• 제목/요약/키워드: Interfacial Zone

검색결과 125건 처리시간 0.024초

SiC 휘스커 강화 Al2O3 복합재료의 고인화 (Toughening of SiC Whisker Reinforced Al2O3 Composite)

  • 김연직;송준희
    • 한국재료학회지
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    • 제14권9호
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    • pp.649-654
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    • 2004
  • In this paper, the fracture toughness and mechanisms of failure in a random SiC-whisker/$Al_{2}O_3$ ceramic composite were investigated using in situ observations during mode I(opening) loading. $SiC_{w}/Al_{2}O_3$ composite was obtained by hot press sintering of $Al_{2}O_3$ powder and SiC whisker as the matrix and reinforcement, respectively. The whisker and powder were mixed using a turbo mill. The composite was produced at SiC whisker volume fraction of $0.3\%$. Compared with monolithic $Al_{2}O_3$, fracture toughness enhancement was observed in $SiC_{w}/Al_{2}O_3$ composite. This improved fracture toughness was attributed to SiC whisker bridging and crack deflection. $SiC_{w}/Al_{2}O_3$ composite exhibited typically brittle fracture behavior, but a fracture process zone was observed in this composite. This means that the load versus load-line displacement curve of $SiC_{w}/Al_{2}O_3$ composite from a fracture test may involve a small non-linear region near the peak load.

Sustainable self compacting acid and sulphate resistance RAC by two stage mixing approaches

  • Rajhans, Puja;Kisku, Nishikant;Nayak, Sanket;Panda, Sarat Kumar
    • Advances in concrete construction
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    • 제9권1호
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    • pp.55-70
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    • 2020
  • In this research article, acid resistance, sulphate resistance and sorptivity of self compacted concrete (SCC) prepared from C&D waste have been discussed. To improve the above properties of self compacted recycled aggregate concrete (SCRAC) along with mechanical and durability properties, different two stage mixing approaches (TSMA and TSMAsfc) were followed. In the proposed two stage mixing approach (TSMAsfc), silica fume, a proportional amount of cement and a proportional amount of water were mixed in premix stage which fills the pores and cracks of recycled aggregate concrete (RAC). The concrete specimen prepared using above mixing approaches were immersed in 1% concentration of sulphuric acid (H2SO4) and magnesium sulphate (MgSO4) solution for 28, 90 and 180 days for evaluating the acid resistance of SCRAC. Experimental results concluded that the proposed two stage mixing approach (TSMAsfc) is most suitable for acid resistance and sulphate resistance in terms of weight loss and strength loss due to the elimination of pores and cracks in the interfacial transition zone (ITZ). In modified two stage mixing approach, the pores and cracks of recycled concrete aggregate (RCA) were filled up and make ITZs of SCRAC stronger. Microstructure analysis was carried out to justify the reason of improvement of ITZs by electron probe micro analyser (EPMA) analysis. X-ray mapping was also done to know the presence of strength contributing elements presents in the concrete sample. It was established that SCRAC with modified mixing approach have shown improved results in terms of acid resistance, sulphate resistance, sorptivity and mechanical properties.

The effective properties of saturated concrete healed by EDM with the ITZs

  • Chen, Qing;Jiang, Zhengwu;Zhu, Hehua;Ju, J.W.;Yan, Zhiguo;Li, Haoxin
    • Computers and Concrete
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    • 제21권1호
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    • pp.67-74
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    • 2018
  • A differential scheme based micromechanical framework is proposed to obtain the effective properties of the saturated concrete repaired by the electrochemical deposition method (EDM) considering the interfacial transition zone (ITZ) effects. The constituents of the repaired concrete are treated as different phases, consisting of (micro-)cracks, (micro-)voids and (micro-)pores (occupied by water), deposition products, intrinsic concrete made up by the three traditional solid phases (i.e., mortar, coarse aggregates and their interfaces) and the ITZs. By incorporating the composite sphere assemblage (CSA) model and the differential approach, a new multilevel homogenization scheme is utilized to quantitatively estimate the mechanical performance of the repaired concrete with the ITZs. The CSA model is modified to obtain the effective properties of the equivalent particle, which is a three-phase composite made up of the water, deposition products and the ITZs. The differential scheme is employed to reach the equivalent composite of the concrete repaired by EDM considering the ITZ effects. Moreover, modification procedures considering the ITZ effects are presented to attain the properties of the repaired concrete in the dry state. Results in this study are compared with those of the existing models and the experimental data. It is found that the predictions herein agree better with the experimental data than the previous models.

