• Title/Summary/Keyword: Instrumental Analysis Method

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Analysis of the hazardous RoHS materials in polyethylene and polypropylene samples by bench-top and portable XRF methods (탁상형 및 휴대형 X-선 형광 분석기를 이용한 폴리에틸렌 및 폴리프로필렌 시료 중 RoHS 규제 물질의 비교 분석)

  • Choi, Soo-Jung;Kim, Chong-Hyeak;Lee, Sueg-Geun;Kang, In-Sung
    • Analytical Science and Technology
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    • v.23 no.1
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    • pp.74-82
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    • 2010
  • As a basic research for development of the domestic portable XRF spectrometer, we discussed the analytical results of bench-top and portable XRF methods for RoHS materials of the Cd, Pb, Hg, Cr(IV), polybrominated biphenyls(PBB) and polybrominated diphenyl ehters(PBDE). The instrumental parameters such as measurement time of bench-top and portable XRF were optimized using certified reference materials of polyethylene and polypropylene with 5 hazardous materials of 0~1,200 mg/kg. The quantitative analysis of total-Cr, total-Br, Cd, Hg and Pb in certified reference materials and plastic samples were compared by empirical method, fundamental parameter method of bench-top XRF and portable XRF.

Antioxidant Activity of 2,3,6-Tribromo-4,5-dihydroxy benzyl methyl ether from Symphyocladia latiuscula

  • Park Hye Jin;Chung Hae Young;Kim Jong;Choi Jae Sue
    • Fisheries and Aquatic Sciences
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    • v.2 no.1
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    • pp.1-7
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    • 1999
  • Antioxidant activity of a methanol extract of Symphyocladia latiuscula was evaluated by the thiocyanate method in the linoleic acid system. The methanol extract inhibited the peroxidation of linoleic acid in a dose-dependent manner. The MeOH extract was then sequentially partitioned with n-hexane, $CH_2Cl_2$, EtOAc, n-BuOH and H20. The antioxidant activity of the fractions increased in order of $CH_2Cl_2$, n-hexane, EtOAc, and n-BuOH. There was no activity found in $H_2O$ partitoned fraction by the thiocyanate method. Especially, the activities of the fractions of n-hexane and $CH_2Cl_2$ were comparable to that of 2,6-di-tert­butylhydroxytoluene (BHT). Column chromatography of the $CH_2Cl_2$ fraction over silica gel yielded cholesterol (1) and 2,3,6-tribromo 4,5-dihydroxybenzyl methyl ether (2) which were identified by instrumental analysis of MS and $^1H-$ and $^{13}C-NMR$. The latter (2) demonstrated significant antioxidant activity.

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Simultaneous Analysis of the Coloring Compounds in Indigo, Phellodendron bark, and Madder Dye Using HPLC-DAD-MS

  • Ahn, Cheunsoon;Zeng, Xia;Obendorf, S. Kay
    • Journal of the Korean Society of Clothing and Textiles
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    • v.37 no.6
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    • pp.827-836
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    • 2013
  • Indigotin, indirubin, berberine, palmatine, alizarin, and purpurin are major pigments of indigo plant, Phellodendron bark, and madder. The six pigments were examined using the HPLC-DAD-MS instrument for the purpose of the simultaneous detection of the pigments in a single sample run. The HPLC-DAD-MS method examined the individual pigment solutions in DMSO, a solution containing 6 pigments, and the DMSO extract of the silk dyed with a dye solution of 5 pigments excluding indirubin. The retention times of the HPLC chromatograms, ${\lambda}_{max}$ of the uv-vis absorption bands in the DAD analyses, and the molecular ions detected for the compound peaks in the MSD analyses were consistent throughout the analyses of individual pigment solutions, mixed pigment solutions, and dye extracted from silk dyeing. The developed instrumental method of the simultaneous detection of six pigments can identify dye in an exhumed textile if the textile is dyed using any one (or multiple) pigments of indigo, Phellodendron bark, or madder plant.

