• Title/Summary/Keyword: Initial spray

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Synthesis and Optical Property of (GaN)1-x(ZnO)x Nanoparticles Using an Ultrasonic Spray Pyrolysis Process and Subsequent Chemical Transformation (초음파 분무 열분해와 화학적 변환 공정을 이용한 (GaN)1-x(ZnO)x 나노입자의 합성과 광학적 성질)

  • Kim, Jeong Hyun;Ryu, Cheol-Hui;Ji, Myungjun;Choi, Yomin;Lee, Young-In
    • Journal of Powder Materials
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    • v.28 no.2
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    • pp.143-149
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    • 2021
  • In this study, (GaN)1-x(ZnO)x solid solution nanoparticles with a high zinc content are prepared by ultrasonic spray pyrolysis and subsequent nitridation. The structure and morphology of the samples are investigated by X-ray diffraction (XRD), field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The characterization results show a phase transition from the Zn and Ga-based oxides (ZnO or ZnGa2O4) to a (GaN)1-x(ZnO)x solid solution under an NH3 atmosphere. The effect of the precursor solution concentration and nitridation temperature on the final products are systematically investigated to obtain (GaN)1-x(ZnO)x nanoparticles with a high Zn concentration. It is confirmed that the powder synthesized from the solution in which the ratio of Zn and Ga was set to 0.8:0.2, as the initial precursor composition was composed of about 0.8-mole fraction of Zn, similar to the initially set one, through nitriding treatment at 700℃. Besides, the synthesized nanoparticles exhibited the typical XRD pattern of (GaN)1-x(ZnO)x, and a strong absorption of visible light with a bandgap energy of approximately 2.78 eV, confirming their potential use as a hydrogen production photocatalyst.

Interfacial bonding Energy between Laser Surface Treated HA layer and Ti alloy (레이저 표면처리에 의한 수산화아파타이트 코팅된 타이타니움합금 경계면의 결합에너지)

  • Moon, D.S.;Kim, Y.K.;Nam, S.Y.;Cho, H.S.;Huh, E.J.;Kim, S.Y.;Lee, J.H.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.05
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    • pp.35-38
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    • 1997
  • The interfacial bonding energy between laser surface treated HA layer and Ti alloy substrate was investigated using a mechanical push-out tester. The initial slope of shear-stress and reduced displacement curves, maximum interfacial bond strength and bonding energy were calculated from results of the push-out test. The calculated initial slpoes are 38 MPa for the Ti alloy(A), 65 MPa for the sandblast finished specimen(B), 95 MPa for the HA plasma spray coated specimen and 49 MPa for the laser surface treated specimen(D). The maximum interfacial bonding strength are 3 MPa for the A, 19 MPa for the B, 20 MPa for the C, 10 MPa for the D. The interfacial bonding energies are $3.3\times10^{-9}J/mm^2$ for the A, $15.5\times10^{-9}J/mm^2$ for the B, $15.6\times10^{-9}J/mm^2$ for the C and $18.3\times10^{-9}J/mm^2$ for the D. Microscopic observation shows that the breaking of the laser treated specimen had been occured through the boundary between HA layer and polymer resin, but the untreated specimen had been occured through the inside of HA coating layer.

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Determination of Economic Threshold Level of Whitefly, Dialeuropora decempuncta (Quaintance and Baker) in Mulberry, Morus alba L.

  • Bandyopadhyay, U.K.;Santhakumar, M.V.;Saratchandra, B.;Das, K.K.
    • International Journal of Industrial Entomology and Biomaterials
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    • v.4 no.2
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    • pp.133-136
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    • 2002
  • Whitefly, Dialeuropora decempuncta (Quaintance rind Baker) (Homoptera: Aleyrodidae) has attained the major pest status in mulberry, causing 24% crop loss by sucking the leaf juice and manifesting leaf curl, chlorosis and sooty mould desease during monsoon season in West Bengal, India. The assessment of economic threshold revel is an essential component for formulating the management practices. Experiments were carried out by inoculating five different densities of whitefly viz.,10, 20, 30, 40 and 50 adults on covered mulberry plants in glass houses. From the findings, it was observed that irrespective of released density, no crop loss was observed in the initial period. But with the passing of days, the percent crop loss was increased rapidly. The linear relationship between percent crop loss and number of adults released was established to highlight the significance of economic threshold. The statistical analysis in the linear form of equation showed that initial population of 10, 20, 30, 40 and 50 whiteflies/plant causes 3%, 12%, 21%, 30% and 40% crop loss in a period of 28 days which is equivalent to 57 kg, 247 kg, 437 kg, 626 kg and 816 kg leaf/acre. Execution of management practices (spray of 0.01% monocrotophos) are economical to the farmer whenever the loss is above 247 kg/acre, but below which application of control measures is not economical. From this study, it can be inferred that the economic threshold level far whitefly is 20 individuals/plant beyond which a farmer has to take appropriate control measures.

