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Preparation and Characterization of Polymer Coated BaTiO3 and Polyimide Nanocomposite Films (고분자로 표면 코팅된 BaTiO3와 이를 이용한 폴리이미드 나노복합필름의 제조 및 특성)

  • Han, Seung San;Han, Ji Yun;Choi, Kil-Yeong;Im, Seung Soon;Kim, Yong Seok
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.527-531
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    • 2006
  • We have prepared organophilic inorganic particles and polyimide (PI) nanocomposite having excellent thermal stability and high dielectric constant that can be used for electronic application such as capacitor. We have chosen barium titanate (BT), a high dielectric constantmaterial and its surface was coated with nylon 6 to improve the affinity with PI. The FT-IR and TEM studies showed that the organophilic inorganic particle (BTN) has a polymer shell with thickness of 5 nm. We have suggested that it is possible to control the thickness of coating surface and also indicated the relationship between the ratio of inside and outside radius of BTN and the weight fraction of BT. The PI nanocomposite films based on poly(amic acid) and BTN were prepared by cyclodehydration reaction. The homogeneous dispersion of BTN in PI matrix was identified by using SEM. We have investigated the effect of BTN content on the coefficient of thermal stability, integral procedural decomposition temperature (IPDT), and dielectric constant of PI nanocomposite films.

Mechanical Properties and Stress-Strain Model of Re-Bars Coldly Bent and Straightened (굽힌 후 편 철근의 기계적 성질과 응력-변형률 모델)

  • Chun, Sung-Chul;Tak, So-Young;Ha, Tae-Hun
    • Journal of the Korea Concrete Institute
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    • v.24 no.2
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    • pp.195-204
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    • 2012
  • In the construction of high-rise buildings, bent re-bars are manually straightened to connect slabs to core-walls, which are usually cast before floor structures. During cold bending and straightening of re-bars, plastic deformation causing work hardening, Bauschinger effect and aging hardening is unavoidable. Tensile tests of coldly bent and straightened re-bars were conducted with test parameters of grade, diameter, and bend radius of re-bars as well as age between bending and straightening. Test results showed that proportional limits were lower and strain hardening occurred without yield plateaus. Inside and outside of re-bars with compression and tension deformations, respectively, during bending showed lower yield points due to Bauschinger effect and no yield plateaus due to work hardening, respectively. When re-bar grade was higher, yield point became significantly lower where Grade 400 re-bars had yield strengths lower than specified yield strength of 400 MPa. Because the surface of re-bar has higher strength than the core of re-bar, Bauschinger effect was more obvious for higher-grade re-bars. When age between bending and straightening was greater, yield strength increased and elongation decreased (i.e. embrittlement occurs). Using measured data, stress-strain relationship for straightened re-bars was developed based on Ramberg-Osgood model, which can be used to evaluate stiffness of joints when straightened re-bars are applied.

Design Study of Engine Inlet Duct for Measurement Improvement of the Flow Properties on AIP (AIP면 유동측정 정확도 향상을 위한 가스터빈엔진 입구덕트 설계 연구)

  • Im, Ju Hyun;Kim, Sung Don;Kim, Yong Ryeon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.3
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    • pp.49-55
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    • 2017
  • In this study, gas turbine engine inlet duct was designed to satisfy uniform flow at aerodynamic interface plane (AIP). Haack-series was selected as nose cone profile and duct outer radius($r_o$) was designed to satisfy to match with area change rate between the nose cone and outer duct wall by the 1-D sizing. The design object of the inlet duct wall profile which has the gradual area change rate was uniform Mach number in the core flow region and minimum boundary later thickness at the both inner nose wall and outer duct wall. The flow characteristics inside the inlet duct was evaluated using CFD. The static pressure distribution at the AIP showed uniform pattern within 0.16%. Based on Mach number profile, the boundary layer thickness was 2% of channel height. Kiel temperature rake location was decided less than 100 mm in front of nose cone where the Mach number is less than 0.1 in order to maximize the temperature probe recovery rate.