기지내 반응법에 의한 WC 복합재료의 제조에 관한 연구(1);주조접합된 주철/텅스텐 와이어의 계면반응층 생성기구와 조직특성 (A Study on the Manufacture of WC MMCs by In-situ Reaction Process(1);The Formation Mechanism of Interfacial Reaction Layer in Cast-bonded Cast iron/W wire and Its Structure)

  • 박흥일;김창업;허보영;이성렬;김창규
    • 한국주조공학회지
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    • 제15권3호
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    • pp.272-282
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    • 1995
  • Iron-based metal matrix composites have been recently investigated for the use of inexpensive abrasion resistance material. This paper carried out to investigate the in-situ reaction effects on the microstructural characteristics and the formation mechanism of tungsten carbides in a white cast iron matrix. The specimens of Fe-3.2%C-2.8%Si alloy cast-bonded with tungsten wire were cast in the metal mold and isothermally heat treated at $950^{\circ}C$ up to 48 hours. The typical microstructure of heat treated specimens showed the reaction layer of WC at the interface of tungsten wire and the carbon depletion zone between the WC layer and the matrix. During the formation of WC layer, if the carbon supply is insufficient due to the decarburization of matrix or the isolation of matrix by cast-bonded W wires, the reaction layer develops coarse hexagonal crystalline WC. From the microstructural investigation, it was found that the volume of WC layer and the carbon depletion zone increased linearly with the isothermal heat treating time. This results supported that the formation rate of WC in the white cast iron matrix is controlled by the interfacial reaction with a constant reaction rate.

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AI 이온 주입된 p-type 4H-SiC에 형성된 Ni/AI 오믹접촉의 전기 전도 특성 (Conduction Properties of NitAI Ohmic Contacts to AI-implanted p-type 4H-SiC)

  • 주성재;송재열;강인호;방욱;김상철;김남균;이용재
    • 한국전기전자재료학회논문지
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    • 제22권9호
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    • pp.717-723
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    • 2009
  • Ni/Al ('/' denotes deposition sequence) contacts were deposited on Al-implanted 4H-SiC for ohmic contact formation, and the conduction properties were characterized and compared with those of Ni-only contacts. The thicknesses of the Ni and Al thin film were 30 nm and 300 nm, respectively, and the films were sequentially deposited bye-beam evaporation without vacuum breaking. Rapid thermal anneal (RTA) temperature was varied as follows : $840^{\circ}C$, $890^{\circ}C$, and $940^{\circ}C$. The specific contact resistivity of the Ni contact was about $^{\sim}2\;{\pm}\;10^{-2}\;{\Omega}{\cdot}cm^2$, However, with the addition of Al overlayer, the specific contact resistivity decreased to about $^{\sim}2\;{\pm}\;10^{-4}\;{\Omega}{\cdot}cm^2$, almost irrespective of RTA temperature. X-ray diffraction (XRD) analysis of the Ni contact confirmed the existence of various Ni silicide phases, while the results of Ni/Al contact samples revealed that Al-contaning phases such as $Al_3Ni$, $Al_3Ni_2$, $Al_4Ni_3$, and $Ab_{3.21}Si_{0.47}$ were additionally formed as well as the Ni silicide phases. Energy dispersive spectroscopy (EDS) spectrum showed interfacial reaction zone mainly consisting of Al and Si at the contact interface, and it was also shown that considerable amounts of Si and C have diffused toward the surface. This indicates that contact resistance lowering of the Ni/Al contacts is related with the formation of the formation of interfacial reaction zone containing Al and Si. From these results, possible mechanisms of contact resistance lowering by the addition of Al were discussed.

라텍스개질콘크리트로 보수·보강된 RC 보의 휨 거동에 관한 실험적 연구 (Experimental Study on the Flexural Behavior Effect of RC Beam Repaired and Strengthened by Latex Modified Concrete)

  • 김성환;윤경구;김용곤
    • 대한토목학회논문집
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    • 제29권5A호
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    • pp.503-510
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    • 2009
  • 본 연구의 목적은 LMC로 덧씌우기 또는 보수 된 형태의 RC 보의 정적 거동 특성을 파악하는데 있다. 따라서, LMC로 덧씌우기 및 보수된 RC 보를 상대습도 60%, 온도 $20^{\circ}C$의 조건에서 양생을 실시하여 제작하였으며, 제작된 시험체를 4점 휨 실험을 수행하여 균열양상, 파괴거동 및 극한강도 등의 거동을 고찰하였다. 실험결과 전단철근이 보강된 보수형태의 RC보의 경우 100%이상의 내하력을 회복하여 보수 효과가 뛰어난 것을 알 수 있었고, LMC로 압축부에 덧씌우기 된 시험체의 경우 덧씌우기 두께가 증가함에 따라 내하력이 크게 증진되었다. 그러나, 전단철근이 보강되지 않은 보수형태의 시험체와 인장부 덧씌우기된 시험체는 부착계면 파괴양상을 보여주어 보수 및 보강 효과가 거의 없는 것으로 나타났다. 또한 부착계면의 거동특성을 파악하기 위하여 전단흐름 개념을 도입하여 LMC로 압축 덧씌우기된 시험체를 대상으로 하중증가에 따른 전단흐름량을 계산하여 부착계면 특성을 수치적으로 나타내었다.

