• Title/Summary/Keyword: Inorganic Additives

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Study on scheme for screening, quantification and interpretation of trace amounts of hazardous inorganic substances influencing hazard classification of a substance in REACH registration (REACH 물질 등록 시 분류에 영향을 주는 미량 유해 무기물질의 스크리닝·정량·해석을 위한 체계도 연구)

  • Kwon, Hyun-ah;Park, Kwang Seo;Son, Seung Hwan;Choe, Eun Kyung;Kim, Sanghun
    • Analytical Science and Technology
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    • v.32 no.6
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    • pp.233-242
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    • 2019
  • Substance identification is the first step of the REACH registration. It is essential in terms of Classification, Labelling and Packaging (CLP) regulation and because even trace amounts of impurities or additives can affect the classification. In this study, a scheme for the screening, quantification, and interpretation of trace amounts of hazardous inorganic substances is proposed to detect the presence of more than 0.1% hazardous inorganic substances that have been affecting the hazard classification. An exemplary list of hazardous inorganic substances was created from the substances of very high concern (SVHCs) in REACH. Among 201 SVHCs, there were 67 inorganic SVHCs containing at least one or ~2-3 heavy metals, such as As, Cd, Co, Cr, Pb, Sb, and Sn, in their molecular formula. The inorganic SVHCs are listed in excel format with a search function for these heavy metals so that the hazardous inorganic substances, including each heavy metal and the calculated ratio of its atomic weight to molecular weight of the hazardous inorganic substance containing it, can be searched. The case study was conducted to confirm the validity of the established scheme with zinc oxide (ZnO). In a substance that is made of ZnO, Pb was screened by XRF analysis and measured to be 0.04% (w/w) by ICP-OES analysis. After referring to the list, the presence of Pb was interpreted just as an impurity, but not as an impurity relevant for the classification. Future studies are needed to expand on this exemplary list of hazardous inorganic substances using proper regulatory data sources.

A Study on Sintering and mechanical Properties of Sinter/HIPed SiC Whisker/$Al_2O_3$ Composite (Sinter/HIP 공정으로 제조한 SiC whisker/$Al_2O_3$ 복합재료의 소결 및 기계적 물성에 관한 연구)

  • Lee, Chae-Hyun;Kim, Jong-Ock;Kim, Chong-Hee
    • The Journal of Natural Sciences
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    • v.8 no.1
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    • pp.53-59
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    • 1995
  • Effects of sintering additives and sintering temperatures on the sintering behavior and mechanical properties of SiC whisker reinforced alumina composites have been investigated in this study. Dense (>95% TD) composites were obtained by using 2 wt% $Y_2O_3$ as liquid phase sintering additive. But only porous composite could be obtained when the sintering additives were MgO and $TiO_2$, which were known as the sintering additives for solid state sintering of alumina. Bending strength and fracture toughness were enhanced by reinforcement of SiC whisker. It is belived from the microstructure investigation that the enhanced by strength and toughness could be attribute to the reinforcing and grain growth inhibition effects of SiC whisker. After HIP treatment, fully dense composites were obtained and further enhanced mechanical properties achieved.

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Shrinkage of Injection Molded Part for Inorganic Additive Compositions (무기 첨가물 함량에 따른 사출성형품의 성형 수축)

  • Kim B.D.;Yoo Y.H.;Hwang B.H.;Lyu M.Y.;Kim A.S.;Park S.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.58-64
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    • 2004
  • The shrinkages of injection molded parts are different in molding operational conditions, resins and additives. The shrinkage of injection molded part for crystalline polymer, PBT (polybutylene terephthalate) has been studied for various operational conditions of injection molding and content of additives. Mica was used as a additive to PBT to examine the part shrinkage according to the mica content. The part shrinkages of mica contained PBT decreased as mica content increases. Higher injection temperature and injection pressure resulted in a lower shrinkage. As mold temperature increases the part shrinkage decreased. The part shrinkage of flow direction was less than that of the perpendicular direction to the flow for both pure and mica contained PBT. However the shrinkage difference between flow and perpendicular to flow directions decreased as mica content increased.

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An Experimental Study on the Anti-corrosion and Anti-wear Characteristics of MoS$_2$ Bonded Films for Automotive Wheel Joints (방청 및 내마모 특성이 향상된 자동차 휠 조인트용 $MoS_2$계 고체 피막 윤활제)

  • 한흥구;공호성;윤의성;권오관
    • Tribology and Lubricants
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    • v.16 no.3
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    • pp.173-181
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    • 2000
  • Friction, wear and corrosion characteristics of various MoS$_2$ bonded film lubricants were investigated to apply them to automotive wheel joints. MoS$_2$ bonded film lubricants were formulated by combinations of several additives and binders, and they were coated onto the pre-treated surfaces of specimens. Friction and wear characteristics were evaluated with Falex pin & vee-block test and LFW-1 block-on-ring test. For the corrosion resistant characteristics of the films, salt solution spray corrosion tests were performed. Results showed that MoS$_2$ bonded films containing both inorganic and organic corrosion-resistant additives yielded a synergy effect on anti-corrosion resistance. Also, binders having the better water-proof and thermal stability showed the lower friction and higher corrosion resistance.

