• Transactions of the Korean hydrogen and new energy society
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• v.24 no.2
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• pp.142-149
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• 2013

Carbon materials are mainly used as catalyst supports for polymer exchange membrane fuel cell (PEMFC). Catalyst supports are required specific characteristics of the carbon materials, such as large surface area and high electrical conductivity. Attempted were to improve electrical conductivity and to maintain high surface area of carbon materials using a microwave treatment. Microwave treatment, as a relatively new technique, takes short reaction time and reduce the consumption of the gases used for carbon treatment compared to a traditional heat treatment. Hybrid carbon (ACF/Graphene) as catalyst supports by microwave-irradiation method for PEMFC increase the cell performance because of increased electrical conductivity resulting in triple-phase contact and reduced the interfacial resistance. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-Ray Diffraction (XRD) were employed to analyze carbon materials. The performance of microwave-treated carbon materials was evaluated by measuring current-voltage (I-V) characteristics and electrode impedance.

• Composites Research
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• v.34 no.3
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• pp.148-154
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• 2021

Carbon/epoxy composite bipolar plate (BP) is a BP that is likely to replace existing graphite bipolar plate of vanadium redox flow cell (VRFB) due to its high mechanical properties and productivity. Multi-functional carbon/epoxy composite BP requires graphite coating or additional surface treatment to reduce interfacial contact resistance (ICR). However, the expanded graphite coating has the disadvantage of having low durability under VRFB operating conditions, and the surface treatments incur additional costs. In this work, an excessive resin absorption method is developed, which uniformly removes the resin rich area on the surface of the BP to expose carbon fibers by applying polyester fabric. This method not only reduces ICR by exposing carbon fibers to BP surfaces, but also forms a unique ditch pattern that can effectively hold carbon felt electrodes in place. The acidic environmental durability, mechanical properties, and gas permeability of the developed carbon/epoxy composite BP are experimentally verified.

• Journal of Dental Rehabilitation and Applied Science
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• v.24 no.1
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• pp.41-56
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• 2008

The methods of surface modification of commercial implants were various according to the manufacturer. Surface modification of implant may produce diverse physical and chemical surface characteristics resulted from the treatment method and treatment condition. As a result, the bone response might be different. Even though surface modified implants have been used clinically, most researches are focusing on the bone response of surface modified implants comparing to machined implants rather than surface modified commercial implants. This study compare and analyze bone responses of 4 surface modified commercial implants with different shapes and surfaces. Eighty surface modified commercial implants with 4 different surface characteristics were installed in the tibia of white Newzealand rabbits. Biomechanical stability tests and histomorphometric evaluation were done. The results were as follows: 1. Surface modified commercial implants showed stable osseointegration at 6 weeks after installation. 2. Histomorphometric evaluation showed that there was no significant differences in bone to implant contact among 4 different commercial titanium implants. In comparing the implants with different shape the measurement of bone growth in subcortical area would be more reliable than entire bone to implant contact length. 3. Resonance Frequency Analysis showed that there was no significant differences among 4 types of implants, even though they were significantly different in installation. 4. There was significant differences in interfacial shear strength among 4 type of implants. 5. It is difficult to observe accurate bone to implant interface using Micro-CT. However, it is possible to measure the entire contact length of the implant to the bone.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.52-60
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• 2018

In the automobile industry, in order to increase the fuel efficiency and conform to the safety regulations, it is necessary to make the vehicles as light as possible. Therefore, it is crucial to manufacture dual phase steels, complex phases steels, MS steels, TRIP steels, and TWIP from high strength steels with a tensile strength of 700Mpa or more. In order to apply ultra-high tensile strength steel to the body, the welding process is essential. Resistance spot welding, which is advantageous in terms of its cost, is used in more than 80% of cases in body welding. It is generally accepted that ultra-high tensile strength steel has poor weldability, because its alloy element content is increased to improve its strength. In the case of the resistance spot welding of ultra-high tensile steel, it has been reported that the proper welding condition area is reduced and interfacial fracture and partial interfacial fracture occur in the weld zone. Therefore, research into the welding quality judgment that can predict the defect and quality in real time is being actively conducted. In this study, the dynamic resistance of the weld was monitored using the secondary circuit process variables detected during resistance spot welding, and the factors necessary for the determination of the welding quality were extracted from the dynamic resistance pattern. The correlations between the extracted factors and the weld quality were analyzed and a regression analysis was carried out using highly correlated pendulums. Based on this research, a regression model that can be applied to the field was proposed.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.579-584
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• 1998

Polymer dispersed liquid crystal(PDLC) composite films were made by polymerization induced phase separation method using UV-curing to investigate the effect of fabrication conditions, such as photoinitiator concentration, film thickness, polymerization temperature, and electric field during polymerization, etc., on the electro-optic properties. As the amount of photoinitiator increased, the driving voltage of PDLC device increased due to the increase of small-size liquid crystal phases. This was considered as the results from the increased interfacial area between liquid crystal (LC) and polymer matrix, since LC molecules at the interfacial regions were relatively difficult to response for the applied electric field. When the higher molecular weight oligomer (PTDA-1000) was used as matrix, the initial transmittance was observed to be relatively higher than that for the lower molecular weight oligomer (PTDA-250). Saturation transmittance for PTDA-1000 was observed at relatively lower voltage than that for PTDA-250, of which transmittance was not saturated even at 60 V. As polymerization temperature increased, the initial transmittance of resulting PDLC film increased due to the larger LC droplets formation and the more matched refractive index between LC and matrix than those cases for the lower polymerization temperature. Though driving voltage decreased for the thinner film, it was considered that optimum thickness of the film should be maintained to get some practical contrast, which is the ratio of off- and on-state transmittance. Furthermore, electro-optic properties such as initial transmittance, driving voltage, and response time were observed to be considerably affected by application of external field during polymerization.

