• Title/Summary/Keyword: Introduction Phase

검색결과 319건 처리시간 0.027초

Optimization of Solid Phase Extraction Method for Quantitative Analysis of Perfluorooctanoic Acid in Serum using Liquid Chromatography-Tandem Mass Spectrometry

  • Lee, Hyun-Seok;Yim, Yong-Hyeon
    • Mass Spectrometry Letters
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    • 제5권1호
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    • pp.30-33
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    • 2014
  • A solid phase extraction (SPE) method was optimized for the quantitative analysis of perfluorooctanoic acid (PFOA) in serum using hydrophilic-lipophilic balance SPE and LC-MS/MS. Fetal bovine serums spiked with $^{13}C_8$-PFOA before or after SPE were used as test samples for evaluation of the SPE efficiency. Simultaneous evaluation of matrix effects and absolute SPE recovery for $^{13}C_8$-PFOA in serum using different sample pre-treatments and SPE conditions allowed optimization of SPE process efficiency with minimal matrix effect and decent SPE recovery. Introduction of protein precipitation as a sample pre-treatment procedure for serum samples before SPE generally decreased matrix effect in LC-MS/MS analysis and provided more stable recovery of PFOA.

사성분계 시스템의 액액상분리에 관한 연구 (폴리술폰/폴리에테르술폰/NMP/물) (Liquid-Liquid Phase Separation in a Quaternary System of PolysuIfone/Polyethersulfone/N-Methyl-2-pyrrolidone/water)

  • 백기전;김제영;이환광;김성철
    • 한국막학회:학술대회논문집
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    • 한국막학회 1998년도 춘계 총회 및 학술발표회
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    • pp.22-24
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    • 1998
  • 1. INTRODUCTION : The phase inversion method is widely used to prepare a variety of polymeric membranes ranging from micro-filtration to gas separation. The final morphology obtained by immersion precipitation strongly reflects the thermodynamics and kinetics of the system involved. The equilibrium thermodynamics of the ternary system of polymer/solvent/ nonsolvent is still very important to understand and predict membrane structure. Polysulfone (PSf) and polyethersulfone (PES) are important polymers as membrane materials due to the chemical resistance, mechanical strength, thermal stability and transport properies. There are several reports on the experimental phase diagrams in ternary mixtures of PSf/solvent/nonsolvent, and PES/solvent/nonsolvent. It would be interesting to investigate the solution thermodynamics containing these two polymers since PES is slightly less hyclrophobic than PSf.

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플라즈마 용융법으로 제조된 Fe계 자성분말의 자기연마 특성 (Characteristics of Magnetic Polishing with Magnetic Abrasive Powder Fabricated by Plasma Melting Method)

  • 이영란;배승열;안인섭;이용철
    • 한국분말재료학회지
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    • 제8권1호
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    • pp.20-25
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    • 2001
  • Most of mold manufacturing procedures have been automated by the introduction of NC machine tool and CAD/CAM system. But the three-dimensional surface curvature of the mold must be done by hand work of well-skilled workers. Magnetic abrasive polishing powders were investigated for surface polishing for 3D curvature. This study aims to investigate homogeneously distributed hard phase in Fe matrix and strong bonding between Fe-matrix and hard phase. The NbC powder, $B_4C$ powder and $Al_2O_3$ powder were mixed in Fe-matrix respectively. Mixed Fe-hard phase powders were compacted by press and then these were melted by plasma melting. According to SEM, XRD and OM observation, Fe-NbC magnetic abrsive powder had the most homogeneous distribution and strong bonding. As a result of magnetic polishing, the surface roughness before magnetic polishing, 1 ${\mu}m$ $R_{max}$, was reduced to 0.2 ${\mu}m$ $R_{max}$ over the entire inner surface of the tube.