A Study on the Structural Analysis with Geometry Design for Dome of a Composite Pressure Vessel (복합재 압력용기의 돔형상 설계에 따른 구조 해석)

  • Kim, Minsik;Bae, Joochan;Kim, Donggeon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.825-831
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    • 2017
  • In this study, we perform the design of dome geometry for the composite pressure vessel with applying the equation of Fulton and Vasiliev considering external load(thrusts). Variables of the dome geometry are opening radius ratio(${\rho}_0$) from 0.1 to 0.5 and thrust level from 40kN to 200kN. We conduct Finite Element Analysis(FEA) by using ABAQUS. As a result, the strain of the composite pressure vessel has shown strain gradient from inner to outer of dome surface. And the strain gradient may cause crack of resin inside the composite laminate. Strain gradient of Fulton dome is monotonously decreased as the ${\rho}_0$ increases, but the strain gradient of Vasiliev dome bas shown some different trend. when ${\rho}_0{\leq}0.1$, strain gradient of Fulton's is higher than Vasiliev's. But when 0.1<${\rho}_0$<0.35, strain gradient of Vasiliev's becomes higher than Fulton's. And in the case of $0.35{\leq}{\rho}_0$, strain gradient of Vasiliev's is higher than Fulton's. So the Vasiliev dome is more effective in ${\rho}_0{\leq}0.1$ condition and Fulton dome is more effective in $0.35{\leq}{\rho}_0$ condition. So, it's important for dome design to consider the crack of resin cause of the strain gradient.

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A Numerical Study of Tumble Effect on Spray/wall Impingement in the D. I. Engines (직접분사식 엔진내의 분무/벽 충돌 현상에서 텀블 효과에 관한 연구)

  • Chae, Soo;Yang, Hyup;Ryou, Su-Yeal;Ryou, Hong-Sun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.5
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    • pp.45-57
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    • 2002
  • In this paper, the results gained by applying many impingement models to the cylinder and flat plate were analyzed in comparison with the experimental data to study a spray/wall interaction phenomena. To begin with, the behavior of spray injected normal to the wall was analysed using three different impingement models ; Naber and Reitz model(NR model), Watkins and Wang model(WW model) and Park and Watkins model(PW model) in the present calculation. The results obtained from these models were compared with experimental data of Katsura et. al. The results indicated that PW model was in better agreement with experimental data than the NR and WW model. Also f3r spray injected at 30DEG , the result of three models were compared with experimental data of Fujimoto et. al. The results showed that m model overpredicted the penetration in the radial direction because this model was based on the inviscid jet analogy. WW model did not predicted the radius and height of the wall spray effectively. It might be thought that this discrepancy was due to the lack of consideration of spray film velocity occurred at impingement site. The result of PW model agrees with the experimental data as time goes on. In particular, a height of the spray droplets was predicted more closely to the experimental data than the other two models. The results of PW model in which the spray droplets were distributed densely around the edge of droplet distribution shaped in a circle had an agreement with the experimental data of Fujimoto et. al. Therefore, it was concluded that PW model performed better than M and WW model for prediction of spray behavior. The numerical calculation using PW model performed to the cylinder similar to the real shape of DI engine. The results showed that vortex strength near the wall in the cylinder was stronger than that in the case of flat plate. Contrary to the flat plat, an existence of the side wall in the cylinder caused the tangential velocity component to be reduced and the normal velocity component to be increased. The flow tends to rotate to the inside of cylinder going upward to the right side wall of cylinder gradually as time passes. Also, the results showed that as the spray angle increases, the gas velocity distribution and the tumble flow seemed to be formed widely.

Characterizing Par ticle Matter on the Main Section of the Seoul Subway Line-2 and Developing Fine Particle Pollution Map (서울시 지하철 2호선 본선구간의 입자상물질 농도 특성 및 미세분진의 오염지도 개발)

