• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2696-2701
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• 2007

For the analysis of a two-phase flow, the interaction between two phases such as the interfacial momentum or heat transfer is proportional to the interfacial area. So the interfacial area concentration (IAC) is one of the most important parameters governing the behavior of each phase. This study focuses on the development of a computational fluid dynamics (CFD) code for investigating a boiling flow with a one-group IAC transport equation. It was based on the two-fluid model and governing equations were calculated by SMAC algorithm. For checking the robustness of the developed code, the experiment of a subcooled boiling in a vertical annulus channel was analyzed to validate the capability of the IAC transport equation. As the results, the developed code was confirmed to have the capability in predicting multi-dimensional phenomena of vapor generation and propagation in a subcooled boiling.

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1679-1684
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• 2011

Interfacial reactions kinetics often differ from kinetics of bulk reactions. Here, we describe how the density change of an immobilized reactant influences the kinetics of interfacial reactions. Self-assembled monolayers (SAMs) of alkanethiolates on gold were used as a model interface and the Diels-Alder reaction between immobilized quinones and soluble cyclopentadiene was used as a model reaction. The kinetic behavior was studied using varying concentrations of quinones. An unusual threshold density of quinones (${\Gamma}_c$ = 5.2-7.2%), at which the pseudo-first order rate constant started to vary as the reaction progressed, was observed. This unexpected kinetic behavior was attributed to the phase-separation phenomena of multi-component SAMs. Additional experiments using more phase-separated two-component SAMs supported this explanation by revealing a significant decrease in ${\Gamma}_c$ values. When the background hydroxyl group was replaced with carboxylic or phosphoric acid groups, ${\Gamma}_c$ was observed at below 1%. Also, more phase-separated thermodynamically controlled SAMs produced a lower critical density (3% < ${\Gamma}_c$ < 4.9%) than that of the less phaseseparated kinetically controlled SAMs (6.5% < ${\Gamma}_c$ < 8.9%).

• 전기화학회지
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• 제4권1호
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• pp.26-33
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• 2001

프랙탈 기하학의 계면 전기화학에로의 응용과 관련하여 프랙탈 전극의 임피던스 거동에 대하여 다루었다. 우선, 전기화학적 임피던스 측정시에 자주 관찰되는 constant phase element (CPE)를 간략히 설명하였고, 이와 관련하여 de Levie가 제안한 transmission line model에 대하여 다루었다. CPE현상의 해석을 위하여 Nyikos 와 Pajkossy가 제안한 프랙탈 기하학을 이용한 접근 방법을 소개하였고, 또한 프랙탈 차원과 CPE exponent 사이의 관계를 이론적으로 유도하였다 마지막으로 rough혹은 porous전극의 임피던스 거동을 설명하기 위해 제안된 여러 가지 프랙탈 모델들에 대하여 설명하였다.

• 한국고분자학회지:고분자과학과기술
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• 제6권5호
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• pp.481-487
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• 1995

• 한국자동차공학회논문집
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• 제19권3호
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• pp.52-56
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• 2011

Active regeneration in CDPF requires $O_2$ which regenerates soot at high temperature. However, small amount of NO can interrupt $O_2$ regeneration in CDPF. To verify this phenomena, soot oxidation experiments using a flow reactor with a $Pr/CeO_2$ catalyst are carried out to simulate Catalyzed Diesel Particulate Filter (CDPF) phenomena. Catalytic soot oxidation with and without small amount of NO is conducted under tight contact condition. As the heating rate rises, the temperature gap of maximum reaction rate is increased between with and without 50ppm NO. To accelerate the $NO_2$ de-coupling effect, CTO process is performed to eliminate interfacial contact for that time. As CTO process is extended, temperature which indicates peak reaction rate increases. From this result, it is found that small amount of NO can affect tight contact soot oxidation by removal of interfacial contact between soot and catalyst.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1999년도 춘계학술발표회요약집
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• pp.115-115
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• 1999

To demonstrate the applicability of RELAP5 to the prediction of the onset offlooding in the hot leg at the reflux condensation phase during mid-loop operation, numerical analysis is performed for the counter-current flow in a horizontal pipe with the inclined riser using the RELAP5/MOD3.2.2b code. It is found that the RELAP5, simulating the CCFL phenomena using interfacial friction along with the flow regime map in the horizontal pipe, produces unsatisfactory results. Under the CCFL condition, it is observed that large oscillation exists in the flow rate, void fraction, and etc. and the liquid flow rate is much lower than that predicted by the CCFL model measured in the experiment. The CCFL model of RELAP5 for the vertical volume is extended to the model for the horizontal and inclined volumes. The horizontal volume flow regime map and interfacial friction model coupled to the CCFL model are modified. And a new correlation developed from Kang's experiment is implemented to the CCFL model of RELAP5. With this modified RELAP5, the analysis of CCFL phenomena in the horizontal pipe and hot leg geometry is performed, and produces reasonable results in comparison with experimental data.

