• Applied Chemistry for Engineering
• /
• v.31 no.2
• /
• pp.193-199
• /
• 2020

The effects of the composition of the dishwashing detergent on interfaces of the oil (O) and the aqueous (W) solution in addition to the cleaning effects of interfacial properties were investigated. Also, the cleaning power of the oil contaminated on the surface of the dish according to each composition and the residuals of the contaminants and the cleaning agent after the washing rinses were evaluated. The removal of contaminated oil on the solid (S) surface in the composition of the cleaning agents used in this study was strongly related to the interfacial properties between the W/O/S, and was particularly dependent on the forward and backward dynamic contact angles. When both contact angles were low at the same time, the permeability of the cleaning solution was so high that the contaminated oil showed a high removal effect. The smaller the interfacial tension of O/W was, the better emulsification of the contaminated oil, the higher the interfacial tension, and the poorer emulsification were achieved. However, the emulsification effect did not significantly affect the cleaning power. In particular, in the case of the cleaner having low interfacial tension, the cleaning material remained on the surface of the solid after washing.

• Journal of the Microelectronics and Packaging Society
• /
• v.28 no.2
• /
• pp.65-70
• /
• 2021

In this study, interfacial properties and mechanical properties of joints were reported after Cu pads finished with organic solderability preservative (OSP) on flame retardant-4 (FR-4) printed circuit board (PCB) and electronic components were joined with a Sn-57Bi-1Ag solder paste by using a laser bonding process. The laser bonding process was performed under various bonding conditions with changing a laser power and a bonding time and effects of bonding conditions on interfacial and mechanical properties of joints were analyzed. In order to apply for industry, properties of bonding joints using a reflow bonding process which are widely used were compared. When the laser bonding process were performed, we observed that Cu₆Sn₅ intermetallic compounds (IMCs) were fully formed at the interface although the bonding times were very short about 2 and 3 s. Furthermore, void formations of the joints by using the laser bonding process were suppressed at the joints with comparing to the reflow bonding process and shear strengths of bonding joints were higher than that by using the reflow bonding process. Therefore, in spite of a very short bonding time, it is expected that joints will be stably formed and have a high mechanical strength by using the laser bonding process.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2009.11a
• /
• pp.123-123
• /
• 2009

In our experiment, a PTFE was sputter-coated on substrates to induce water-repellent properties and the RF-magnetron sputtering method for fabrication of PTFE film is used due to the advantages of the simple process, time saving, environmentally friendly, insulating property, and a good adhesion property to substrates. As a result of the correlation between surface roughness of PTFE films and contact angle with water, we found that the roughness surfaces are proportioned to contact angles related to low interfacial energy.

• International Journal of Concrete Structures and Materials
• /
• v.5 no.1
• /
• pp.3-10
• /
• 2011

Theoretical models for prediction of the mechanical properties of cement mortar are developed based on the morphology and interactions of cement hydration products, capillary pores and microcracks. The models account for intermolecular interactions involving the nano-scale calcium silicate hydrate (C-S-H) constituents of hydration products, and consider the effects of capillary pores as well as the microcracks within the hydrated cement paste and at the interfacial transition zone (ITZ). Cement mortar was modeled as a three-phase material composed of hydrated cement paste, fine aggregates and ITZ. The Hashin's bound model was used to predict the elastic modulus of mortar as a three-phase composite. Theoretical evaluation of fracture toughness indicated that the frictional pullout of fine aggregates makes major contribution to the fracture energy of cement mortar. Linear fracture mechanics principles were used to model the tensile strength of mortar. The predictions of theoretical models compared reasonably with empirical values.

• Macromolecular Research
• /
• v.13 no.3
• /
• pp.194-205
• /
• 2005

The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

• Computers and Concrete
• /
• v.7 no.6
• /
• pp.497-510
• /
• 2010

For better estimation of elastic property of concrete composites, the effect of Interfacial Transition Zone (ITZ) has been found to be significant. Numerical concrete composites models have been introduced using Finite Element Method (FEM), where ITZ is modeled as a thin shell surrounding aggregate. Therefore, difficulties arise from the mesh generation. In this study, a numerical concrete composites model in 3D based on FEM and random unit cell method is proposed to calculate elastic modulus of concrete composites with ITZ. The validity of the model has been verified by comparing the calculated elastic modulus with those obtained from other analytical and numerical models.