표면코팅 경량골재의 전기저항 특성 (Investigation of Electrical Resistance Properties in Surface-Coated Lightweight Aggregate)

  • 김호진;김창현;최정욱;박선규
    • 한국건축시공학회지
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    • 제23권6호
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    • pp.727-738
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    • 2023
  • 계면은 콘크리트 강도 결정 요인 중 가장 약한 영역으로, 골재와 시멘트 페이스트 사이에서 형성된다. 경량골재는 원재료를 팽창, 소성시켜 제조하기 때문에 표면에 수많은 공극을 형성하여 밀도가 낮은 장점을 지니지만 골재 강도가 약하다. 콘크리트는 골재강도가 약하면 골재의 파단이 발생한다. 경량골재의 콘크리트 적용은 골재 파단 때문으로 계면의 강도가 중요하다. 본 연구에서는 경량골재의 계면강도 증진을 위해 고로슬래그 미분말로 골재표면을 코팅하고, 시험체의 임피던스를 비교하여 표면개질에 의한 계면 변화를 분석하였다. 실험결과, 경량골재 표면코팅 시 압축강도가 약 4%정도 증가하였고, 강도 증가에 따라 임피던스 값 중 레지스턴스 값이 증가하는 것을 확인하였다.

AZ31 마그네슘 합금 판재의 전기저항 이중 스폿용접 특성 (Characteristics of Electric Resistance Dual Spot Welding Process of AZ31 Magnesium Alloy Sheets)

  • 순샤오광;진인태
    • 한국기계가공학회지
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    • 제21권3호
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    • pp.1-11
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    • 2022
  • In this study, an electric resistance dual-spot welding process using a copper electrode inserted in a heating electrode is suggested for the spot welding of AZ31 magnesium sheets. This spot-welding process involves two heating methods for welding at the interfacial zone between the magnesium sheets, one of which is the heating method by thermal conduction from the heating electrode heated by the welding current induced to the steel electrode, and the other heating method uses the electric resistance between the contacted surfaces of the two sheets by the welding current induced to the copper electrode. This welding process includes the welding variables, such as the current induced in the heating electrode and the copper electrode, and the outer diameters of the heating electrode. This is because the heat conducted from the heating electrode can be maintained at a higher temperature in the welding zone, which has a slow cooling effect on the nugget of the melted metal after the welding step. The pressure exerted during the pressing of the magnesium sheets by the heating electrode can be increased around the nugget zone at the spot-welding zone. Thus, it not only reduces the warping effect of the elastoplastic deformation of sheets, but also the corona bond can make it less prone to cracking at the welded zone, thereby reducing the number of nuggets expelled out of the corona bond. In conclusion, it was known that an electric resistance dual spot welding process using the copper electrode inserted in the heating electrode can improve the welding properties in the electric resistance spot welding process of AZ31 magnesium sheets.

Crack behaviour of top layer in layered rocks

  • Chang, Xu;Ma, Wenya;Li, Zhenhua;Wang, Hui
    • Geomechanics and Engineering
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    • 제16권1호
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    • pp.49-58
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    • 2018
  • Open-mode cracks could be commonly observed in layered rocks. A concept model is firstly used to explore the mechanism of the vertical cracks (VCs) in the top layer. Then the crack behaviour of the two-layer model is simulated based on a cohesive zone model (CZM) for layer interfaces and a plastic-damage model for rocks. The model indicates that the tensile stress normal to the VCs changes to compression if the crack spacing to layer thickness ratio is lower than a threshold. The results indicate that there is a threshold for interfacial shear strength that controls the crack patterns of the layered system. If the shear strength is lower than the threshold, the top layer is meshed by the VCs and interfacial cracks (ICs). When the shear strength is higher than the threshold, the top layer is meshed by the VCs and parallel cracks (PCs). If the shear strength is comparative to the threshold, a combining pattern of VCs, PCs and ICs for the top layer can be formed. The evolutions of stress distribution in the crack-bound block indicate that the ICs and PCs can reduce the load transferred for the substrate layer, and thus leads to a crack saturation state.

Numerical and statistical analysis of permeability of concrete as a random heterogeneous composite

  • Zhou, Chunsheng;Li, Kefei
    • Computers and Concrete
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    • 제7권5호
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    • pp.469-482
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    • 2010
  • This paper investigates the concrete permeability through a numerical and statistical approach. Concrete is considered as a random heterogeneous composite of three phases: aggregates, interfacial transition zones (ITZ) and matrix. The paper begins with some classical bound and estimate theories applied to concrete permeability and the influence of ITZ on these bound and estimate values is discussed. Numerical samples for permeability analysis are established through random aggregate structure (RAS) scheme, each numerical sample containing randomly distributed aggregates coated with ITZ and dispersed in a homogeneous matrix. The volumetric fraction of aggregates is fixed and the size distribution of aggregates observes Fuller's curve. Then finite element method is used to solve the steady permeation problem on 2D numerical samples and the overall permeability is deduced from flux-pressure relation. The impact of ITZ on overall permeability is analyzed in terms of ITZ width and contrast ratio between ITZ and matrix permeabilities. Hereafter, 3680 samples are generated for 23 sample sizes and 4 contrast ratios, and statistical analysis is performed on the permeability dispersion in terms of sample size and ITZ characteristics. By sample theory, the size of representative volume element (RVE) for permeability is then quantified considering sample realization number and expected error. Concluding remarks are provided for the impact of ITZ on concrete permeability and its statistical characteristics.