  • Lee, Eun-Sun;Park, Min-Bin;Lee, Tae-Jung;Kim, Shin-Do;Park, Duck-Shin;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.2
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    • pp.216-232
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    • 2016
  • In present, the Seoul City is undergoing traffic congestion problems caused by rapid urbanization and population growth. Thus the City government has reorganized the mass transportation system since 2004 and the subway has become a very important means for public transit. Since the subway system is typically a closed environment, the indoor air quality issues have often raised by the public. Especially since a huge amount of PM (particulate matter) is emitted from ground tunnels passing through the subway train, it is now necessary to assess the characteristics and behaviors of fine PM inside the tunnel. In this study, the concentration patterns of $PM_1$, $PM_{2.5}$, and $PM_{10}$ in the Seoul subway line-2 were analyzed by real-time measurement during winter (Jan 13, 2015) and summer (Aug 7, 2015). The line-2 consisting of 51 stations is the most busy circular line in Seoul having the railway of 60.2 km length. The the one-day average $PM_{10}$ concentrations were $148{\mu}g/m^3$ in winter and $66.3{\mu}g/m^3$ in summer and $PM_{2.5}$ concentrations were $118{\mu}g/m^3$ and $58.5{\mu}g/m^3$, respectively. The $PM_{2.5}/PM_{10}$ ratio in the underground tunnel was lower than the outdoor ratio and also the ratio in summer is higher than in winter. Further the study examined structural types of underground subsections to explain the patterns of elevated PM concentrations in the line-2. The subsections showing high PM concentration have longer track, shorter curvature radius, and farther from the outdoor stations. We also estimated the outdoor PM concentrations near each station by a spatial statistical analysis using the $PM_{10}$ data obtained from the 40 Seoul Monitoring Sites, and further we calculated $PM_{2.5}/PM_{10}$ and $PM_1/PM_{10}$ mass ratios near the outdoor subway stations by using our observed outdoor $PM_1$, $PM_{2.5}$, and $PM_{10}$ data. Finally, we could develop pollution maps for outdoor $PM_1$ and $PM_{2.5}$ near the line-2 by using the kriging method in spatial analysis. This methodology may help to utilize existing $PM_{10}$ database when managing and control fine particle problems in Korea.

Efficient Processing using Static Validity Circle for Continuous Skyline Queries (연속적인 스카이라인 질의의 정적 유효 영역을 이용한 효율적인 처리)

  • Li, Zhong-He;Park, Young-Bae
    • Journal of KIISE:Databases
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    • v.33 no.6
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    • pp.631-643
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    • 2006
  • Moving objects in a mobile environment to change their position based on the change of time require a query with their position as a basis. Efficient Regional Decision for Continuous Skyline Queries requires objectively pre-calculating the OSR(Optimal Skyline Region) regardless of the speed and direction of the moving objects. It proposes techniques to reduce the frequency of continuous queries by choosing a VCircle(Validity Circle) as safe location which has radius of the distance to the closest region with position on the moving object at center. But, a VCircle's area varies based on the Moving object's position from first marked time of continuous query. Therefore, the frequency of its continuous query is variable and also when the object moves inside of OSR, query can re-occur frequently In this paper, we suggest a technique of selecting an IVCircle(Interior Validity Circle) in a Skyline Region as the static Safe Region using the characteristics of the OSR. An Interior IVCircle can be calculated in advance when the OSR is decided. Our experiment shows that the frequency of using IVcircle as safe region reduced than that of using VCircle as safe region by 52.55%.

Influence of Temperature and Affinity of Disperse Dye on Dyeing of PET(Polyethylene Terephthalate) Microfiber (PET 초극세사 염색에서 분산염료의 친화력과 온도 의존성)

  • Lee, Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.9
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    • pp.532-540
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    • 2019
  • PET microfibers with various diameters (0.5, 0.2, 0.06, and 0.01 dpf) were dyed with a dispersed dye (C.I. Disperse Blue 56) at various temperatures. The dyeing process was conducted under infinite dyebath conditions at constant temperatures. The effects of the dyeing temperature and diameter on the partition coefficient, affinity, and diffusion coefficient of disperse dyes were studied. The curve of isotherms was fitted well to Nernst-type model in a large range of initial dye concentrations. At the same temperature, the partition coefficient and affinity decreased with increasing sample diameter due to the increase in surface area. At all deniers, the partition coefficient and affinity decreased with increasing temperature because the dyeing process is an exothermic reaction. In addition, the decrease in radius of the sample gives rise to a decrease in the heat of dyeing. The fine diameter of the sample resulted in an increased surface area but decreased space between the microfibers. Consequently, decreasing the diameter of the microfibers leads to a decrease in the diffusion coefficient. At the same diameter, the diffusion coefficient increased with increasing temperature because of rapid dye movement and the large free volume of the sample inside. In addition, thermal dependence of the diffusion coefficient increased when the diameter of the sample increased.