• Journal of the Korean Society of Radiology
• /
• v.4 no.4
• /
• pp.33-36
• /
• 2010

Multilayer mirrors are very useful for applications of high energy X-ray. X-rays of high energy require very small thickness, a few nanometers, in the d-spacing of a multilayer mirror. Each layer is composed of a multilayr mirror influences to interfacial roughness or interdiffusion which gives rise to degrade specular reflection. Carbon layer of 1 nm thick in a C/W multilayer mirror of 3.25 nm d-spacing was examined. Carbon as well as tungsten layers were very uniform, and there was no micro-structure in carbon layers. However, interdiffusion between carbon and tungste layers was observed by a transmission electron microscope.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.16 no.1
• /
• pp.53-59
• /
• 2003

Using Platinum-silicide (PtSi) formed between silicon substrate and carbon film, we have improved the field emission of electrons from carbon films. Pt films were deposited on n-Si(100) substrates at room temperature by DC sputter technique. After deposition, these PtSi thin films were annealed at 400 ~ $600^{\circ}C$ in a vacuum chamber, and the carbon films were deposited on those Pt/Si substrates by laser ablation at room temperature. The field emission property of C/Pt/Si system is found to be better than that of C/Si system and it is showed that property was improved with increasing annealing temperature. The reasons why the field emission from carbon film was improved can be considered as follows, (1)the resistance of carbon films was decreased due to graphitization, (2)electric field concentration effectively occurred because the surface morphology of carbon film deposited on Pt/si substrates with rough surface, (3)it is showed that annealing induced reaction between Pt film and Si substrate, as a consequence that the interfacial resistance between Pt film and Si substrate was decreased.

• Transactions on Electrical and Electronic Materials
• /
• v.7 no.1
• /
• pp.16-20
• /
• 2006

In this paper, we investigated the effects of short-term oxygen plasma treatment of semiconducting silicone layer to improve interfacial performances in joints prepared with a insulating silicone materials. Surface characterizations were assessed using contact angle measurement and x-ray photoelectron spectroscopy (XPS), and then adhesion level and electrical performance were evaluated through T-peel tests and electrical breakdown voltage tests of treated semi-conductive and insulating joints. Plasma exposure mainly increased the polar component of surface energy from $0.21\;dyne/cm^2$ to $47\;dyne/cm^2$ with increasing plasma treatment time and then leveled off. Based on XPS analysis, the surface modification can be mainly ascribed to the creation of chemically active functional groups such as C-O, C=O and COH on semi-conductive silicone surface. This oxidized rubber layer is inorganic silica-like structure of Si bound with three to four oxygen atoms ($SiO_x,\;x=3{\sim}4$). The oxygen plasma treatment produces an increase in joint strength that is maximum for 10 min treatment. However, due to brittle property of this oxidized layer, the highly oxidized layer from too much extended treatment could be act as a weak point, decreasing the adhesion strength. In addition, electrical breakdown level of joints with adequate plasma treatment was increased by about $10\;\%$ with model samples of joints prepared with a semi-conducting/ insulating silicone polymer after applied to interface.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2005.04a
• /
• pp.111-115
• /
• 2005

Recently, natural fibers draw much interests in composite industry due to low cost, light weight, and environment-friendly characteristics compared with glass fibers. In this study, mechanical properties were evaluated for two extreme cases of jute fiber orientations, i.e. the unidirectional yarn composites and the felt fabric composites. Samples of jute fiber composites were fabricated by RTM process using epoxy resin, and tensile, compression, and shear tests were conducted. As can be expected, unidirectional fiber specimens in longitudinal direction showed the highest strength and modulus. Compared with glass/epoxy composites of the similar fabric architecture and fiber volume fraction, the tensile strength and modulus of jute felt/epoxy composites reached only 40% and 50% levels. However, the specific tensile strength and modulus increased to 80% and 90% of the glass/epoxy composites. The main reason for the poor mechanical properties of jute composites is associated with the weak interfacial bonding between fiber and matrix. The effect of surface treatment of jute fibers on the interfacial bonding will be examined in the future work.