• Title/Summary/Keyword: Interface temperature

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Sintering and Electrical Properties of Cr-doped ZnO-Bi2O3-Sb2O3 (Cr을 첨가한 ZnO-Bi2O3-Sb2O3계의 소결과 전기적 특성)

  • Hong, Youn-Woo;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.942-948
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    • 2010
  • In this study we aims to examine the effects of 0.5 mol% $Cr_2O_3$ addition on the reaction, microstructure development, resultant electrical properties, and especially the bulk trap and interface state levels of ZnO-$Bi_2O_3-Sb_2O_3$ (Sb/Bi=0.5, 1.0, and 2.0) systems (ZBS). The samples were prepared by conventional ceramic process, and characterized by XRD, density, SEM, I-V, impedance and modulus spectroscopy (IS & MS) measurement. The sintering and electrical properties of Cr-doped ZBS (ZBSCr) systems were controlled by Sb/Bi ratio. Pyrochlore ($Zn_2Bi_3Sb_3O_{14}$) was decomposed more than $100^{\circ}C$ lowered on heating in ZBS (Sb/Bi=1.0) by Cr doping. The densification of ZBSCr (Sb/Bi=0.5) system was retarded to $800^{\circ}C$ by unknown Bi-rich phase produced at $700^{\circ}C$. Pyrochlore on cooling was reproduced in all systems. And $Zn_7Sb_2O_{12}$ spinel ($\alpha$-polymorph) and $\delta-Bi_2O_3$ phase were formed by Cr doping. In ZBSCr, the varistor characteristics were not improved drastically (non-linear coefficient $\alpha$ = 7~12) and independent on microstructure according to Sb/Bi ratio. Doping of $Cr_2O_3$ to ZBS seemed to form $Zn_i^{..}$(0.16 eV) and $V^{\bullet}_o$ (0.33 eV) as dominant defects. From IS & MS, especially the grain boundaries of Sb/Bi=0.5 systems were divided into two types, i.e. sensitive to oxygen and thus electrically active one (1.1 eV) and electrically inactive intergranular one (0.95 eV) with temperature.

Functional Verification of Nylon Wire Cutting-Type Holding & Release Mechanism for 6U CubeSat's Solar Panel (나일론선 절단방식 6U 큐브위성용 태양전지판 구속분리장치의 기능검증)

  • Park, Yeon-Hyeok;Go, Ji-Seong;Chae, Bong-Geon;Lee, Seong-Ho;Oh, Hyun-Ung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.10
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    • pp.867-875
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    • 2018
  • Conventional nylon wire cutting-type holding and release mechanisms (HRMs) are limited to securely hold the solar panel under launch environment as the size of the panel increases because the nylon wire is tightened directly on the surface of the solar panel. In this study, we proposed a nylon wire cutting-type HRM for 6U CubeSat's solar panel applying elliptic-shaped bracket with a Ball & Socket interface. The proposed HRM has the advantage of higher holding capability along in-plane and out-of plane directions of solar panel and simplicity in tightening process of nylon wire. The design drivers of structural design of CubeSat's solar panel with the proposed HRM were defined by structural analysis under launch loads. In addition, The design effectiveness of the proposed HRM was verified through the functional tests according to the thickness of nylon wire and the number of wire winding under various temperature conditions.

Evaluation of Companion Crop for Conservation of Soil in Highland Cultivativation of Chinese Cabbage (고랭지배추 재배지 토양보전을 위한 동반작물 도입 평가)

  • Kim, Ki-Deog;Ahn, Jae-Hoon;Lee, Jeong-Tae;Hong, Soon-Choon;Hwang, Seon-Woong;Kim, Chung-Guk
    • Journal of Bio-Environment Control
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    • v.17 no.1
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    • pp.1-8
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    • 2008
  • Four cover plants such as Phlox subulata, Glechoma hederacea var. longituba, Sedum middendorffianum and Saxifraga laciniata were evaluated to investigate the effect of companion planting on reducing soil erosion in Chinese cabbage cultivated highland. The experiment was conducted using lysimeters of $5\;m{\times}2\;m$ (length$\times$width) with 5, 15 and 30% slopes. Companion plants except Sedum middendorffianum did not interface with growth of Chinese cabbage Glechoma hederacea var. longituba and Sedum middendorffianum grew faster than Phlox subulata and Saxifraga laciniata in the early growth stage suer transplanting, resulting in fast ground covering, but the ground covering by Phlox subulata and Saxifraga laciniata was delayed because growth suppression by high air temperature during summer season. Soil erosion became severe as increasing degree of slope. Assessments of the four cover plants were conducted in relation to soil conservation characteristic of scenery, endurance to the environment stress, plant growth and weed suppression. From the assessments, Phlox subulata was superior to other intercropping crops tested for reducing soil erosion in highland cultivation of Chinese cabbage.

