• Title/Summary/Keyword: Inorganic injection

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Electrical Characteristics of Organic Light Emitting Diodes (OLED) using the Alkali Metal Complex as New Electron Injection Layers (알칼리 금속 전자 주입층을 사용한 유기 전기 발광 소자 (OLED)의 전기적 특성)

  • Lee, Hyun-Koo;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1015-1018
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    • 2004
  • We investigate the influence of the New Electron Injection Layers (EIL) on the performance of the Alkali Metal Complex vapor-deposited Organic Light Emitting Diodes(OLED). Two different Alkali Metal Complex were used; Lithium Quinolate (Liq), and Sodium Quinolate (Naq). In all cases, $Alq_3$ was the Electron Transporting Layer (ETL). We measure and compare the current density-voltage (J-V) and luminance-voltage (L-V) characteristics. We concluded that the turn-on voltage, and luminance efficiency are controlled by the type of EIL material used. We show the longer life-time OLED with Alkali Metal Complex EIL than OLED with LiF EIL. And we show the Optimized Alkali Metal Complex thickness is 3nm. Existent LiF to because is inorganic material, there is trouble to do epitaxy into thin layers but regulates the thickness in case of Alkali Metal Complex matter characteristic that is easy be. Alkali Metal Complex also appeared by sensitive thing in thickness than LiF If utilize this material, It is thought much advantages may be at common use of OLED.

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A Comparison Study on Various Quantum Dots Light Emitting Diodes Using TiO2 Nanoparticles as Inorganic Electron Transport Layer (무기 전자 수송층으로 TiO2 나노입자를 사용한 다양한 양자점 전계발광 소자의 특성 비교 연구)

  • Kim, Moonbon;Yoon, Changgi;Kim, Jiwan
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.3
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    • pp.71-74
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    • 2019
  • In this study, we fabricated two standard and inverted quantum dot light emitting diodes (QLEDs) using $TiO_2$ nanoparticles (NPs) with lower electron mobility than ZnO NPs as inorganic electron transport layer to suppress electron injection into the emitting layer. Current density was much higher for the inverted QLEDs than the standard ones. The inverted QLEDs were brighter, but showed low current efficiency due to the high current density. In addition, as the current density was higher, the driving voltage was higher, and the red shift was confirmed in the emission wavelength spectrum. The low current density in the standard structured devices showed that the possibility that $TiO_2$ NPs could suppress the electron injection in the QLEDs.

Improvement of Sewage Sludge Dewaterability using BIO-CLOD (BIO-CLOD를 이용한 하수 슬러지 탈수성 개선 효과분석)

  • Sung, Il-Wha
    • Journal of Environmental Health Sciences
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    • v.41 no.5
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    • pp.327-334
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    • 2015
  • Objectives: In order to review both the effects of sewage sludge dewaterability and deodorizing ability in the existing advanced sewage treatment process, BIO-CLOD (a solidified mixture of 10% Bacillus concentrate and inorganics) was used as an inorganic conditioner effective for deodorization treatment in addition to the removal of organic matter and nutritive salts. Methods: Sludge dewaterability was evaluated using specific resistance to filtration (SRF) experiments with six agitators and two types of commercially available BIO-CLOD; one that is made by grinding solid matter (powdered BIO-CLOD) and one that has been obtained by sieving a separation with a particle diameter of 100 mesh (100 mesh BIO-CLOD). For deodorization odor treatment experiments, 20 g of commercially available solid BIO-CLOD was submerged in four liters of sewage sludge and mixed and agitated for 45 days. Results: When BIO-CLOD was injected into sewage sludge to experimentally compare specific resistance to filtration (SRF), the optimum amount of BIO-CLOD to be injected was shown to be 2% w/v and the SRF value in this case was $1.35{\times}10^{12}m/kg$. pH changes following BIO-CLOD injection were within 6.5-7.0. By 14 days after submerging BIO-CLOD into the sewage sludge to evaluate its deodorizing ability, $H_2S$ decreased by 68% and methyl mercaptan decreased by 74%. By 45 days after the submergal, both items decreased by 100%, indicating deodorizing ability. Conclusion: To compare the levels of dewaterablity of sewage sludge at different particle sizes of inorganic conditioner, powdered BIO-CLOD, particle size 100 mesh BIO-CLOD, and bentonite were tested. It could be seen that as the powdered BIO-CLOD increased, the precipitability increased up to 62% in 30 minutes. As an inorganic conditioner, BIO-CLOD was identified as a stable sludge conditioner that does not affect pH.

