• 한국분말재료학회지
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• 제19권4호
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• pp.259-263
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• 2012

Dependence of the freeze-drying process condition on microstructure of porous W and pore formation mechanism were studied. Camphene slurries with $WO_3$ contents of 10 vol% were prepared by milling at $50^{\circ}C$ with a small amount of dispersant. Freezing of a slurry was done in Teflon cylinder attached to a copper bottom plate cooled at $-25^{\circ}C$. Pores were generated subsequently by sublimation of the camphene during drying in air for 48 h. The green body was hydrogen-reduced at $800^{\circ}C$ for 30 min, and sintered in the furnace at $900^{\circ}C$ for 1 h. After heat treatment in hydrogen atmosphere, $WO_3$ powders were completely converted to metallic W without any reaction phases. The sintered samples showed large pores with the size of about $70{\mu}m$ which were aligned parallel to the camphene growth direction. Also, the internal wall of large pores and near bottom part of specimen had relatively small pores with dendritic structure due to the growth of camphene dendrite depending on the degree of nucleation and powder rearrangement in the slurry.

• 한국물환경학회지
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• 제22권1호
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• pp.140-144
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• 2006

This study was performed to investigate the effect of organic characteristics and feed water solution chemistry on membrane fouling index such as Silt Density Index (SDI) and Modified Fouling Index (MFI). Specifically, Aldrich humic acids (AHA) and Suwannee river humic acids (SHA) were used in SDI/MFI experiments. Higher SDI values were observed with increasing organic concentration. AHA with larger molecular weight (MW) and SUVA (${\approx}UV_{254}/TOC$) resulted in higher SDI values, compared to SHA. The feed solution chemistry (i.e, pH, ionic strength, and hardness) also affects SDI values to some degree. In particular, SDI increased with increasing hardness ($Ca^{2+}$) concentration for AHA. Unlike SDI, the MFI developed on the basis of particle cake filtration theory, was not accurately assessed due to internal fouling by organics such as pore adsorption and subsequent pore blocking.

• 한국분말재료학회지
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• 제27권3호
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• pp.193-197
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• 2020

Porous Cu-14 wt% Co with aligned pores is produced by a freeze drying and sintering process. Unidirectional freezing of camphene slurry with CuO-Co₃O₄ powders is conducted, and pores in the frozen specimens are generated by sublimation of the camphene crystals. The dried bodies are hydrogen-reduced at 500℃ and sintered at 800℃ for 1 h. The reduction behavior of the CuO-Co₃O₄ powder mixture is analyzed using a temperature-programmed reduction method in an Ar-10% H₂ atmosphere. The sintered bodies show large and aligned parallel pores in the camphene growth direction. In addition, small pores are distributed around the internal walls of the large pores. The size and fraction of the pores decrease as the amount of solid powder added to the slurry increases. The change in pore characteristics according to the amount of the mixed powder is interpreted to be due to the rearrangement and accumulation behavior of the solid particles in the freezing process of the slurry.

• Geomechanics and Engineering
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• 제24권5호
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• pp.419-430
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• 2021

Investigation on the compressibility and shear strength of compacted loess is of great importance for the design and operation of engineering infrastructures in filling area. In this study, the mechanical behaviors of Yan'an compacted loess are investigated at various dry densities and water contents by conducting one dimensional compression and direct shear tests. And the elastic compressibility, plastic compressibility, yield stress and strength are obtained from the experiments. Results show that when water content increases, plastic compressibility parameter increases, but yield stress decreases. However, the increase of dry density leads to a decrease in plastic compressibility parameter but an increase in yield stress. In addition, elastic compressibility parameter is found to be a constant which is irrelevant to water content and dry density. As for strength, cohesion and internal friction angle is directly proportional to dry density, but inversely proportional to water content. Moreover, the mercury intrusion porosimetry (MIP) and scanning electron microscope (SEM) tests were also performed to observe the pore size distribution and microstructure of the specimens. Finally, by using results of MIP and SEM tests, the compressibility and strength behaviours of Yan'an compacted loess are explained from the perspective of pore-size distribution and microstructure.

• ALGAE
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• 제37권1호
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• pp.33-47
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• 2022

Two new species of Pseudostaurosiropsis are described based on material collected from rivers in southern United States of America, P. californicus sp. nov. and P. elaboratus sp. nov. Both species have specific characters that set them apart from taxa currently ascribed to the genus. Pseudostaurosiropsis californicus sp. nov. has lanceolate valves with subrostrate, broadly rounded apices, an axial area at the same level as the virgae in internal and external views and both are at the same level as striae in external view, the spine tips are dentate and their growth is produced by filamentous extensions, and it has equal-sized apical pore fields on both valve extremes. On the other hand, P. elaboratus sp. nov. has heavily silicified valves, the virgae are slender than the striae in outer view and wider in inner view, it only has a single, externally occluded apical pore field on one valve extreme, and the spines have a solid core. All species within Pseudostaurosiropsis are contrasted with one another and unique features are described for each based on literature and newly collected image data from type material. The genus is reconsidered and two distinguishing features are recognized: rotae externally occluding the areolae and areolae that are funnel-shaped. These features are contrasted with those in other genera and additional published species that should be included in Pseudostaurosiropsis are discussed.

• 한국세라믹학회지
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• 제42권1호
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• pp.37-42
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• 2005

유리연마슬러지와 graphite를 발포제로 사용하여 경량골재를 제조하였으며, 경량골재 내부기공과 물성과의 상관성을 도출하였다. 이때 graphite 함량을 각각 달리하여 성구를 제조하였으며, $700^{circ}C$ 및 $800^{circ}C$에서 20분 동안 소성하였다. 소성 전후 골제의 부피 변화를 검토한 결과, 발포제의 첨가량보다는 소성 온도가 즘 더 큰 영향을 미침을 확인하였다 기공의 크기 및 면적은 발포제 첨가량과 소성 온도 상승에 따라 증가하는 특징을 나타내었으나, 발포제 첨가량 $1\%$ 이상에서는 큰 폭의 증가를 동반하지 않았다. 흡수율/열전도율과 기공과의 상관성은 매우 높아, 각각의 상관관계계수는 $0.8\pm$ 이상을 나타내었다.