A Study on the Measurement Method for Benthic Nutrient Flux in Freshwater Sediments (담수 퇴적물의 영양염 용출 측정 방법에 관한 고찰)

  • Kim, Kyung Hee;Kim, Sung-Han;Jin, Dal Rae;Huh, In Ae;Hyun, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.5
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    • pp.288-302
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    • 2017
  • Accurate measurement of benthic nutrient fluxes (BNF) is a prerequisite for evaluating the effect of sediments on nutrient cycle in the surface water. The intact sediment cores were collected in July 2015 at the midstream of Nakdong River. We identified pre-incubation time (6, 12, 24 hr), dissolved oxygen concentration (90, 70, 50% saturation), diffusive boundary layer thickness (0, 0.6-0.8, 1.2-1.4 mm), and incubation temperature (10, 17, 20, $25^{\circ}C$) as the most important control factors, and measured the BNF fluctuation with the variation of these factors using the laboratory sediment core incubation method. Since the chemical composition, redox condition, hydrodynamic regimes and microbial activities at the sediment-water interface were changed as a result of the alteration of control factors, sediment core incubation should be conducted under as close to the natural conditions of study site as possible, in order to produce the results similar to actual values. Relative percentage differences between two replicates were below 20% in most control factors, which showed satisfactory precision for strict compliance with the experimental conditions and procedures. In the further studies, we will compare the results of core incubation with those of in situ measurements to confirm the accuracy of the sediment core incubation method.

N2O and CH4 Emission from Upland Forest Soils using Chamber Methods (플럭스챔버에 의한 N2O와 CH4의 산림에서의 토양배출량 측정연구)

  • Kim, Deug-Soo;Kim, Soyoung
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.789-800
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    • 2013
  • $N_2O$ and $CH_4$, Greenhouse gas emission, Forest soil, Closed chamber technique, Soil uptake $N_2O$ and $CH_4$ are important greenhouse gases (GHG) along with $CO_2$ influencing greatly on climate change. Their soil emission rates are highly affected by bio-geo-chemical processes in C and N through the land-atmosphere interface. The forest ecosystems are generally considered to be net emission for $N_2O$; however, net sinks for $CH_4$ by soil uptake. Soil $N_2O$ and $CH_4$ emissions were measured at Mt. Taewha in Gwangju, Kyeonggi, Korea. Closed chamber technique was used for surface gas emissions from forest soil during period from May to October 2012. Gas emission measurement was conducted mostly on daytime (from 09:00 to 18:00 LST) during field experiment period (total 25 days). The gas samples collected from chamber for $N_2O$ and $CH_4$ were analyzed by gas chromatography. Soil parameters were also measured at the sampling plot. GHG averages emissions during the experimental period were $3.11{\pm}16.26{\mu}g m^{-2}hr^{-1}$ for $N_2O$, $-1.36{\pm}11.3{\mu}gm^{-2}hr^{-1}$ for $CH_4$, respectively. The results indicated that forest soil acted as a source of $N_2O$, while it acted like a sink of $CH_4$ on average. On monthly base, means of $N_2O$ and $CH_4$ flux during May (spring) were $8.38{\pm}48.7{\mu}gm^{-2}hr^{-1}$, and $-3.21{\pm}31.39{\mu}gm^{-2}hr^{-1}$, respectively. During August (summer) both GHG emissions were found to be positive (averages of $2.45{\pm}20.11{\mu}gm^{-2}hr^{-1}$ for $N_2O$ and $1.36{\pm}9.09{\mu}gm^{-2}hr^{-1}$ for $CH_4$); which they were generally released from soil. During September (fall) $N_2O$ and $CH_4$ soil uptakes were observed and their means were $-1.35{\pm}12.78{\mu}gm^{-2}hr^{-1}$ and $-2.56{\pm}11.73{\mu}gm^{-2}hr^{-1}$, respectively. $N_2O$ emission was relatively higher in spring rather than other seasons. This could be due to dry soil condition during spring experimental period. It seems that soil moisture and temperature mostly influence gas production and consumption, and then emission rate in subsoil environment. Other soil parameters like soil pH and chemical composition were also discussed with respect to GHG emissions.

