• Title/Summary/Keyword: Input concentration

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Self-Modeling Curve Resolution Analysis of On-line Near Infrared Spectra Measured during the Melt-Extrusion Transesterification of Ethylene/Vinylacetate Copolymer

  • Sasic, Slobodan;Kita, Yasuo;Furukawa, Tsuyoshi;Watari, Masahiro;Siesler, Heinz W.;Ozaki, Yukihiro
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1284-1284
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    • 2001
  • The transesterification of molten ethylene/vinylacetate (EVA) copolymers by octanol as a reagent and sodium methoxide as a catalyst in an extruder has been monitored by on-line near infrared (NIR) spectroscopy. A total of 60 NIR spectra were acquired for 37 minutes with the last spectrum recorded 31 minutes after the addition of octanol and catalyst was stopped. The experimental spectra show strong baseline fluctuations which are corrected for by multiplicative scatter correction (MSC). The chemometric methods of orthogonal projection approach (OPA) and multivariate curve resolution (MCR) were used to resolve the spectra and to derive concentration profiles of the species. The detailed analysis reveals the absence of completely pure variables that leads to small errors in the calculation of pure spectra. The initial estimation of a concentration that is necessary as an input parameter for MCR also presents a non-trivial task. We obtained results that were not ideal but applicable for practical concentration control. They enable a fast monitoring of the process in real-time and resolve the spectra of the EVA copolymer and the ethylene/vinyl alcohol (EVAL) copolymer to be very close to the reference spectra. The chemometric methods used and the decomposed spectra are discussed in detail.

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A Study on the Optimal Use of Silent Discharge Type Ozonizer in Purification Plant (정수장의 무성방전형 오존발생기 최적활용방안에 관한 연구)

  • Shin, Hong-Sub;Park, Hyun-Mi;Kwon, Young-Hak;Song, Hyun-Gig;Park, Won-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.3
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    • pp.54-60
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    • 2015
  • There are 5 purification plants with the adopted advanced water purification treatment process in Korea. Annual operating costs were 8,990 million won including purchase cost of oxygen and power usage charges. We need research to optimize, in the future, when considering the direction of domestic water treatment continues to adopt advanced water treatment process. In this paper, calculate the optimal operating costs by injected the oxygen gas, used power cost. approximately 25% of the operating costs can be reduced when injected the ozone gas is 1.0ppm than 2.0ppm, the necessary amount of oxygen is increased then power is lower. so operating costs are decided according to oxygen costs. On the other hand, high ozone concentration 2.0ppm, the necessary power is increased then amount of oxygen is lower. Therefore, in the case of G purification plant, the controlling factor of the input ozone concentration 2ppm, PID control operation by setting the concentration of over 10Wt% is efficient. The installed capacity is the more little the more better when considering on Ozone injection rate in the process of water treatment.

A Study of Concentration Prediction of Automobile Air Pollutant Near the Highway (자동차 대기오염물질이 고속도로 인접지역에 미치는 농도 예측에 관한 연구)

  • Park, Seong-Gyu;Kim, Sin-Do;Kim, Jong-Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.6
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    • pp.607-620
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    • 1998
  • The influence of transportation on air quality has been elevating in urban area. Air pollutants from automobiles cause primary and secondary air pollution, and need to be tightly controlled. In this study, the effect of automobile air pollutants on highway vicinity area was evaluated by the comparison of field measurement. and target was for modeling using CALINE3, NO2 was the target for this work. It was found that the concentration predicted by CALINE3 is overestimated at low wind speed and input data of wind speed requires correction. Based on the measured data, the wind speed was modified by effective wind speed equation [Ue=U+0.24·EXP(-pxU)], and there after the accuracy of CALINE3 calculation was improved neighborhood area of highway. It was also observed that weather conditions and traffic volume affect the concentration of air pollution. Finally, the NO2 effect of automobile air pollutants on the vicinity area of highway proved to be up to 400∼600m from the highway.