Estimation of FDS Prediction Performance on the Operation of Water-Mist (미세물분무 작동에 대한 FDS 예측 성능 평가)

  • Ko, Gwon Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.8
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    • pp.4809-4814
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    • 2014
  • The aim of the present study was to estimate the prediction performance of a FDS (Fire Dynamic Simulator) to simulate the fire behaviors and suppression characteristics by operating a water-mist. Rosin-Rammler/log-normal distribution function was used to determine the initial droplet distribution of water-mist and the effects of its model constant were considered. In addition, the simulation models were validated by a comparison of the predicted fire suppression characteristics with water-mist injection pressures to the previous experiments, and the thermal flow behaviors and gaseous concentration variations were analyzed. The results showed that water-mists with the same mean diameter were affected by the characteristics of the droplet size distribution, which have different size and velocity distributions at the downstream location. The fire simulations conducted in this study determine the initial droplet size distribution tuned to the base of the spray characteristics measured by previous experiments. The simulation results showed good agreement with the previous measurements for temperature variations and fire suppression characteristics. In addition, it was confirmed that the FDS simulation with a water-mist operation supplies useful details on estimations of the thermal flow fields and gaseous concentration under water mist operation conditions.

Seasonal Weight in Seeding Mixture for the Restoration and Revegetation of the Disturbed Slopes (훼손 비탈면의 생태복원녹화를 위한 종자배합량의 계절별 가중치에 관한 연구)

  • Hur, Young-Jin;Ahn, Tae-Young
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.9 no.1
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    • pp.41-54
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    • 2006
  • In case of leaving artificial slopes resulting from large-scale constructions, there may be secondary damage caused by soil loss due to erosion and collapse. Furthermore, slope-restoring constructions have a few problems such as monotonous landscape and difficult succession of secondary vegetation due to reckless use of exotic grass, despite attaining the initial purpose of revegetation. To settle this problem, selected plants deemed to be proper for revegetation were used on one of thin vegetation base methods, CODRA SYSTEM, and made seeding mixture experimental plots considering germination rates differing in each season. Native herbs, native shrubs and exotic herbs contents were increased by 30% and 50% respectively, centered on seeding quantity(30g/$m^2$) used as design standard in the seed spray method, in order to figure out proper quantity for revegetation in each season.

In-Cylinder Fuel Distribution Measurements in a Lean Burn Engine (희박연소 엔진의 연소실내 연료분포 특성 연구)

  • Kim, K.S.;Lee, K.Y.
    • Journal of ILASS-Korea
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    • v.4 no.2
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    • pp.19-32
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    • 1999
  • The present study investigated the forms and behaviors of fuel during intake and compression process, and the initial flame stability in a lean burn engine modified as a single cylinder engine equipped with quartz windows for visualization. PLIF(Planar Laser Induced Fluorescence) method with KrF Excimer laser was used for measuring the fuel distributions. The principal design concept of the lean burn nin in this study is the axial stratification in the fuel distribution via fuel injection during intake process and different shapes of intake ports; helical and straight. The experiments showed that fuel flowed in as a vapor state in the early part of intake process and lots of this mixture mated down along the intake valve side cylinder wall, but in the latter part, a lot of fuel flowed in as a liquid state and this fuel stayed in the upper part of cylinder, after that the dense fuel cloud moved upward in the early of part compression process. It became clear that the fuel flowed in via straight port had a important role in the axial fuel stratification.