• 진공이야기
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• 제2권2호
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• pp.4-11
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• 2015

본 글에서는 광전자 분광 및 역광전자 분광을 이용한 유기분자 시스템의 전자구조 연구에 대하여 기술하였다. 다양한 유기물간의 계면 연구가 급속도로 늘어나고 있으며, 폴리머, 거대 분자 등 기존의 in situ 분석 방법으로 실험이 어려운 물질까지도 연구의 필요성이 늘어나고 있다. Electrospray 증착 방법이 이러한 새로운 물질들의 계면 전자구조 연구를 가능하게 할 수 있음을 살펴보았으며, 다양한 새로운 분석 기법들의 출현을 기대해 본다. 몇 가지 예에서 살펴본 바와 같이 전자구조는 소자 구동 특성을 직접적으로 지배하는 핵심적인 물리량이며, 전자구조의 이해를 통해 전자소자의 구동 원리, 성능 최적화 및 소자 특성 열화의 원인을 파악할 수 있다. 현재, 유기물 소자 관련 기술의 성숙도는 전자구조 분석과 같은 기초 연구 결과 없이는 더 이상 발전할 수 없는 정도에 이르러, 관련 분석 기술에 대한 수요가 더욱 늘어날 것으로 전망된다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.116-120
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• 2001

Fiber fracture is one of the dominant failure phenomena to determine total mechanical properties in composites. Fiber fracture locations were measured by optical microscopic method and acoustic emission (AE) as functions of matrix toughness and surface treatment by the electrodeposition (ED), and then two methods were compared. Two AE sensors were attached on the epoxy specimen and fiber fracture signals were detected with elapsed time. The interfacial shear stress (IFSS) was measured using tensile fragmentation test and AE system. In ED-treated case, the number of the fiber fracture measured by an optical method and AE was more than that of the untreated case. The signal number measured by AE were rather smaller than the number of fragments measured by optical method, since some fiber fracture signals were lost while AE detection. However, one-to-one correspondence between the x-position location by AE and real break positions by optical method was generally established well. The fiber break source location using AE can be a valuable method to measure IFSS for semi- or nontransparent matrix composites nondestructively (NDT).

• 대한기계학회논문집B
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• 제39권8호
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• pp.677-682
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• 2015

격자 볼츠만 기법(Lattice Boltzmann method)을 사용하여 에멀전의 유변학적 특성을 파악하기 위한 시뮬레이션을 수행하였다. 간단한 전단 유동하에서 온도와 전단속도, 계면장력에 변화를 주어 에멀전(decane-in-water)의 상대점도를 계산하고 이를 분석하였다. 에멀전의 상대점도는 온도가 증가함에 따라 감소하였고, 전단속도가 증가함에 따라 감소하는 전단박하(Shear thinning) 현상을 보여주었다. 이는 크로스 모델(Cross model)을 통해 검증하였고 일치하는 경향을 보여주었다. 계면에 존재하는 계면활성제(Surfactant)를 통해 제어되는 계면장력이 증가할수록 상대점도는 감소하는 경향을 보여주었다. 이것은 큰 계면장력에서는 기름방울의 변형이 억제되고 점도가 상대적으로 높은 기름방울의 표면적이 감소하면서 나타난다고 해석할 수 있다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.127-132
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• 2003

A study of high-pressure n-heptane droplet vaporization is conducted with emphasis placed on equilibrium at vapor-liquid interface. General frame of previous rigorous model[1] is retained but tailored for flash equilibrium calculation of vapor-liquid interfacial thermodynamics. The model is based on complete time-dependent conservation equations with a full account of variable properties and vapor-liquid interfacial thermodynamics. The influences of high-pressure phenomena, including ambient gas solubility, thermodynamic non-ideality, and property variation on the droplet evaporation are investigated. The governing equations and associated moving interfacial boundary conditions are solved numerically using a implicit scheme with the preconditioning method and the dual time integration technique. And a parametric study of entire droplet vaporization history as a function of ambient pressure, temperature has been conducted. Some computational results are compared with Sato's experimental data for the validation of calculations. For low ambient temperatures, the droplet lifetime first increases with pressures, then decreases for high pressures. For higher ambient temperatures, the droplet lifetime increase with less amplitude than that of low ambient temperatures, which then decreases with more amplitude than that of low temperatures. The solubility of nitrogen can not be neglected in the high pressure and it becomes higher as the pressure goes up.