Self-healing Performance Evaluation of Cement Mortar with Inorganic Additives Based on Clinker Binder (클링커 바인더 기반 무기계 혼합재를 활용한 시멘트 모르타르의 치유성능 평가)

  • Jung-Il, Suh;Yoon-Suk, Choi;Byung-Sun, Park;Kwang-Myong, Lee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.561-568
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    • 2022
  • In this study, the mechanical properties and self-healing performance of cement mortar containing clinker binder, calcium sulfoaluminate(CSA), and sodium sulfate(Na2SO4) were evaluated. The mechanical properties of cement mortar were investigated by measuring compressive strength and flexural strength, and the healing performance was evaluated through hydrostatic water permeability test and gas diffusion test. In addition, the healing products precipitated in the cracks were visually observed through an optical microscope and a scanning electron microscope(SEM). As a result, the incorporation of the clinker binder-based inorganic additives improved the initial and 28-day strength by about 20 %. Depending on the healing performance evaluation method, there was a difference in the healing rate, and the healing rate showed a tendency to be underestimated. Nevertheless, CaCO3 was precipitated as the main healing product inside the 0.3 mm crack when the inorganic additives were mixed with cement mortar, improving the self-healing performance.

Effects of Chemical Additives on Nitrogen Contents in Dairy Slurry (젖소 액상분뇨에 화학제재를 첨가 시 질소 함량에 미치는 영향)

  • Choi, In-Hak;Kim, Chang-Mann
    • Journal of Environmental Science International
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    • v.18 no.7
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    • pp.811-817
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    • 2009
  • To determine changes in nitrogen contents and optimal rates as N fertilizer, we investigated nitrogen characteristics in the slurry in the respond to the application of 0, 0.5, and 1 g of ferrous sulfate or alum /25g of dairy slurry. Additions of ferrous sulfate or alum increase total nitrogen, inorganic nitrogen, available nitrogen, and predicted available nitrogen contents in dairy slurry, resulting in reduction in pH. The best results were found in the treatment with 0.5 g of ferrous sulfate or alum /25 g of dairy slurry. In conclusion, the use of ferrous sulfate or alum as on-farm amendment to dairy slurry should be represented an alternative to improve N in dairy slurry.

Development of Thixotropic Inorganic-Type Grout and Its Engineering Characteristics (무기계 가소성 그라우트의 개발 및 공학적 특성)

  • Jeong, Gyeong-Hwan;Shin, Min-Sik;Kim, Dong-Hae;Noh, Jin-Teck;Jung, Duh-Woe
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.725-733
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    • 2008
  • A thixotropic grout has been developed for the use of filling a tail void in the shield TBM and as well as various ground voids. The grout developed in this study is a mixture of inorganic substance, cement and some functional additives. Its engineering characteristics was investigated by measuring a viscosity and unconfined compressive strengths. The optimum mix proportion for an effective thixotropic grout was proposed through several repeated laboratory tests. The various physical properties such as thixotropy, unconfined compressive strengths, and durability of the thixotropic grout and the gels produced from the grout were compared with those of the well-known waterglass-type grout such as L.W.. The thixotropic grout developed in the study exhibited an excellent performance for back-filling of tail voids in the shield TBM based on experimental results compared to the existing waterglass grout.

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Modification of Hydroxyapatite-gelatin Nanocomposite using Side Group Reaction of Ca2+-RCOO-

  • Chang, Myung-Chul;Yang, Hae-Kwon
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.72-77
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    • 2012
  • In the preparation of a hydroxyapatite [HAp]/gelatin [GEL] nanocomposite, the GEL matrix in aqueous solution of $H_3PO_4$ was modified by the introduction of aspartic acid [Asp], asparagine [Asn], and glycine [Gly]. The addition of Asp, Asn and Gly greatly affected the slurry formation of HAp/GEL nanocomposite and the resulting dry body showed variations in toughness with the addition of the different amino acids. The introduction of Asn into HAp/GEL nanocomposite was effective for producing the organic-inorganic interaction between HAp and GEL, and caused the increase of toughness. The formation reaction of the modified HAP/GEL nanocomposites was investigated by using XRD and FT-IR. The organic-organic interaction between the GEL matrix and the additives of Asp, Asn and Gly was confirmed from FT-IR analysis, and the organic-inorganic interaction between HAp nanocrystallites and the modified GEL matrix was also discussed, using FT-IR spectra patterns. Nanocrystallites of HAp were covalently bound with the GEL macromolecules and differently influenced by the modification species of Asp, Asn, and Gly.

Instrumental Characterization of Dyes and their Inorganic Additives (기기분석에 의한 염료 구조 및 무기배합제 조성에 대한 접근)

  • 최은경;이은경;조영달
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.139-142
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    • 2002
  • Color Index의 염료 분류 방법은 chemical type에 따라 25개 구조 분류(예로, 아조, 안트라퀴논, tryarylmethane 등) 그리고, 염료의 응용 범위에 따라 19개 속명(Acid, Direct, Disperse, Reactive 등)을 사용한다. 상품화되어 있는 수많은 염료는 현재 생산 회사의 상품명과 Color Index generic name을 보편적으로 사용하고 있으나, 체계적인 화학명은 복잡할 뿐 만 아니라, 상업적 이유로 많은 경우 밝히지 않고 있다. (중략)

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