Study on Color Formation of Cheolhwa Buncheong Stoneware Glaze by Pigment Raw Materials of Iron Oxides and Firing Conditions (철산화물 안료 원료와 번조조건에 따른 철화분청사기의 유약 발색 연구)

  • Kim, Ji Hye;Han, Min Su;Jeong, Young Yu;Choi, Sung Jae
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.573-587
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    • 2019
  • In this study, reproducing specimens were made from mixing domestically produced magnetite, clay and non-plastic raw materials to reproduce the pigments used in the manufacture of traditional cheolhwa buncheong stoneware. In order to reveal the color fomation of glaze, 30 specimens with good color development were analyzed scientifically. Magnetite, which is the main raw material of the pigment, is a pigment capable of creating a dark black color in a reducing environment at 1,200℃. However, it reacts with the additionally added lime component and discolors to greenish yellow color in oxidizing environment at 1,230℃. Hematite is not significantly affected by the firing temperature and environment, but develops a dark black color when mixed with clay with iron content of more than 10%. The fluidity of the pigment is determined by R2O3/RO2 value, which also affects the color development. In the microtexture observation, the color formation of the glaze layer and the iron oxide crystals identified some differences depending on the particle size of the pigment and the firing environment. Reproduced specimens made of magnetite are present in the form of aggregates of iron oxide in the interface between glaze layer and slip layer in the oxidizing environment at 1,200℃. However, in the reducing environment, aggregates of iron oxides do not exist in the reproduced specimens, and they are homogeneously distributed in the glaze layer and formed a dark black color. In contrast, hematite-based specimens form dendritic structures in the glaze layer in an oxidizing environment and develop black.

POLYMERIZATION SHRINKAGE, HYGROSCOPIC EXPANSION AND MICROLEAKAGE OF RESIN-BASED TEMPORARY FILLING MATERIALS (레진계 임시수복재의 중합수축, 수화팽창과 미세누출)

  • Cho, Nak-Yeon;Lee, In-Bog
    • Restorative Dentistry and Endodontics
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    • v.33 no.2
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    • pp.115-124
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    • 2008
  • The purpose of this study was to measure the polymerization shrinkage and hygroscopic expansion of resin-based temporary filling materials and to evaluate microleakage at the interface between the materials and cavity wall. Five resin-based temporary filing materials were investigated: Fermit (Vivadent), Quicks (Dentkist), Provifil (Promedica), Spacer (Vericom), Clip (Voco). Caviton (GC) was also included for comparison. Polymerization shrinkage of five resin-based temporary filling materials was measured using the bonded disc method. For the measurement of hygroscopic expansion, the discs of six cured temporary filling materials were immersed in saline and a LVDT displacement sensor was used to measure the expansion for 7 days. For estimating of microleakage, Class I cavities were prepared on 120 extracted human molars and randomly assigned to 6 groups of 20 each. The cavities in each group were filled with six temporary filling materials. All specimens were submitted to 1000 thermocycles, with temperature varying from $5^{\circ}C/55^{\circ}C$. Microleakage was determined using a dye penetration test. The results were as follows: 1. Fermit had significantly less polymerization shrinkage than the other resin-based temporary fill ing materials. Fermit (0.22%) < Spacer (0.38%) < Quicks (0.64%), Provifil (0.67%), Clip (0.67%) 2. Resin-based temporary filling materials showed 0.43-1.1% expansion in 7 days. 3. Fermit showed the greatest leakage, while Quicks exhibited the least leakage. 4. There are no correlation between polymerization shrinkage or hygroscopic expansion and microleakage of resin-based temporary filling materials.

Friction and Wear Behavior of Ultra-Thin TiN Film during Sliding Wear against Alumina and Hardened Steel (마모 상대재 변화에 따른 TiN 극박막의 마찰 및 마모거동)

  • Song, Myeong-Hun;Lee, Jae-Gap;Kim, Yong-Seok
    • Korean Journal of Materials Research
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    • v.10 no.1
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    • pp.62-68
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    • 2000
  • Ultra thin TiN films (50∼700nm thickness) were deposited on AISI 304 stainless steel substrates using a reactive DC magnetron sputtering deposition process to investigate their wear and friction properties. Dry sliding wear tests of the films were carried out against hardened steel and alumina counterparts using a pin-on-disk type wear tester at room temperature. Variation of friction coefficient was measured as a function of film thickness, load, sliding speed and roughness of the substrate. Worn surfaces of the film were examined by a scanning electron microscope. Wear resistance of the TiN film increased with the increase of the film thickness. The TiN film showed relatively high wear resistance in spite of its ultra thin thickness when it is mated by the steel counterpart, while it showed poor wear resistance with the alumina counterpart. The good wear resistance with the steel counterpart was explained by the formation of oxide layers on the film surface and sound interface character between the ultra thin film and the substrate.

