• 제목/요약/키워드: Initial material size

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A New Method of HTS Material Synthesis by Combination of MCA and SHS

  • Korobova, N.;Soh, Dea-Wha
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1270-1273
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    • 2004
  • The combination of methane-chemical activation and Self-propagating High-temperature synthesis (SHS) has widened the possibilities for both methods. For YBCO systems the investigation showed that a short-term mechano-chemical activation of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors of YBCO composition with a grain size d < $1{\mu}m$ is developed. The specific feature of the technique is formation of the $YBa_2Cu_3O_{7-x}$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors (HTS) are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples investigated.

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전기저항 분석을 통한 은나노 입자 합성 시의 입자거동 연구 (Particle Behavior of Silver Nanoparticles Synthesized by Electrical Resistance Analysis)

  • 윤영우;유시홍;양성주;이성의
    • 한국전기전자재료학회논문지
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    • 제28권8호
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    • pp.531-538
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    • 2015
  • This study examined the size and shape of the nano-silver particle through the analysis of electrical resistance when synthesizing nano-sized silver by using the chemical liquid reduction. Changes in particle behaviors formed according to the changes in electronic characteristics by electric resistance in each time period in the beginning of reduction reaction in a course of synthesizing the nano-silver particle formation were studied. In addition, analysis was conducted on particle behaviors according to the changes in concentration of $AgNO_3$ and in temperature at the time of reduction and nucleation and growth course when synthesizing the particles based on the particle behaviors were also examined. As the concentration of $AgNO_3$ increased, the same amount of resistance of approximately $5{\Omega}$ was increased in terms of initial electronic resistance. Furthermore, according to the result of formation of nuclear growth graph and estimation of slope based on estimated resistance, slops of $6.25{\times}10^{-3}$, $2.89{\times}10^{-3}$, and $1.85{\times}10^{-3}$ were derived from the concentrations of 0.01 M, 0.05 M, and 0.1 M, respectively. As the concentration of $AgNO_3$ increased, the more it was dominantly influenced by the nuclear growth areas in the initial phase of reduction leading to increase the size and cohesion of particles. At the time of reduction of nano-silver particle, the increases of initial resistance were $4{\Omega}$, $4.2{\Omega}$, $5{\Omega}$, and $5.3{\Omega}$, respectively as the temperature increased. As the temperature was increased into $23^{\circ}C$, $40^{\circ}C$, $60^{\circ}C$, and $80^{\circ}C$, slopes were formed as $4.54{\times}10^{-3}$, $4.65{\times}10^{-3}$, $5.13{\times}10^{-3}$, and $5.42{\times}10^{-3}$ respectively. As the temperature increased, the particles became minute due to the increase of nuclear growth area in the particle in initial period of reduction.

플록의 입경과 밀도에 따른 부유된 미세 미립자의 침전률 특성에 관한 연구 (A Study on Characteristics of Sedimentation Rate of Suspended Fine Particles under Floc Size and Density)

  • 김종우
    • 한국방재학회 논문집
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    • 제9권4호
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    • pp.107-113
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    • 2009
  • 본 연구는 점착성 미립자의 침전률에 대한 플록의 영향에 관한 것이다. 연구 진행시 플록 밀도와 입경변화의 영향도 고려하였다. 플록입자의 침전속도는 정지수면에서 측정되었다. 플록 입경과 밀도는 수정된 Stokes방정식에 유체의 밀도, 입자의 밀도, 점성계수 및 측정된 침전속도와 입경과의 관계식으로부터 얻은 플록 차원을 이용하여 분석되었다. 석영과 알루미나의 플록지름은 초기농도가 증가함에 따라 증가되었으며, 염도농도의 증가에 따른 석영의 플록된 입경은 $0.8{\sim}10$ ${\mu}m$이다. 플록밀도는 입경이 증가함에 따라 감소하였다. 플록 침전속도와 입경의 관계는 로그표위에 직선식으로 표현된다. 플록 차원($=n_f$)은 초기농도가 증가할 경우 2.65이며, 염도가 증가할 때 2.93이다. 침전속도를 예측하기 위한 비례상수(n)는 제시되었으며, 그 범위는 $1{\sim}1.93$이다.

