong-Sik;Kim, Bok-Young;Kim, Jin-Ho;Hong, Seung-Gil
    • Korean Journal of Environmental Agriculture
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    • v.18 no.2
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    • pp.169-173
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    • 1999
  • To investigate the chemical properties of rainwater in the southern part of gyeonggi Province, the rainwater was collected in Suwon and Ansung for six months from May to October in 1998, and analyzed its chemical composition. The ion balance and electric conductivity balance showed confidence to chemical analyses of rainwater. The most frequent pH range of rainwater was pH $5.0{\sim}5.6$ both in Suwon and Ansung area with distribution ratio of 37.9% and 35.3%, respectively. Among the 1mm fraction for initial 5mm of rainfall, ion concentration of initial rainwater (less than 1mm of rainfall) was higher than those of the later terms. The major ions in rainwater were $NH_4^-,\;Ca^{2+}$and $Na^+$ for cations, and $SO_4^{2-}$ and $NO_3^-$ for anions. Monthly variation of pH of rainwater showed low level of 4.2 to 4.5 in Suwon and 4.6 to 4.7 in Ansung in August and September, respectively. The $nss-SO_4^{2-}/NO_3^-$ ratio of rainwater in Suwon and Ansung area were 2.2 and 2.9 which means nonsea salt $SO_4^{2-}$ contrbuted to acidity of rainwater more in Ansung than Suwon area.

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