Indirect Determination of Nitrite by Flame Atomic Absorption Spectrometry Using a Lead(IV) Dioxide Oxidant Microcolumn

  • Noroozifar, Meissam;Khorasani Motlagh, Mozhgan;Taheri, Aboozar;Homayoonfard, Marjan
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.875-880
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    • 2006
  • A new, simple and fast flow injection analysis (FIA) method has been developed for the indirect determination of nitrite. The proposed indirect automatic method is based on the oxidation of nitrite to nitrate using a lead(IV) dioxide oxidant microcolumn where the flow of the sample through the microcolumn reduces the $PbO_2$ solid phase reagent to Pb(II), which is measured by flame atomic absorption spectrometry. The absorbance of Pb(II) are proportional to the concentration of nitrite in the samples. The calibration curve was linear up to 30 mg $L ^{-1}$, with a detection limit of 0.11 mg $L ^{-1}$ for a 400 mL injected sample volume and a sampling rate of about 80 $h ^{-1}$. The results exhibit no interference from the presence of large amounts of ions. The developed procedure was found to be suitable for the determination of nitrite in foodstuffs and wastewaters. A relative standard deviation better than 0.9% was obtained in a repeatability study. The reliability of the method was established by parallel determination against the standard method.

Equilibria and Kinetics of Cr(VI) Reduction (심층 지하에서의 육가 크롬 환원)

  • 현재혁
    • The Journal of Engineering Geology
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    • v.3 no.2
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    • pp.191-201
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    • 1993
  • Reduction is one of the important mechanisrns in decreasing the amount of Cr(VI) in wastewater and this reaction is quite dependent on pH and temperature. Either soil organic materials, or a high inorganic salt concentration with elevated temperature and low pH will provide a good condition for the reduction of Cr(VI) to Cr(III) in deep well injection zones. Chromate reduction by soil organic materials and chloride ion in various environment conditions is investigated. Aquifer and aquitard formation samples have been obtained from a deep well in St. Bernard Parish, and St. Charles Parish, LA, U.S.A., respectively. For this study, pH ranging from -0.81 to 2.0, temperature $50^{\circ}C{\;}and{\;}70^{\circ}C$, and cliloride concentration 0 M, 0.26 M and 0.52 M are used to represent the actual conditions in deep well injection zones.

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Study on the Atomic Layer Deposition System and Process of the MgO Thin Layer for the Thin Film Encapsulation of OLED (OLED의 Thin Film Encapsulation을 위한 MgO 박막의 원자층 증착 장치 및 공정에 관한 연구)

  • Cho, Eou Sik;Kwon, Sang Jik
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.22-26
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    • 2021
  • Thin-film encapsulation (TFE) technology is most effective in preventing water vapor and oxygen permeation in the organic light emitting diodes (OLED). Of those, a laminated structure of Al2O3 and MgO were applied to provide efficient barrier performance for increasing the stability of devices in air. Atomic layer deposition (ALD) method is known as the most promising technology for making the laminated Al2O3/MgO and is used to realize a thin film encapsulation technology in organic light-emitting diodes. Atomic layer deposited inorganic films have superior barrier performance and have advantages of excellent uniformity over large scales at relatively low deposition temperatures. In this study, the control system of the MgCP2 precursor for the atomic layer deposition of MgO was established in order to deposit the MgO layer stably by the injection time of second level and the stable heating temperature. The deposition rate was obtained stably to be from 4 to 10 Å/cycle using the injection pulse times ranging from 3 to 12 sec and a substrate temperature ranging from 80 to 150 ℃.

An Efficiency Improvement of the OLEDs due to the Thickness Variation on Hole-Injection Materials (정공주입물질 두께 변화에 따른 유기발광다이오드의 효율 개선)