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Current Wet Deposition of Pu Isotopes in the mid-Yellow Sea Coast of Korea (최근 한반도 중부 황해안의 Pu 핵종 습식 침착)

  • 이상한;정창수;김석현;이광우
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.2
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    • pp.79-87
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    • 1999
  • $^{239+240}Pu$ concentrations in precipitation were determined for the period of May 1994 to August 1996 in oder to describe current $^{239+240}Pu$ deposition at the mid-western coat of Korea (Ansan, 37$^{\circ}$17'N, $126^{\circ}$50'E). $^{239+240}Pu$ concentration in daily precipitation varied from 0.05 to 131$\mu$Bq $kg^{-1}$ with a geometric mean of $1.26\mu$Bq $kg^{-1}$. The concentration was high in the period of Yellow Sand Storm in spring and low in wet summer monsoon. The specific $^{239+240}Pu$ concentration in daily precipitation appears to be controlled by the $^{239+240}Pu$ input to the atmosphere in spring and washout effects by precipitation in the wet summer monsoon. Wet depositional flux of $^{239+240}Pu$ varied from 4 to 123$\mu$Bq $m^{-2}d^{-1}$ with a geometric mean of $33.8\mu$Bq $m^{-2}d^{-1}$ and with a maximum in the period of Yellow Sand Storm and a minimum in the period of wet summer monsoon. $^{238}Pu$/$^{239+240}Pu$ activity raios(0.04~0.31) in precipitation for March-June period suggested that one of the major sources of Pu isotopes falling in Ansan area is the arid region of the Chinese continent.

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Distribution of Polycyclic Aromatic Hydrocarbon at Kongsfjorden in Spitsbergen, Svalbard Islands (북극 스발바드 군도 스피츠베르겐섬 콩스피요르드에서의 다환 방향족 탄화수소화합물의 분포 특성)

  • Kim, Gi Beom;Ha, Seong Yong;An, In Yeong
    • Journal of Environmental Science International
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    • v.13 no.9
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    • pp.819-826
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    • 2004
  • In order to elucidate the polycyclic aromatic hydrocarbon concentration and its origin in arctic area, four arctic brown algae (Laminaria saccharina, L. digita, Alaria esculenta, Desmarestia aculeata), one marine invertebrate (Echinoidea) and sediments were collected from Kongsfjorden in Spitsbergen from the late July to early August, 2003. In case of macroalgae, the young blade part above growth point and the old stipes and blades beneath growth point were separated and analyzed for polycyclic aromatic hydrocarbons (PAHs) in an attempt to check the mechanism of uptake in macroalgae to accumulate PAH. There was no difference in PAH concentrations between sampling sites (Stations B and C), species, and blades beneath and above growth point. PAH concentrations in all samples collected in this study were relatively higher than those reported in other areas of arctic. Especially, station C, which is known as an unpolluted area, showed 10 times higher PAH concentration (8,765 ng/g) in sediment than station A (694 ng/g) around harbor. In addition high PAH concentration, station C had very higher proportion of methylated PAH to parent PAH in sediment than station A. Source analysis using PAH isomer pair ratios as indicators showed that Kongsfjorden area seemed to be relatively contaminated with PAH derived from direct petroleum input.

Noise Reduction Method for Particle Measurement System using Beta-ray Absorption Method (베타선 흡수법을 이용하는 미세먼지 측정시스템을 위한 잡음제거 방법)

  • Choi, Hun;Sohn, Sang-Wook;Bae, Hyeon-Deok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.11
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    • pp.1706-1712
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    • 2012
  • The Beta-ray absorption method (BAM) gives a good solution for measuring the mass concentration of atmospheric particles(PM10 and PM2.5). To determine particular matters (PM) concentration, a ratio of the number of detected beta-ray intensity passing through the clean filter and the dust-sampled filter is used. These intensity data measured in air pollution monitoring such as PM10 and PM2.5 usually contained the additive noise(thermal noise, power supply noise and etc.). Therefore, the estimation performance of mass concentration can be deteriorated by these noises. In this paper, we present a new noise reduction method that is essentially required to develope an automatic continuous PM monitoring system using beta-ray absorption method. By combining the block data averaging technique and curve fitting, in the proposed method, the additive noise can be reduced in the measured data. To evaluate the performance of the proposed method, computer simulations were performed with computer generated signals as the input.

지하수 조사에서 환경추적자로서의 $SF_6$의 적용

  • ;Niel Plummer;Eurybiades Busenberg
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.73-76
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    • 2003
  • SF$_{6}$ (Sulfur Hexafluoride) is a gaseous compound whose use is being greatly increased recently. The compound has a negligible background concentration from natural sources and is stable in most of groundwater environments. Therefore, SF$_{6}$ has potential for a dating tool for young groundwater. It has many advantages over chlorofluorocarbons (CFCs) for groundwater investigation that sampling procedure is much simpler than CFCs and its growth is continued up to at least near future in the atmosphere. However, solubility of SF$^{6}$ is so low that excess air causes large uncertainties in recharge date of groundwater. To compensate the limitation, $N_2$/Ar method can be employed to estimate excess air content. A groundwater study is currently carrying out in Jeju Island using SF$_{6}$ as an environmental tracer, Well waters and spring waters were sampled for SF$_{6}$ and $N_2$/Ar. To establish SF$_{6}$ input history in the study area, air sampling is being conducted in the area near the center of the island on a monthly and weekly basis. Based on the present data, the level of SF$_{6}$ concentration in the atmosphere of the Island is corresponding to the trend of the Northern Hemisphere.