• Journal of Adhesion and Interface
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• v.23 no.4
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• pp.122-129
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• 2022

In this study, the hydrophilicity of the metal fiber is improved by introducing an oxygen-containing functional group to the fiber surface after treatment of the metal fiber using the oxygen plasma treatment time as an experimental variable. For the surface modification of metal fibers, changes in surface properties before and after plasma treatment were observed using SEM and x-ray photoelectron spectroscopy (XPS). In order to observe the effect of the plasma treatment time on the surface of the metal fiber, the change in contact angle of the metal fiber with respect to a polar solvent and a non-polar solvent was measured. After calculating the change in surface free energy using the measured contact angle, the contact angle and the surface free energy for metal fibers before and after oxygen plasma treatment were compared, and the correlation with the adhesion work was also considered. The microdroplet specimens were prepared to investigate the effect of surface changes of these metal fibers on the improvement of shear strength at the interface when combined with other materials and the interfacial shear strength was measured, and the correlation with the adhesion work was also identified. Therefore, the oxygen plasma treatment of the metal fiber results in an increase in the physical surface area on the fiber surface and a change in contact angle and surface energy according to the introduction of the oxygen-containing functional group on the surface. This surface hydrophilization resulted in improving the interfacial shear strength with the polymer resin.

• Composites Research
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• v.20 no.1
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• pp.23-31
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• 2007

In order to improve the mechanical properties of jute fiber/polypropylene(PP) composites, the property change with the addition of a coupling agent, maleic anhydride polypropylene(MAPP) was examined experimentally. The maleated coupler acts as an intermediate to chemically connect the polar nature of the fiber and non-polar nature of the polyolefin polymer resin. Furthermore, the decrease in viscosity of the resin which results from the melting point reduction by the MAPP, leads to an increase of contact area with the fiber interface. We discussed the improvement of the PP composite blend of the maleated coupler with the 80mm jute long fiber mat in conjunction with the change of physical parameters in the thermoplastic resin. We confirmed the extent of contribution to the mechanical physical enhancement by using the following parameters: melting flow index(MI) and viscosity, contact angle, thickness of the composite, interfacial shear strength and morphology observation etc. Especially it was observed that the MI and viscosity, MAPP mixture had a very strong relationship with the tensile and flexural strength and modulus, and interfacial shear strength(IFSS).

• Polymer(Korea)
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• v.27 no.4
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• pp.340-348
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• 2003

A previous stud-pull test was modified to measure the bond strength of polyurethane foam to carbon steel substrate. This test was appropriate in that the specimen foamed on Zn phosphated steel (0.95 kN) was broken at higher load than that of smooth galvanizing treated steel (0.38 kN). Among the samples foamed on the substrate atvarious preheating temperatures, the polyurethane foam to the steel held over 60$^{\circ}C$ exhibited very high bond strength. The samples were exposed at water vapor absorption, and, then, their bond strengths were measured. The adhesion was significantly reduced in the samples foamed on the steel at temperatures below 40$^{\circ}C$ and above 70$^{\circ}C$. For the polyurethane foams formulated with two blowing gases, the adhesion was higher by 0.03 kN in the samples with HCFC-l4lb than that with HFC-245fa. When the these samples were exposed at water vapor soaking, the reduction of the bond strength for the HFC-245fa blown sample was negligible due to smaller area fraction of void area filled with gas at interfacial area. Consequently, it was found that adhesion of polyurethane foam to metal substrate was determined by variation of microstructural features with substrate preheating, surface treatment type of blowing agent.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.2
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• pp.38-46
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• 2014

Effects of various parameters on bond property between reinforcing bar and concrete are investigated in many researchers, and various study is on going to improve the bond strength. Properties of interface between reinforcement and concrete is important role in bond property. This study analyzed the interfacial bond mechanism between deformed bar and concrete by finite element analysis (FEA) to evaluate the effect of rib shape. The FEA model in this study is simplified 2D plane stress model. The variables of analysis are selected by rib angle, rib height, rib spacing and relative rib area. From the results of analysis, reinforcing bars with rib angle $30{\sim}60^{\circ}$ showed better bond strength than the others. Bond strength ratio following to the rib height is proportionally increased up to the $0.12d_b$, but rib spacing has little effect on bond strength. The results also indicated that relative rib area can be efficiently represented the properties of deformed shape in reinforcing bars, and zigzagged rib height shape showed excellent bond strength increase.

• Composites Research
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• v.14 no.1
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• pp.1-7
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• 2001

In this study, damage evaluation of glass fiber reinforced thermoplastic composites was investigated with acoustic emission method. Specimens of 1.7mm thickness laminate were made from PET and 7 layers o171ass fabrics. Notch and impact loading were added to the specimen and normal tensile test and tensile test with the dead load were carried out. AE signal was measured as the functions of notch ratio to the width0 and impact energy in order to find out the correlation between fracture mode and AE parameters. The result has shown that low amplitude of AE signal was due to the microcrack of matrix and its growth, whereas the amplitude in the mid range was the response to the delamination and interfacial separation. In the range of high amplitude above 90dB. the fracture of glass fabric was found. Tensile strength decreased with increasing notch ratio to the width and impact energy because of tile effect or delamination, the cracking of matrix and stress concentration. In proportion to the size of damaged area. AE signal showed its wider range of frequency and energy as well as increased number of hits.