• 제목/요약/키워드: Intermediate products

검색결과 374건 처리시간 0.027초

Ce0.8Sm0.2O2 Sol-gel Modification on La0.8Sr0.2Mn0.8Cu0.2O3 Cathode for Intermediate Temperature Solid Oxide Fuel Cell

  • Lee, Seung Jin;Kang, Choon-Hyoung;Chung, Chang-Bock;Yun, Jeong Woo
    • 마이크로전자및패키징학회지
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    • 제22권4호
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    • pp.77-82
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    • 2015
  • To increase the performance of solid oxide fuel cell operating at intermediate temperature ($600^{\circ}C{\sim}800^{\circ}C$), $Sm_{0.2}Ce_{0.8}O_2$ (SDC) thin layer was applied to the $La_{0.8}Sr_{0.2}Mn_{0.8}Cu_{0.2}O_3$ (LSMCu) cathode by sol-gel coating method. The SDC was employed as a diffusion barrier layer on the yttria-stabilized zirconia(YSZ) to prevent the interlayer by-product formation of $SrZrO_3$ or $La_2Zr_2O_7$. The by-products were hardly formed at the electrolyte-cathode interlayer resulting to reduce the cathode polarization resistance. Moreover, SDC thin film was coated on the cathode pore wall surface to extend the triple phase boundary (TPB) area.

3 차원 FEM 을 이용한 CB100의 압연공정 및 롤 응력 해석 (Rolling Process and Roll Stress Analysis of CB100 using by 3D FEM)

  • 김정민;박춘수;우기만
    • 소성∙가공
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    • 제19권2호
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    • pp.101-106
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    • 2010
  • CB100 is one of the channel type products in the steel beam. In this study, rolling process of CB100 is analyzed by 3D FEM simulation and rolling process. FEM simulation result is compared with rolling process data. Also the intermediate & finishing roll stress analysis is carried out and the suitability of the roll through roll stress resultant analysis is evaluated. In order to decrease the roll stress, new pass schedule is developed for stable load balance between intermediate and finishing rolling stand. Therefore new rolling pass schedule is verified by the analysis results of rolling process and roll stress. By the analysis results, the credibility of rolling process analysis was obtained and it was determined that the possibility of roll damage between intermediate and finishing mill was high. So the new pass schedule was developed. Through the result of rolling process and roll stress analysis, it was obtained that the reduction of roll stress and stable load balance.

A Novel Iron(III) Complex with a Tridentate Ligand as a Functional Model for Catechol Dioxygenases: Properties and Reactivity of [Fe(BBA)DBC]$ClO_4$

  • 윤성호;이호진;이강봉
    • Bulletin of the Korean Chemical Society
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    • 제21권9호
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    • pp.923-928
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    • 2000
  • [FeIII(BBA)DBC]ClO4 as a new functional model for catechol dioxygenases has been synthesized, where BBA is a bis(benzimidazolyl-2-methyl)amine and DBC is a 3,5-di-tert-butylcatecholate dianion.The BBA complex has a structuralfeature that iron cent er has a five-coordinate geometry similar to that of catechol dioxygenase-substrate complex.The BBA complex exhibits strong absorptionbands at 560 and 820 nm in CH3CN which are assigned to catecholate to Fe(III) charge transfer transitions. It also exhibits EPR signals at g = 9.3 and 4.3 which are typical values for the high-spin FeIII (S = 5/2) complex with rhombicsymmetry. Interestingly, the BBA complex reacts with O2 within an hour to afford intradiol cleavage (35%) and extradiol cleavage (60%) products. Surprisingly, a green color intermediate is observed during the oxygenation process of the BBA com-plex in CH3CN. This green intermediate shows a broad isotropic EPR signal at g = 2.0. Based on the variable temperature EPR study, this isotropic signalmight be originated from the [Fe(III)-peroxo-catecholate] species havinglow-spin FeIII center, not from the simple organic radical. Consequently,it allows O2 to bind to iron cen-ter forming the Fe(III)-superoxide species that converts to the Fe(III)-peroxide intermediate. These present data can lead us tosuggest that the oxygen activation mechanism take place for the oxidative cleavingcatechols of the five-coordinate model systems for catechol dioxygenases.

Isolation and Characterization of Terpene Synthase Gene from Panax ginseng

  • Kim, Yu-Jin;Ham, Ah-Rom;Shim, Ju-Sun;Lee, Jung-Hye;Jung, Dae-Young;In, Jun-Gyo;Lee, Bum-Soo;Yang, Deok-Chun
    • Journal of Ginseng Research
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    • 제32권2호
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    • pp.114-119
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    • 2008
  • Terpene synthase plays a key role in biosynthesis of triterpene saponins (ginsenosides) and is intermediate in the biosynthesis of a number of secondary metabolites. A terpene synthase (PgTPS) cDNA was isolated and characterized from the root of Panax ginseng c.A. Meyer. The deduced amino acid sequence of PgTPS showed a similarity with A. deliciosa (AAX16121) 61%, V. vinifera (AAS66357) 61%, L. hirsutum (AAG41891) 55%, M. truncatula (AAV36464) 52%. And the segment of a terpene synthase gene was amplified by reverse transcriptase-polymerase chain reaction (RTPCR). We studied expression of terpene synthase under stressful conditions like chilling, salt, UV, and heavy metal stress treatment. Expression of PgTPS was increased gradually after exposure to stresses such as chilling, salt, and UV illumination. But its transcription seems to be reduced by cadmium and copper treatment.

