• Title/Summary/Keyword: Internal (gradient) structure

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Structure Optimization of Solute Molecules via Free Energy Gradient Method

  • Nagaoka, Masataka
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.805-808
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    • 2003
  • Fundamental ideas of the free energy gradient method are briefly reviewed with three applications: the stable structures of glycine and ammonia-water molecule pair in aqueous solution and the transition state (TS) structure of a Menshutkin reaction $NH_3 + CH_3Cl → CH_3NH_3^+ + Cl^-$ in aqueous solution, which is the first example of full TS optimization of all internal degrees of freedom.

The Internal Structure of an Identification Function in Korean Lexical Pitch Accent in North Kyungsang Dialect

  • Kim, Jungsun
    • Phonetics and Speech Sciences
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    • v.5 no.1
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    • pp.91-98
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    • 2013
  • This paper investigated Korean prosody as it relates to graded internal structure in an identification function. Within Korean prosody, variants regarded as dialectal variations can appear as different prosodic scales, which contain the range of within-category variations. The current experiment was intended to show how the prosodic scale corresponding to the range of within-category differences relates to f0 contours for speakers of two Korean dialects, North Kyungsang and South Cholla. In an identification task, participants responded by selecting an item from two answer choices. The probability of choosing the correct response from the two choices was computed by a logistic regression analysis using intercepts and slopes. That is, the correct response between two choices was used to show a linear line with an s-shape presentation. In this paper, to investigate the graded internal structure of labeling, 25%, 50%, and 75% of predicted probability were assessed. Listeners from North Kyungsang showed progressive variations, whereas listeners from South Cholla revealed random patterns in the internal structure of the identification function. In this paper, the results were plotted using scatterplot graphs, applying the range of within-category variation and predicted probability obtained from the logistic regression analyses. The scatterplot graphs showed the different degree of the responses for f0 scales (i.e., variations within categories). The results demonstrate that the gradient structures of native pitch accent users become more progressive in response to f0 scales.

Thermomechanical Analysis of Functionally Gradient Al-$SiC_{p}$ Composite for Electronic Packaging (전자패키지용 경사조성 Al-$SiC_{p}$ 복합재료의 열 . 기계적 변형특성 해석)

  • 송대현;최낙봉;김애정;조경목;박익민
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.175-183
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    • 2000
  • The internal residual stresses within the multilayered structure with shan interface induced by the difference in thermal expansion coefficient between the materials of adjacent layers often provide the source of failure such as delamination of interfaces and etc. Recent development of the multilayered structure with functionally graded interface would be the solution to prevent this kind of failure. However a systematic thermo-mechanical analysis is needed fur the customized structural design of multilayered structure. In this study, theoretical model for the thermo-mechanical analysis is developed for multilayered structures of the Al-$SiC_p$ functionally graded composite for electronic packaging. The evolution of curvature and internal stresses in response to temperature variations is presented for the different combinations of geometry. The resultant analytical solutions are used for the optimal design of the multilayered structures with functionally graded interface as well as with sharp interface.

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Patterns of consonant deletion in the word-internal onset position: Evidence from spontaneous Seoul Korean speech

  • Kim, Jungsun;Yun, Weonhee;Kang, Ducksoo
    • Phonetics and Speech Sciences
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    • v.8 no.1
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    • pp.45-51
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    • 2016
  • This study examined the deletion of onset consonant in the word-internal structure in spontaneous Seoul Korean speech. It used the dataset of speakers in their 20s extracted from the Korean Corpus of Spontaneous Speech (Yun et al., 2015). The proportion of deletion of word-internal onset consonants was analyzed using the linear mixed-effects regression model. The factors that promoted the deletion of onsets were primarily the types of consonants and their phonetic contexts. The results showed that onset deletion was more likely to occur for a lenis velar stop [k] than the other consonants, and in the phonetic contexts, when the preceding vowel was a low central vowel [a]. Moreover, some speakers tended to more frequently delete onset consonants (e.g., [k] and [n]) than other speakers, which reflected individual differences. This study implies that word-internal onsets undergo a process of gradient reduction within individuals' articulatory strategies.

Supravalvular Pulmonic Stenosis with Pulmonary Hypertension in a Bedlington Terrier Dog

  • Park, Kuk-Te;Hyun, Changbaig
    • Journal of Veterinary Clinics
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    • v.34 no.4
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    • pp.268-271
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    • 2017
  • A 1.3 year-old Castrated male Bedlington terrier (10.0 kg of body weight) was presented with heart murmur and occasional coughing. Diagnostic imaging studies revealed supravalvular pulmonic stenosis (maximal velocity 2.91 m/s) from abnormal membranous structure (aperture) distal to the pulmonary valve in the main pulmonary artery. Further study also revealed pulmonic regurgitant (1.82 m/s of peak velocity, 13.2 mmHg of pressure gradient) jets started from the abnormal membranous structure. Since the dog had no obvious clinical signs related to heart failure, no interventional therapy including balloon dilation was considered in this case. Instead, medical treatment for preventing further deterioration of clinical signs related to PS was done with enalapril. This case report described a rare case of type III supravalvular PS in a dog, which has never been reported. Further deterioration of clinical signs has yet been recognized after medical treatment.