  • Shin, Jong-Yeol;Guo, Yi-Wei;Kim, Tae-Wan;Hong, Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.5
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    • pp.344-349
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    • 2015
  • A new information society of late has arrived by the rapid development of various information & communications technologies. Accordingly, mobile devices which are light and thin, easy and convenient to carry on the market. Also, the requirements for the larger television sets such as fast response speed, low-cost electric power, wider visual angle display are sufficiently satisfied. The currently most widely studied display material, the Organic Light-emitting Diodes(OLEDs) overwhelms the Liquid Crystal Display(LCD), the main occupier of the market. This new material features a response speed of more than a thousand times faster, no need of backlight, a low driving voltage, and no limit of view angle. And the OLEDs has high luminance efficiency and excellent durability and environment resistance, quite different from the inorganic LED light source. The OLEDs with simple device structure and easy produce can be manufactured in various shapes such as a point light source, a linear light source, a surface light source. This will surely dominate the market for the next generation lighting and display device. The new display utilizes not the glass substrate but the plastic one, resulting in the thin and flexible substrate that can be curved and flattened out as needed. In this paper, OLEDs device was produced by changing thickness of Teflon-AF of hole injection material layer. And as for the electrical properties, the four layer device of ITO/TPD/$Alq_3$/BCP/LiF/Al and the five layer device of ITO/Teflon AF/TPD/$Alq_3$/BCP/Lif/Al were studied experimentally.

Photometric Determination of Chlorite ion by Flow Injection Analysis (흐름주입 분석에 의한 아염소산 이온의 분광광도법 정량)

  • Choi, Yong Wook;Lee, Su Young;Kim, Mi Kyung;Park, Sung Ho
    • Journal of the Korean Chemical Society
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    • v.44 no.6
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    • pp.556-562
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    • 2000
  • The determination of chlorite ion by flow injection analysis(FIA) with iodometric UV detection were investigated. Under rather acidic condition, chlorite ion react with iodide ion to form iodine and itself is reduced to chloride ion. The chlorite ion was determined indirectly by measuring absorbance of yellow colored iodine at 370 nm. The lengths of the mixing coil and the reaction coil, the pH of the acid stream, the concentration of the iodide ion, the injection loop volume, temperature, and flowrate were optimized as parameters for selectively determining a sort of inorganic disinfection by-product, chlorite ion by using FIA-UV detection setup. Masking agents for removing oxidants or interferences from the prepared water were tested. Independent calibration curve presented linear range of 0.002-0.2 mg/L for chlorite ion with a correlation coefficient of 0.999 or better. The limit of detection(LOD) was 0.18 ${\mu}g/L$ for chlorite ion.

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Evaluation of Field Application for the mix properties of the thixotropic grout (가소성그라우트의 배합특성 및 현장 적용성 평가)

  • Kim, Hak-Moon;Jang, Kyung-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.9
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    • pp.4223-4238
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    • 2011
  • The advantages of grouting are the simple instrument, the simple procedure of practice and the simple verification of grouting result. but the more grouting practice there is, the more damages of environment from grouting practice and grouting materials there are. so, the grouting materials and methods with the character of environment friendly are introduced in construction field, recently. This paper is to study of the physical characteristics that has thixotropic character and that consists of inorganic and polycarboxylate co-polymer. In study, various testing methods are performed such as a viscosity, a thixotropy, a compressive strength, a heavy metal detection and pH measurement in lab test and a low pressure injection test and a high pressure injection test in field with different soil type. As a result, a optimum mix ratio is proposed by analyzing the result of lab test. the field applicability is verified by checking a injection pressure, a grout volume and a hardened body of grout by excavating the practice site.

Influence of sodium selenite on oxygen free radical in mercuric chloride induced renal failure (Mercuric chloride 유발 신부전에서 산소유리기에 미치는 Sodium selenite의 영향)

  • Kim, Hyoung-Chun;Jhoo, Wang-Kee;Huh, In-Hoi
    • YAKHAK HOEJI
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    • v.32 no.4
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    • pp.287-293
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    • 1988
  • Oxygen free radical have recently been found to mediate cell injury after ischemia in the kidney. The purpose of our study was to determine whether selenium had an effect on damge mediated by oxygen free radical in inorganic mercury induced renal failure, toxic model of renal failure. Toxic renal failure model was produced by subcutaneous injection of mercuric chloride (4mg/kg) once a day for 7 consecutive days. In additionally, coadministration of sodium selenite (1mg/kg) was performed by the same condition. As a consequence of this study, we were able to detect partially unequivocal role of selenium as below dipicted. The combination of sodium selenite showed that markedly inhibited production of superoxide radical in mercuric chloride alone. On the other hand, combined sodium selenite was unable to enhance against significantly lowered superoxide dismutase activity after mercuric chloride insult. However, simultaneous administration of sodium selenite was inclined to induce mitochondrial superoxide dismutase and catalase.

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