• 한국재료학회지
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• 제25권11호
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• pp.602-606
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• 2015

Porous W with spherical and directionally aligned pores was fabricated by the combination of sacrificial fugitives and a freeze-drying process. Camphene slurries with powder mixtures of $WO_3$ and spherical PMMA of 20 vol% were frozen at $-25^{\circ}C$ and dried for the sublimation of the camphene. The green bodies were heat-treated at $400^{\circ}C$ for 2 h to decompose the PMMA; then, sintering was carried out at $1200^{\circ}C$ in a hydrogen atmosphere for 2 h. TGA and XRD analysis showed that the PMMA decomposed at about $400^{\circ}C$, and $WO_3$ was reduced to metallic W at $800^{\circ}C$ without any reaction phases. The sintered bodies with $WO_3$-PMMA contents of 15 and 20 vol% showed large pores with aligned direction and small pores in the internal walls of the large pores. The pore formation was discussed in terms of the solidication behavior of liquid camphene with solid particles. Spherical pores, formed by decomposition of PMMA, were observed in the sintered specimens. Also, microstructural observation revealed that struts between the small pores consisted of very fine particles with size of about 300 nm.

• 청정기술
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• 제13권2호
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• pp.127-133
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• 2007

세라이트는 내부 공동이 매우 넓어서 그 내부에 다양한 분자성 물질을 저장할 수 있으며, 세라이트 분말은 PE 필름 내부에 잘 분산될 수 있어서 세라이트를 함유한 PE 필름을 제조할 수 있었다. 표면을 계면활성제로 처리하여 극성을 낮춘 세라이트를 함유한 PE 필름 그리고 표면 처리하지 않은 세라이트를 이용한 PE 필름 등 2 가지 필름을 제조하였다. 제조된 필름내부의 세라이트 내부 공동에는 방청물질인 dicyclohexylamine, dicyclohexylamine nitrite 또는 diisopropylamine 등이 스며들게 하여, 포함된 방청분자들이 서서히 외부로 방출되게 함으로서 필름 백 내부에 포장된 철물에 대한 방청효과를 지속적으로 발휘하도록 하였다. 여러가지 밀봉필름 백 내부의 방청물질 농도 변화를 gas chromatography를 이용하여 한 달간 각 필름 백의 방청물질 발산 지속기간을 비교하였고, 실제로 실험실에서 사용되는 철물을 대상으로 6 개월에 걸쳐 방청실험을 진행하였다. 실험 결과 세라이트 필름은 일반 PE 필름에 비해 방청효과가 뛰어나며, 방청물질 발산 지속기간이 우수하였다.

• 한국지반공학회논문집
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• 제27권11호
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• pp.93-101
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• 2011

X-ray micro-CT를 이용한 지반재료 내부 미세구조 및 공극구조의 정밀한 이미지 처리는 종종 이미지 내에 원천적으로 포함되는 화상결함으로 인해 제약된다. 본 논문에서는 X-ray micro-CT 이미지에 가장 일반적으로 나타나는 화상결함인 패임(영상 외곽과 중심부의 명암 차이) 및 동심원상(영상 중심으로부터 방사방향으로 연속적으로 나타나는 원)을 제거할 수 있는 이미지 보정 기법을 제시한다. 결함 제거는 좌표 변환법, 정규화 및 2차원 푸리에 변환에 의한 저역 통과 필터링 기법의 순차적 적용을 통해 이루어진다. 이미지 처리 기법의 효과를 다공성 현무암의 CT 이미지에서 화상결함들을 제거하고 이진화 후 적층하여 3차원 공극 구조를 추출하는 과정을 통해 설명하였다. 패임 및 동심원상 결함을 제거한 이미지와 원본 이미지의 비교 결과 결함 제거는 대상 재료 공극률의 과대평가를 방지할 수 있으며, 따라서 화상결함의 적절한 보정은 X-ray CT의 지반재료 적용 시 필수적인 과정으로 판단된다.

• 터널과지하공간
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• 제23권3호
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• pp.228-240
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• 2013

퇴적암에서 나타나는 이방성은 층리에 의한 영향이 크며, 암석의 수리적 특성에도 영향을 주게 된다. 본 연구에서는 층리가 발달한 다공질 사암을 대상으로, 층리구조에 의해 발생한 공극구조 이방성이 사암의 수리 이방성에 미치는 영향을 분석하였다. 사암의 공극구조 이방성 파악을 위해 X-ray CT(computed tomography)를 이용하여 내부 공극률의 변화양상을 분석하였다. 층리방향에 따른 수리이방성은 층리면과 수평면이 이루는 각도를 $0^{\circ}$에서 $90^{\circ}$까지 $15^{\circ}$간격으로 코어링한 샘플을 제작하여 투수실험을 통해 파악하였다. 투수실험 결과 층리면과 투수방향이 수직인 경우 투수율이 가장 작은 값을 나타낸 반면, 층리면과 투수방향이 평행일 때 가장 높은 투수율을 나타내었으며, 평균 수리이등방비($k_{90^{\circ}}/k_{0^{\circ}}$)가 1.8로 층리에 따른 수리 이방성이 확연하게 나타났다. 또한, 이러한 사암의 수리이방특성은 층리에 의해 공극특성이 서로 다른 층상구조가 형성되기 때문임을 확인하였다.