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Integrated Network System of Milk Cow Stock-Farming Facilities for Stockbreeding Management (사양관리를 위한 젖소 목장 시설 통합 네트웍 시스템)

  • 김지홍;이수영;김용준;한병성;김동원
    • Journal of Animal Environmental Science
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    • v.8 no.3
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    • pp.199-208
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    • 2002
  • This paper introduces the method to make management network about milking cow farm tasks. The object of this research was to design of biological measuring system and managing network system in a livestock farm. This auto-management system provides informations about individual cows' temperature, conductivity of milk and weight for efficient management of feeding, and milking works by a micro-processor and RS -485 type serial COM. ports. And measured bio-data which are basic informations for remote raising management are saved to user PC by serial communication between the PLC and user PC. Milking cow farm is divided into three working place to each measurement work and feed. The first working place is milking station which has two thermometers, a conduct meter and a scale set. The second working place is feeding station, and the third place is cattle cage. These are combined by network system and the PLC which is used to drive network and sub-modules. Sub-modules have a micro-process to control the sensor and to interface with network. The PLC which drive network and control sequence has two serial communication port to be linked with user PC for sending the measured data and for receiving data. Above all, in this study tells the sequence operating method by the driving scenario of breeding milk cow for livestock auto-management using the PLC and network system.

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Geochemistry and Mineralogy of Metapelite and Barium-Vanadium Muscovite from the Ogcheon Supergroup of the Deokpyeong Area, Korea (덕평지역(德平地域)의 옥천누층군(沃川累層群)에 분포(分布)하는 변성이질암(變成泥質岩)과 바륨-바나듐 백운모(白雲母)의 지구화학적(地球化學的) 및 광물학적(鑛物學的) 특성(特性))

  • Lee, Chan Hee;Lee, Hyun Koo
    • Economic and Environmental Geology
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    • v.30 no.1
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    • pp.35-49
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    • 1997
  • The coal formation of the Deokpyeong area are interbedded along metapelites of the Ogcheon Supergroup, which are composed mainly of graphite, quartz, muscovite and associated with small amounts of biotite, chlorite, pyrite and barite. The ratios of $SiO_2/Al_2O_3$, $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ of the coaly metapelite are variable and wide range from 1.80 to 10.21, from 27.8 to 388.8 and from 7.6 to 61.8, respectively. These coal formation were deposited in basin of marine environments, and the REE of these rocks are not influenced with metamorphism and hydrothermal alterations on the basis of $Al_2O_3$ versus La, La against Ce, the ratios of La/Ce (0.19 to 0.99) and Th/U (0.02 to 4.75). These rocks also show much variation in $La_N/Yb_N$ (1.19 to 22.89), Th/Yb (0.14 to 21.43) and La/Th (0.44 to 13.67), and their origin is explained by derivation from a mixture of sedimentary and igneous rocks. The wide range in trace and REE element characteristics as Co/Th (0.12 to 2.78), La/Sc (0.33 to 10.18), Sc/Th (0.57 to 5.73), V/Ni (8 to 2347), Cr/V (0.02 to 0.67) and Ni/Co (1.56 to 32.95) of these coaly metapelites argues for inefficient mixing of the various source lithologies during sedimentation. Deep to pale green barium-vanadium muscovites (vanadium-oellacherite) have been found in this coal formations. Modes of occurrence and grain size of muscovite are heterogeneous, but most of the barium and vanadium-bearing muscovites occur along the boundaries between graphite and quartz grains, ranging from 200 to $350{\mu}m$ in length and from 40 to $60{\mu}m$ in width. Results of X-ray diffraction data of the minerals characterized to be monoclinic system with $a=5.249{\AA}$, $b=8.939{\AA}$, $c=20.924{\AA}$ and ${\beta}=95.894^{\circ}$. Representative chemical formula of the muscovite was $(Na_{0.09}K_{1.44}Ba_{0.46})(Al_{2.75}Ti_{0.07}V_{0.56}Fe_{0.08}Mg_{0.50})(Si_{6.12}Al_{1.88})O_{22}$. The V possibly substitute octahedral Al, and the Ba is coupled substitution of $K^+Si^{4+}=Ba^{2+}Na^+Ca^{2+}$, which compositional ranges of V and Ba are from 0.42 to 0.69 and from 0.34 to 0.56 based on $O_{22}$, respectively. Formation mechanism of the barium-vanadium muscovites in the coaly metapelite is shown that the formed by high pressure and temperature from regional metamorphism origanated during diagenesis at the interface between a basinal brine and organic matter.

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