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Advances in Ion Mobility Spectrometry-Mass Spectrometry (IMS-MS)-Based Techniques for Elucidating Higher-Order Protein Structures

  • Seo, Jongcheol
    • Mass Spectrometry Letters
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    • 제11권4호
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    • pp.65-70
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    • 2020
  • Despite its great success in the field of proteomics, mass spectrometry has limited use for determining structural details of peptides, proteins, and their assemblies. Emerging ion mobility spectrometry-mass spectrometry has enabled us to explore the conformational space of protein ions in the gas phase, and further combinations with the gas-phase ion spectroscopy and the collision-induced unfolding have extended its abilities to elucidating the secondary structure and local details of conformational transitions. This review will provide a brief introduction to the combined approaches of IMS-MS with gas-phase ion infrared spectroscopy or collision-induced unfolding and their most recent results that successfully revealed higher-order structural details.

실내 수공간 도입에 따른 온열 환경 변화 분석 (Analysis of Thermo Environment Change by Introduction of Indoor Water Space)

  • 오상목;오세규
    • KIEAE Journal
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    • 제12권3호
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    • pp.53-60
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    • 2012
  • This research is an illustrative research to verify the thermo environmental change created after introduction of indoor pond through abridged model test and simulation analysis. Especially, temperature and comfort level are analyzed by adjusting factors like size of water space, distance length, and location. Summary of the research is as follows. First, the most effective size of water space is 7% of the indoor size, from southern side. Temperature reduction effect is about $1.6^{\circ}C$(5.5%), and for the comfort level, it is found that pmv index increases 8%. Second, based on the simulation of distance length with the sphere, it is more effective as it is close to the surface. If distance length is more than 0.5m, there is no effect on reduction of temperature and comfort level of indoor environment. Lastly, for the analysis by location of the introduced water space, simulation is undertaken by dividing the water space (14% of the indoor size) with front, side, rear and center types. Temperature reduction effect is found to be : front type ($-1.53^{\circ}C$), side type ($-0.82^{\circ}C$), rear type ($-0.44^{\circ}C$), center type ($-0.28^{\circ}C$), respectively. The indoor environment change data by introduction of water space, found in this research, is at initial phase, but it is deemed to be a basic data to refer when planning actual water space.

초등학교 저학년 학생들의 단계적 비유추론 학습과정을 통한 혼합물 학습 과정에서 제시된 생성적 비유의 특징 분석 (An Analysis of Features in Self Generated Analogies during Phaseal Teaching Learning Process about Mixture Using Analogy for Lower Elementary School Students)

  • 정진규;김영민
    • 한국초등과학교육학회지:초등과학교육
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    • 제34권4호
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    • pp.419-433
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    • 2015
  • Analogical reasoning is a central component of human cognition and contributes to scientific discovery and to develop science education. In this study, we investigated the process features of lower elementary school students' analogical reasoning to explain mixture concept. The subjects are 24 lower elementary students. And the research design includes three phases instruction to investigate the features of students' self generated analogy. Phase 1 is the introduction of analogy in which student learn to use analogy. Phase 2 is a POE class about mixture conception. Piaget and Inhelder studied the conception of mixing among children in relation to cognitive development. In phase 2, we taught the student with Piaget and Inhelder's the experiment and observed the features of learning process about mixture conception. Phase 3 is students' generation of analogy (self generated analogy) for the experienced phenomena in phase 2. We analyzed the students' responses through the three phases in the view of Gentner's Structure Mapping Theory. The results showed that many lower elementary school students even before formal operation stage understood the mixture conception and made well their self generated analogy to explain the mixture conception in spite of the difficulty of making self generated analogy.

$L1_2$${\gamma}^{\prime}-Ni_3(Al,Ti)$ 규칙상 중에 불규칙 ${\gamma}$상의 석출거동에 관한 연구 (A Study on the Precipitation Behavior of Disordered ${\gamma}$ Phase in an $L1_2$ Ordered ${\gamma}^{\prime}-Ni_3(Al,Ti)$ Phase)