Study on Environmental Project Factors in Peripheral Spaces around Children's Parks within Low-rise Housing Areas by Using IPA Analysis - Focusing on user consciousness survey - (IPA분석을 이용한 저층주거지 내 어린이공원 주변공간의 환경계획요인에 관한 연구 - 이용자 의식조사를 중심으로 -)

  • Bae, Yeonhee;Byun, Gidong;Ha, Mikyoung
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.35 no.1
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    • pp.73-81
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    • 2019
  • The purpose of this study is to draw safe environmental project factors for enhancing the safety of children in peripheral space around children's park and suggest environmental project measures for peripheral spaces around children's parks, based on the survey of children's park users' consciousness on peripheral spaces. Physical space range for this study was limited to low-rise housing area wihtin the radius of 250m, as peripheral spaces around children's parks in which children's playgrounds were built. In addition, the target areas for examining users' consciousness on peripheral spaces around children's parks were selected according to following criteria. 1)areas with highter portion of children; 2) those with higher portion of single-family houses/multi-housing/tenement houses, which constitute low-rise housing areas; and 3) those with higher safety accident rate of children, which was measured based on criminal and traffic accidents. The finding are as follows: first, users' consciousness on safety accidents that are likely to occur in peripheral spaces around children's parks was examined to show that there is most prominent difference between satisfaction and necessity. This result suggests that users are clearly conscious of the necessity of environmental improvement rather than the satisfaction with the current peripheral environment around children's park.; second, for the difference between satisfaction with and necessity of environmental project factors for access/boundary spaces around children's pakrs, there is most significant difference between the satisfaction with and the necessity of establishment of facilities against illegal parking for clear visibility of community roads, for access spaces, and the separate establishment of bicycle racks around main entry into parks, for boundary spaces. Users' necessity of the establishment of them is judged to be derived from the fact that the safety of children and even adults is threatened, because bicycles invaded into the deep inside of children parks. This study analyzed a correlation between satisfaction and necessity through factor and IPA analysis, and should be initially considenred if the future environmental improvement project would be conducted to promote safe environment in peripheral spaces around children's parks in the future. It will be necessary to provide practical environmental project factors through a field investigation.

Design Optimization to achieve an enhanced flatness of a Lab-on-a-Disc for liquid biopsy (액체생검용 Lab-on-a-Disc의 평탄도 향상을 위한 최적화)

  • Seokkwan Hong;Jeong-Won Lee;Taek Yong Hwang;Sung-Hun Lee;Kyung-Tae Kim;Tae Gon Kang;Chul Jin Hwang
    • Design & Manufacturing
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    • v.17 no.1
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    • pp.20-26
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    • 2023
  • Lab-on-a-disc is a circular disc shape of cartridge that can be used for blood-based liquid biopsy to diagnose an early stage of cancer. Currently, liquid biopsies are regarded as a time-consuming process, and require sophisticated skills to precisely separate cell-free DNA (cfDNA) and circulating tumor cells (CTCs) floating in the bloodstream for accurate diagnosis. However, by applying the lab-on-a-disc to liquid biopsy, the entire process can be operated automatically. To do so, the lab-on-a-disc should be designed to prevent blood leakage during the centrifugation, transport, and dilution of blood inside the lab-on-a-disc in the process of liquid biopsy. In this study, the main components of lab-on-a-disc for liquid biopsy are fabricated by injection molding for mass production, and ultrasonic welding is employed to ensure the bonding strength between the components. To guarantee accurate ultrasonic welding, the flatness of the components is optimized numerically by using the response surface methodology with four main injection molding processing parameters, including the mold & resin temperatures, the injection speed, and the packing pressure. The 27 times finite element analyses using Moldflow® reveal that the injection time and the packing pressure are the critical factors affecting the flatness of the components with an optimal set of values for all four processing parameters. To further improve the flatness of the lab-on-a-disc components for stable mass production, a quarter-disc shape of lab-on-a-disc with a radius of 75 mm is used instead of a full circular shape of the disc, and this significantly decreases the standard deviation of flatness to 30% due to the reduced overall length of the injection molded components by one-half. Moreover, it is also beneficial to use a quarter disc shape to manage the deviation of flatness under 3 sigma limits.

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