Effect on Mechanical Properties of 3Y-TZP; (II) Addition of Alumina (3Y-TZP의 기계적 물성에 미치는 영향: (II) 알루미나의 첨가)

  • Yang, Seong-Koo;Bae, Kyung-Man;Cho, Bum-Rae;Kang, Jong-Bong
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.417-424
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    • 2005
  • Although a lot of studies in fracture toughness of Y-TZP ceramics for structural applications have been done, it remains an important challenge to be able to improve fracture toughness of Y-TZP ceramics. In this research, milling method adding monoclinic zirconia and $Al_2O_3$ to 3Y-TZP was introduced to improve the fracture toughness of 3Y-TZP. Experimental results showed that addition of small amount of $Al_2O_3$ causes to make lots of oxygen vacancies (VO) by substituting $Al^{3+}$ for $Zr^{4+}$. It is believed that the produced vacancies provides useful routes far mass transfer. Y-TZP ceramics having higher microhardness and better fracture toughness was fabricated by sintering at $1400^{\circ}C$.

Effect on Mechanical Properties of 3Y-TZP; (I) Addition of Monoclinic Zirconia (3Y-TZP의 기계적 물성에 미치는 영향: (I) 단사정지르코니아의 첨가)

  • Yang, Seong-Koo;Bae, Kyung-Man;Cho, Bum-Rae;Kang, Jong-Bong
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.411-416
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    • 2005
  • Y-TZP(Yttria-stabilized Tetragonal Zirconia Polycrystal) ceramics are of great interest as engineering and structural materials due to their excellent mechanical properties arising from transformation toughening, it is also reported that the 3Y-TZP($3 mol\%$ Yttria-stabilized Tetragonal Zirconia Polycrystal) has the best mechanical properties in Y-TZP ceramics. But to use widely for engineering and structural materials, it remains an important challenge to be able to improve its fracture toughness. In order to produce the 3Y- TZP ceramics showing much better mechanical properties, milling method adding monoclinic zirconia to 3Y-TZP was adopted and the resultant mechanical properties containing apparent density and fracture toughness were measured by using proper techniques. Experimental results showed that the 3Y-TZP specimen containing $33 wt\%$ of monoclinic zirconia, which was sintered at $1450^{\circ}C$, has the highest fracture toughness value of $11.38 MPa{\cdot}m^{1/2}$ which is three times higher than that of normal 3Y-TZP ceramics.

The Relationships among Food Image, Tourist Satisfactions and Destination Loyalty Intention: A Case of Hanoi Local Cuisine

  • Tu, Minh;Lee, Kwang-Woo;Park, Soo-Han
    • Culinary science and hospitality research
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    • v.23 no.6
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    • pp.70-77
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    • 2017
  • The purpose of this study was to examine tourist satisfaction towards Hanoi local food image as well as examine the relationship between those two variables with tourist destination loyalty intention. A self-administered survey was carried out in Hanoi, Vietnam. Of the distributed 400 questionnaires, a total 393 respondents of foreign tourists were used to data analysis by a convenience sampling method. Factor analysis was performed to identify underlying dimensions of what foreign tourists expect most from Hanoi local food image. The results showed that foreign tourist perceived Hanoi local food image as, food quality, food culture, contexture features and atmospheric. The finding showed that Hanoi local food image had a direct effect on foreign tourist's satisfaction and destination loyalty intention. In addition, tourist satisfaction had a positive influence on destination loyalty intention. At last, considering the results from this study, it is suggested that it is necessary to create and maintain the identity of image by formulating appropriate strategies and it is instrumental to promote local food image based on its distinctiveness and diversity which stands for the unique native culture.