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Preliminary assessment of derived concentration guideline level (DCGL) for a hypothetical contaminated site planned for Ninh Thuan 1 nuclear power plant project in Vietnam by using RESRAD-ONSITE code

  • Bui Thi Hoa;Yongheum Jo;Jun-Yeop Lee
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.2274-2281
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    • 2024
  • RESRAD-ONSITE v7.2 code is used to assess the radiation effects on a farmer resident located in a hypothetical contaminated site planned for the first nuclear power plant project in Vietnam, namely Ninh Thuan 1, after decommissioning. Derived concentration guideline levels are preliminarily calculated for 17 radionuclides that are assumed to remain on a contaminated surface soil with an initial concentration of 1 pCi/g in the protected area of NPP site. For a reliable estimation, the site-specific conditions regarding the geological, hydrological, climate, and occupancy data gathered from the Feasibility Study Report (FSR) and relevant literatures for the Ninh Thuan 1 NPP site is employed as input parameters. The calculation results indicate that the peak of total exposure dose is estimated to be ca. 0.191 mSv/yr at the time of decommissioning, and then decrease over time. Furthermore, the protected site is assessed to be released at ca. 6.71 years after decommissioning under the regulation on radiation protection in Vietnam. Through this study, a radiation exposure model for residents living near the Ninh Thuan 1 NPP is preliminarily established by using the RESRAD-ONSITE code, which are expected to be useful for future implementation of the Ninh Thuan 1 NPP project in Vietnam.

Analysis of regional inequality of social welfare facilities according to local welfare environment (지역복지환경에 따른 사회복지시설의 지역분포 불평등 분석)

  • Lee, Yong-Jae
    • Journal of Digital Convergence
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    • v.16 no.5
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    • pp.75-84
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    • 2018
  • The purpose of this study was to analyze the regional distribution of the number of social welfare facilities per 100,000 population by using the concentration index(CI) and to evaluate the relationship with the local welfare environment. The results of the analysis are as follows. First, the distribution of social welfare facilities between urban and rural area were distributed in rural areas. And concentration of rural area was gradually decreasing. Second, the concentration index of the social welfare institution was calculated as the negative index. Therefore, social welfare facilities are concentrated in rural areas. However, the absolute value of concentration index decreased. Finally, there are many social welfare facilities in areas with poor economic conditions, low incomes, low welfare budget input, and poor social demolition indicators. In the future, the relationship between inequality of regional distribution of welfare resources and the relationship between local welfare environment should be continuously monitored.

Biodegradation Kinetics of Diesel in a Wind-driven Bioventing System

  • Liu, Min-Hsin;Tsai, Cyuan-Fu;Chen, Bo-Yan
    • Journal of Soil and Groundwater Environment
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    • v.21 no.5
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    • pp.8-15
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    • 2016
  • Bioremediation, which uses microbes to degrade most organic pollutants in soil and groundwater, can be used in solving environmental issues in various polluted sites. In this research, a wind-driven bioventing system is built to degrade about 20,000 mg/kg of high concentration diesel pollutants in soil-pollution mode. The wind-driven bioventing test was proceeded by the bioaugmentation method, and the indigenous microbes used were Bacillus cereus, Achromobacter xylosoxidans, and Pseudomonas putida. The phenomenon of two-stage diesel degradation of different rates was noted in the test. In order to interpret the results of the mode test, three microbes were used to degrade diesel pollutants of same high concentration in separated aerated batch-mixing vessels. The data derived thereof was input into the Haldane equation and calculated by non-linear regression analysis and trial-and-error methods to establish the kinetic parameters of these three microbes in bioventing diesel degradation. The results show that in the derivation of μm (maximum specific growth rate) in biodegradation kinetics parameters, Ks (half-saturation constant) for diesel substance affinity, and Ki (inhibition coefficient) for the adaptability of high concentration diesel degradation. The Ks is the lowest in the trend of the first stage degradation of Bacillus cereus in a high diesel concentration, whereas Ki is the highest, denoting that Bacillus cereus has the best adaptability in a high diesel concentration and is the most efficient in diesel substance affinity. All three microbes have a degradation rate of over 50% with regards to Pristane and Phytane, which are branched alkanes and the most important biological markers.