Effect of Surface Film on Void Behavior in Composite Integrated Structure (표면접착필름이 복합재 일체형 구조물에서의 기공 거동에 미치는 영향)

  • Park, Dong-Cheol;Kim, Yun-Hae
    • Composites Research
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    • v.33 no.3
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    • pp.147-152
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    • 2020
  • In this study, void behavior of composite laminate by local internal pressure gradient due to structural geometry and surface film application condition was experimentally evaluated through fabrication of spar/skin integrated structure specimens. Viscosity comparison and thermal analysis for both carbon fiber prepreg and surface film were conducted and cure characteristic and rate difference were analyzed. 2 types of spar/skin integrated structural specimens were prepared based on different application condition of surface film. Subsequently, those specimens were evaluated through visual surface inspection, non-destructive and destructive inspection. In a specimen #1 with full application of surface film, low pressurized area of composite laminate created by pressure gradient of structural geometry had voids. It exhibited that voids could not be evacuated and were locked in cured laminate by the influence of pre-cured surface film with relatively faster cure rate. In a specimen #2 without surface film, it revealed that all internal voids disappeared in the cured laminate. Therefore, it is verified that surface film acts as barrier film preventing void movement and evacuation during autoclave cure.

Optimization of Block-based Evolvable Neural Network using the Genetic Algorithm (유전자 알고리즘을 이용한 블록 기반 진화신경망의 최적화)

  • 문상우;공성곤
    • Proceedings of the IEEK Conference
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    • 1999.06a
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    • pp.460-463
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    • 1999
  • In this paper, we proposed an block-based evolvable neural network(BENN). The BENN can optimize it's structure and weights simultaneously. It can be easily implemented by FPGA whose connection and internal functionality can be reconfigured. To solve the local minima problem that is caused gradient descent learning algorithm, genetic algorithms are applied for optimizing the proposed evolvable neural network model.

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A study for the residual strain of aluminum thin film for MEMS structures (MEMS용 구조물을 위한 알루미늄 박막의 잔류응력에 대한 연구)

  • Kim, Youn-Jin;Shin, Jong-Woo;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 1998.07g
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    • pp.2521-2523
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    • 1998
  • Freestanding flexible microstructures fabricated from deposited thin films become mechanically unstable when internal stresses exceed critical values. The residual stress and stress gradient of aluminum thin film were examined to make sure of fabricating the reproduceable aluminium structure. For good shape of micro mirror array and microstructures, the experiment was done varying thickness and deposition rate. As the aluminium film thickness increased from 0.8${\mu}m$ to 1.6${\mu}m$, the stress gradient decreased from 11.62MPa/${\mu}m$ to 2.62MPa/${\mu}m$. The residual stress values are from 42.4MPa to 62.24MPa of tensile stresses.

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Analysis for the Control of Thermal Cracks in a Subway Concrete Structure (지하철 구조물의 온도균열제어를 위한 수화열해석)

  • Kim, Sang-Chel;Kim, Yeon-Tae
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.1205-1210
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    • 2004
  • Cracks in the underground structures are mainly observed due to internal ununiformity of thermal stresses or restraint of structural movement in associate with rapid temperature gradient. Especially, thermal cracks are known to occur easily in a massive structure, but possibility of these depend on the amount of cement applied and ratio of span to height of the structure even though the thickness is less than specification‘s. Thus, this study aims at how to control thermal cracks in a massive subway structure and figures out an optimized construction method and procedure. As results of parametric study for length, height and outer temperature for concrete placement, it is found that hydration heats were not affected by both length and height of concrete placement but thermal stresses were greatly dependent. Most effective ways of controling thermal cracks were to fit a proper ratio of length to height of concrete placement and to decrease temperature of concrete placement as much as possible.

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Analysis of Thermal Runaway Phenomenon Caused by ZnO Varistor Operation Using Finite Element Method (유한요소법에 의한 ZnO 바리스터 동작 시 발생되는 열폭주 현상 해석)

  • Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.4
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    • pp.372-376
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    • 2022
  • Since the ZnO varistor is a semiconductor device, the internal thermal distribution during the varistor operation is recognized as an important factor in the performance and deterioration of the varistor. For an optimal varistor structure design, the thermal runaway phenomenon during the varistor operation was interpreted using the Comsol 5.2 analysis program by a finite element analysis. The maximum temperature of the center measured in the cross section of the ZnO varistor was confirmed to increase as the temperature moved from the lower electrode to the center towards the upper electrode up to 572.6 K. The electrodes are thinned so that the influence of the Schottky barrier is not great. The heat gradient balance is determined to be improved when the electrode of the hybrid form is introduced. The thickness, density, pore distribution, impurity uniformity, and particle size of the ZnO varistor are required, and it is determined that the pyrolysis gradient will be improved regardless of the electrode thickness. When these results are applied to design the ZnO varistor, the optimal structure of the ZnO varistor can be obtained.