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A Study on the Improvement of Lubrication Characteristics for Fuel Pump in LPG Engine (자동차용 LPG 연료펌프의 윤활성 개선에 관한 연구)

  • Kim, Chang-Up;Choi, Kyo-Nam;Kang, Kern-Yong;Park, Cheol-Woong
    • Journal of ILASS-Korea
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    • v.16 no.1
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    • pp.1-6
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    • 2011
  • In recent years, the need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as LPG (Liquefied Petroleum Gas) which is able to meet the limits of better emission levels without many modifications to current engine design. LPG has a high vapor pressure and lower viscosity and surface tension than diesel and gasoline fuels. These different fuel characteristics make it difficult to directly apply the conventional gasoline or diesel fuel pump. Self acting lubricated groove design or coating can be used in high-speed and high precision spindle system like a roller-vane type fuel pump, because of its advantages such as low frictional loss, low heat generation, averaging effect leading better running accuracy and simplicity in manufacturing. Those design method can also affect the atomization of fuel from the injector and the formation of fuel film on the intake manifold. In this study, experiments are carried out to get performance characteristics of initial and steady state operation, The characteristics of vane type fuel pump were investigated to access the applicability on LPLi engine.

Group Ignition of Liquid Fuel Droplets Cloud (액체연료 액적군의 집단 점화)

  • 박용열;김호영
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.12
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    • pp.2376-2384
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    • 1992
  • A theoretical analysis is carried out to predict the characteristics of transient ignition phenomena for the spherical fuel droplets cloud with non-uniform droplet size and number density distribution. Numerical calculations are performed for various cases depending on the combinations of the major parameters such as ambient temperature and initial distributions of droplet size and number density. The results of present study show that the ignition delay decreases for higher ambient temperature and smaller droplet size. Droplets cloud of hollow type with outer concentrated distribution ignites most rapidly.

An Experimental Study on the Reduction of Exhaust Emissions by using Glow Plug during Cold-start and Warm-up in Gasoline Engine (가솔린기관의 냉시동시 Glow Plug를 이용한 배기가스저감에 관한 실험적 연구)

  • 문영호;김종호;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.4
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    • pp.7-14
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    • 2002
  • In order to reduce exhaust omissions of spark ignition engine, it is important not only to improve catalyst conversion efficiency but also to directly reduce engine out exhaust emissions, during cold starting and warm up process. Therefore many researchers have been attracted to develop an early fuel evaporator(EFE) by Introducing a ceramic heater fur a solution of engine out exhaust emissions in SI engine. But, the performance of the EFE in MPI engine to reduce the exhaust emissions and to improve the cold startability has not been clarified yet. The purpose of this study is to evaluate the feasibility of a glow plug far EFE. Impinging spray using heated and unheated glow plug helps the vaporization of the fuel and heat up the three way catalyst sufficiently. The amount of CO, and UHC is reduced overall. The amount of NOx is higher at the initial stage, but become lower as time goes on than without glow plug.

Unstructured Finite-Volume Analysis of Vaporization Characteristics of Fuel Droplets in Laminar Flow Field (비정렬 유한체적법을 이용한 유동장 내의 연료액적 증발 특성 해석)

  • Kim, T.J.;Kim, Y.M.;Sohn, J.L.
    • Journal of ILASS-Korea
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    • v.5 no.1
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    • pp.13-22
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    • 2000
  • The present study has numerically analyzed the vaporization characteristics of fuel droplets in the high temperature convective flow field. The axisymmetric governing equations for mass, momentum, energy, and species are solved by an iterative and implicite unstructured finite-volume method. The moving boundary due to vaporization is handled by the deformable unstructured grid technique. The pressure-velocity coupling in the density-variable flows is treated by the SIMPLEC algorithm. In terms of the matrix solver, Bi-CGSTAB is employed for the numerically efficient and stable convergence. The n-decane is used as a liquid fuel and the initial droplet temperature is 300K. Computations are performed for the nonevaporating and evaporating droplets with the relative interphase velocity(25m/s). The unsteady vaporization process has been simulated up to the nondimensional time, 25. Numerical results indicate that the mathematical model developed in this study succesfully simulates the main features of the droplet vaporization process in the convective environment.

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