Characterization of Doxorubicin-nonproducing Mutant, Nu3 of Streptomyces peucetius ATCC27952

  • Kyu, Hwang-Cheol;Lee, Hong-Sub;Hong, Young-Soo;Paek, Nam-Soo;Kim, Tae-Han;Lee, Jung-Joon
    • Journal of Microbiology and Biotechnology
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    • 제7권5호
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    • pp.363-366
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    • 1997
  • A doxorubicin-nonproducing mutant, Nu23 was selected from the mutagenesis of Streptomyces peucetius ATCC27952. Chemical and molecular biological analysis suggested that the mutant was blocked at the step between polyketide synthase and aklaviketon reductase in the biosynthesis of doxorubicin. Furthermore, the bioconversion experiment with the mutant revealed that 13-dihydrodaunorubicin is likely to be a biosynthetic intermediate.

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황화 $Ni-W/\gamma-Al_2O_3$ 촉매에 의한 Dibeenzothiophene의 수첨탈황반응 (Hydrodesulfurization of Dibenzothiophene by Sulfided $Ni-W/\gamma-Al_2O_3$ Catalyst)

  • 김경림;정지원
    • 한국대기환경학회지
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    • 제2권2호
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    • pp.51-59
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    • 1986
  • Hydrodesulfurization of dibenzothiophene (DBT) dissolved in n-heptane was studied over sulfided $Ni - W/\gamma - Al_2O_3$ catalyst at temperature ranges from 513 to 573 K and at pressure ranges from 20 to 60 x $10^5$ Pa. Hydrogenation of biphenyl (BP) and cyclohexylbenzene (CHB) observed in products were also run. The products were almost biphenyl and cyclohyxylbenzene, and the conversion of DBT was very sensitive to temperature. Concerning the products distribution while the formation of biphenyl decreased, the formation of cyclohexylbenzene increased in the range of high pressure. The reaction network was found to be sequential reaction which formed cyclohexybenzent through the intermediate of biphenyl. The disappearances of DBT and biphenyl were the first order with respect to DBT and biphenyl and their activation energys were 24.3 and 13.6 Kcal/mol, respectively.

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온간 성형법을 이용한 스테인리스 버트 제품의 성형한계 향상에 관한 연구 (A Study on the Improvement of Drawing Limit in Stainless Butt Products using Warm Deep Drawing Process)

  • 김승수;나경환;김종호;한창수
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1995년도 춘계학술대회논문집
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    • pp.203-210
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    • 1995
  • The rapid progress of automobile industry has led to a demand for sheet metal products and the new forming technology for complex product is required. In Deep Drawing process of steel sheet, especially stainless steel sheet at room temperture, some intermediate annealing need to be added to lessen strain hardening effect. The present study is concerned with the wram deep drawing of stainless steel sheet. In order to reduce the number of working process. the limit drawing ration is considered as main parameter. In this study, the effect of process variables such a sblank holder force, working temperature and lubricant on limit drawing ration is investigated . Experiments are carried out for the hemisherical and sqare shape at room and warm temperature respectively. The drawing loads and thickness deviation accoring to process variables measured . As the result of apploying those experimental data to the commerical butt product, the number of process can be reduced and good quality of products can be obtained.

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New Indicators of Global Integration Using Input-Output Analysis

  • DONGSEOK KIM
    • KDI Journal of Economic Policy
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    • 제46권2호
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    • pp.45-74
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    • 2024
  • The import content of export (ICE) has served as an indicator of global integration for several decades. It is defined as the share of imported products embodied in exports and can be interpreted as the relative degree of the utilization of global production network (GPN) over the domestic supply chain (DSC) in terms of 'value-added.' This paper proposes two new indicators of global integration. They are defined as the ratios of imports (foreign products) to gross output (domestic products) generated by exports and can be interpreted as the relative degrees of the utilization of GPN over DSC in terms of 'production.' Both indicators are easy to compute and can be compared between years, between countries, between industries, and between groups of industries. The paper applies the new indicators to the recent edition of the OECD's Input-Output Database. Finally, the paper shows that the recent slowdown in international trade is mostly due to the decrease in the international trade of intermediate goods, with significant implications regarding the future of global integration.

DSP Performance Maximization with Multisample Technique

  • Lee, Hosun;Lawrence K.W. Law;Youngyearl Han
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2000년도 제13회 신호처리 합동 학술대회 논문집
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    • pp.471-474
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    • 2000
  • In this paper, we present multisample DSP coding technique for StarCore, SC 140 DSP. The multisample programming is a pipelining technique that exploits operand reuse both coefficients and variables within kernel. A coefficient or operand is loaded once from memory and then the value may be used by multiple ALUs. It is possible to evaluate one intermediate product from each of four output sample calculations in parallel . Therefore, parallelization has been achieved by processing multiple samples in parallel rather than multiple intermediate products belonging to only one sample. The benefits of decreasing the number of memory moves per sample is to increase the algorithm perforomance. In this paper, the multisample technique has been implemented in FIR filter calculation using Motorola StarCore DSP development tool.

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BaTiO3의 습식 직접 합성(I) (A Study of BaTiO3 Synthesis by Direct Wet Process)

  • 이경희;이병하;이희승
    • 한국세라믹학회지
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    • 제21권4호
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    • pp.323-326
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    • 1984
  • In this study we are going to develop the process of a synthesis about BaTiO3 at the room temperature. We use BaTiO3 as a high dielectric constant in many dielectric materials and more stable in the temperature, We need high temperature over 1300$^{\circ}C$ for the synthesis of BaTiO3 by the process of industrials and there are difficulty which synthesize a final products not to have a intermediate composition. So we studied to synthesize a pure BaTiO3 from the room temperature to 90$^{\circ}C$ and also to develop the process of synthesis which can control the particle size and which has the final product not to have a intermediate composition.

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