  • 한창석
    • 열처리공학회지
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    • 제19권5호
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    • pp.249-256
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    • 2006
  • Structural studies have been performed on precipitation hardening found in $L1_2$ ordered ${\gamma}^{\prime}-Ni_3(Al,Ti)$ alloys using transmission electron microscopy. A uniform solid solution of ${\gamma}^{\prime}-L1_2$ ordered phase supersaturated with Ni can be obtained by solution annealing in a suitable temperature range. The ${\gamma}^{\prime}$ phase hardens appreciably by the fine precipitation of disordered ${\gamma}$. The shape of ${\gamma}$ precipitates formed during aging is initially spherical or round-cubic and grow into platelets as aging proceeds. High resolution electron microscopy revealed that the ${\gamma}$ precipitates are perfectly coherent with the matrix ${\gamma}^{\prime}$ as long as the ${\gamma}$-precipitates are plates. The loss of coherency initiates by the introduction of dislocations at the ${\gamma}/{\gamma}^{\prime}$ interface followed by the step formation at the dislocations. The ${\gamma}$ precipitates become globular after the loss of coherency. The strength of ${\gamma}^{\prime}-Ni_3(Al,Ti)$ increases over the temperature range of experiment by the precipitation of fine ${\gamma}$ particles. The peak temperature where a maximum strength was obtained shifted to higher temperature.

BIM 적용을 통한 소규모 건물 리모델링 시 현장시공관리 (The construction management of BIM-based small building remodeling.)

  • 정태호;김상원;박승환;홍성욱
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2012년도 춘계 학술논문 발표대회
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    • pp.191-192
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    • 2012
  • The BIM(Building Information Modeling) introduction of the construction and maintenance at the design phase through the life cycle of the building until it is destroyed, I will bring big changes in the process. If you are building a small action by a variety of variables difficult to manage on-site construction, but, BIM remodeling of the building by applying a small improvement in the quality of imported building and construction delays, such as design changes or re-construction by removing the elements of economic 04 to make. Since the early stages of applying BIM to complement the introduction part, but the future seems to lead to changes in the built environment, academics and practitioners of the construction industry seem to have an active research.

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수리계획법에 의한 대형시스템의 최적운용 앨고리즘 (Algorithm for optimum operation of large-scale systems by the mathematical programming)

  • 박영문;이봉용;백영식;김영창;김건중;김중훈;양원영
    • 전기의세계
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    • 제30권6호
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    • pp.375-385
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    • 1981
  • New algorithms are derived for nonlinear programming problems which are characterized by their large variables and equality and inequality constraints. The algorithms are based upon the introduction of the Dependent-Variable-Elimination method, Independent-Variable-Reduction method, Optimally-Ordered-Triangular-Factorization method, Equality-Inequality-Sequential-Satisfaction method, etc. For a case study problem relating to the optimal determination of load flow in a 10-bus, 13-line sample power system, several approaches are undertaken, such as SUMT, Lagrange's Multiplier method, sequential applications of linear and quadratic programming method. For applying the linear programming method, the conventional simplex algorithm is modified to the large-system-oriented one by the introduction of the Two-Phase method and Variable-Upper-Bounding method, thus resulting in remarkable savings in memory requirements and computing time. The case study shows the validity and effectivity of the algorithms presented herein.

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THE INTRODUCTION METHOD OF TECHNOLOGY MANAGEMENT IN THE OIL AND GAS PLANT INDUSTRY

  • Doo Hee Lee;Young Woong Song;Hyoung Chul Lim;Yoon Ki Choi
    • 국제학술발표논문집
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    • The 2th International Conference on Construction Engineering and Project Management
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    • pp.249-258
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    • 2007
  • Recently orders of projects in the field of oil and gas plants have increased due to rising oil prices and consumption. The markets of oil and gas plants are expanding into the Middle East area and all over the world. Because the oil and gas markets have a lot of overseas construction operations, competition among advanced companies is more important. However, companies in the period of growth have not had enough competitive powers of license in the design phase. Therefore, they are faced with difficulty of adopting the technology which is maximizing the effect of investments, and scheduling of a long-range plan. In order to achieve adequate technology management and competitive power, this study considers a long-range plan through an analysis of an appropriate introduction and the strategic planning process of technology management.

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