Subsidy Rationalisation for General Purpose Flour: Market and Economics Implications

  • Kari, Fatimah Binti;Masud, Muhammad Mehedi;Saifullah, Md. Khaled
    • The Journal of Asian Finance, Economics and Business
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    • v.4 no.2
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    • pp.25-36
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    • 2017
  • Subsidies are an instrumental policy making tool for many governments, but their importance depends on the market situation of the national economy. Efficient subsidy implementation would allow the government to correct market failure thereby aligning social and private costs and benefit. The general objective of this study is to justify the need to rationalise subsidies for food items such as flour. This study assessed the structure and conducts of the general purpose flour market in Malaysia; and analysed the impact of subsidies on market performance to recommend policies to increase market efficiency under the subsidy rationalisation program. To accomplish these objectives, the study adopted a microeconomics market analysis as well as the standard structure and performance analysis method. These two approaches showed the characteristics of an industry's consumer behaviour, competition, as well as the efficiency associated with government regulatory policies on the flour industry. One of the biggest influences on the domestic market is related to the food consumption behaviour of the general population. Food consumption behaviour reflects global trends. As income rises, food trends tend to be consumed in processed form or in such a way that adds value in another manner such as the preparation of food products.

Generation of Artificial Acceleration-Time Histories for the Dynamic Analysis of Structures in the Korean Peninsula (구조물(構造物)의 동적해석(動的解析)을 위한 한반도(韓半島)의 인공지진파(人工地震波) 작성(作成))

  • Kim, Won Bae;Yu, Chul Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.3
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    • pp.39-47
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    • 1990
  • The generation of artificial accelerograms considering the characteristic of earthquakes in the Korean peninsula for a time history analysis of structures is accomplised by the stochastic method. The engineering data such as a representative shape of envelope function and an effective duration are investigated from the instrumental records. The maximum ground acceleration value is based on seismic zoning map which are constructed for the Korean peninsula. The acceleration-time histories are generated for two different types of earthquake motions and two types of soil conditions. In the study, the maximum ground acceleration value of 0.2 g and effective durations of 24 seconds are used. The validity of the artificial accelerograms is obtained by the comparison with the required envelope functions and the design response spectrum.

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A Study on the Post-purchase Satisfaction of Clothing related to Clothing Type and Sex (의류제품유형 및 성별에 따른 구매후 만족에 관한 연구)

  • 김지영;박재옥
    • The Research Journal of the Costume Culture
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    • v.10 no.1
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    • pp.49-59
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    • 2002
  • The type of product and consumer characteristis have known to play an important role in the post-purchase behavior. The issue related to the effects of clothing type and sex on the process of consumer satisfaction formation, would be helpful to understand the past-purchase consumer behavior. Therefore, the objective of this study was to clarify differences in the process of satisfaction formation in relation to clothing type and sex. The study was conducted in three steps. Through the two steps, measurement instruments were developed. At the last step, judgement sampling method was utilized to collect the data and subjects were 614 university students. Factor analysis and path analysis were used to analyze the data. The process of consumer satisfaction formation in formal wear and casual wear showed some differences. In the case of format wear, only expressive product performance was found to play an important role in the process of consumer satisfaction formation. However in the case of casual wear, both expressive and instrumental product performances had influence upon clothing satisfaction directly or through consumption emotion. The results revealed a similar tendency in the process of satisfaction formation between male and female groups. However in the male group the consumption emotion had a greater effect on the process of consumer satisfaction formation than in the female group it did.

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The Analysis of Positional Accuracy with Input/Output Instruments in Digital Mapping of National Base Map (국가기본도 수치지도제작 과정에서 입출력장비에 따른 위치정확도 분석)

  • 이현직;손덕재
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.16 no.2
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    • pp.291-297
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    • 1998
  • In order to accomplish the digital map production I/O devices should be used which are used for data input procedure to convert original paper map(hardcopy) data into computer compatible digital map data, and for the mapsheet output procedure of worked out data. For the input device, digitizer and scanner are most frequently used. Digitizer has possibility of direct production of digital data, and are mainly used for input procedure of partly plotted source map. In contrary, scanner is rather easy to operate the instrument, so that is widely used for the input procedure of original sheet map. In this study, to extract the input device characteristics, some kinds of digitizers and scanners were cheesed and used for the positional error analysis through the operational method and types of instruments. Also for the output device characteristics, some kinds of plotter and materials are used and compared to analyze the positional error through the instrumental types and output sheet materials.

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