Bacteria/Fungi 혼합토를 이용한 현장 Bio-barrier 형성 (In Situ Bio-barrier Formation using Bacteria/Fungi-Soil Mixture)

  • 김건하;송영우;구동영
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2000년도 봄 학술발표회 논문집
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    • pp.489-495
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    • 2000
  • When microorganisms such as bacteria and fungi are injected into porous medium such as soils along with appropriate substrate and nutrients, biomass retained in the soil pore. Soil pore size and shape are varied from the initial condition as a result of biofilm formation, which make hydraulic conductivity reduced. In this research, hydraulic conductivity reduction was measured after microorganism are inoculated and cultured with synthetic substrates and nutrients. Biomass-soil mixture was evaluated its applicability to the field condition as an alternative liner material in landfill by measuring hydraulic conductivity change after repetitive freeze-thaw cycles.

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Theory of Nanoparticles Mechanosynthesis

  • Urakaev, Farit Kh.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.405-406
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    • 2005
  • A theoretical investigation of the solid-phase mechanochemical synthesis of nano-sized target product on the basis of dilution of the initial powdered reagent mixture by another product of an exchange reaction is presented. On the basis of the proposed 3-mode particle size distribution in mechanically activated mixture, optimal molar ratios of the components in mixture are calculated, providing the occurrence of impact-friction contacts of reagent particles and excluding aggregation of the nanosized particles of the target reaction product. Derivation of kinetic equations for mechanochemical synthesis of nanoscale particles by the final product dilution method in the systems of exchange reactions is submitted. On the basis of obtained equations the necessary times of mechanical activation for complete course of mechanochemical reactions are designed. Kinetics of solid phase mechanosynthesis of nano-TlCl by dilution of initial (2NaCl + $Tl_2SO_4$) mixture with the exchange reaction product (diluent, $zNa_2SO_4$, $z=z^*=11.25$) was studied experimentally. Some peculiar features of the reaction mechanism were found. Parameters of the kinetic curve of nano-TlCl obtained experimentally were compared with those for the model reaction KBr + TlCl + zKCl = (z + 1) KCl + TlBr ($z=z_l^*=13.5$), and for the first time the value of mass transfer coefficient in a mechanochemical reactor with mobile milling balls was evaluated. Dynamics of the size change was followed for nanoparticle reaction product as a function of mechanical activation time.

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도시철도차량 차체의 경량화를 위한 소재 변경 및 구조체 최적화 연구 (Study on Weight Reduction of Urban Transit Carbody Based on Material Changes and Structural Optimization)

  • 조정길;구정서;정현승
    • 대한기계학회논문집A
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    • 제37권9호
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    • pp.1099-1107
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    • 2013
  • 본 연구에서는 알루미늄 압출재로 구성된 한국형 표준전동차모델(K-EMU)의 차체를 대상으로 치수 최적설계와 구조체 소재 변경을 통한 경량화방안에 대해 연구하였다. 우선 K-EMU 차체의 하부구조, 측벽구조, 단부구조의 부재별 두께를 현재의 압출가능 두께를 적용하여 치수 최적화 기법으로 약 14.8% 경량화 하였다. 그리고 치수최적설계 된 K-EMU 차체에 유지보수성이 좋은 고장력강(SMA570)재질의 프레임타입 하부구조를 적용하여 초기 K-EMU 차체대비 약 3.8% 경량화 된 하이브리드 차체를 도출하였다. 마지막으로 샌드위치 복합재를 하부구조와 지붕구조에 적용하여 초기 K-EMU 차체대비 약 30% 경량화 된 초경량 하이브리드 차체를 도출하였다. 도출된 차체 모델들은 모두 전동차 구조체 하중시험법을 만족하였다.

준설토의 침강형태에 관한 연구 (Settling Mode of the Dredged Soil)

  • 윤상묵;장병욱;차경섭
    • 한국농공학회지
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    • 제45권1호
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    • pp.63-73
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    • 2003
  • The settling of the dredged soil may vary with mineral composition, grain size distribution, initial water content and salt concentration of suspension of the site. A series of settling column test was performed to investigate the behaviour of solid suspension material from dredging and reclamation. Settling mode was divided into four types from the observation of interface and settling curves of clay minerals and marine clay samples, and the relationship charts of salt concentration and the initial water content were established to use in the dredging operation with any salt concentration. The critical initial water content which was defined as a threshold of zone settling and the consolidation settling was varied with salt concentration of water and was proportional to the plasticity of soil in sea water.

Nonlinear resonances of nonlocal strain gradient nanoplates made of functionally graded materials considering geometric imperfection

  • Jia-Qin Xu;Gui-Lin She;Yin-Ping Li;Lei-Lei Gan
    • Steel and Composite Structures
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    • 제47권6호
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    • pp.795-811
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    • 2023
  • When studying the resonance problem of nanoplates, the existing papers do not consider the influences of geometric nonlinearity and initial geometric imperfection, so this paper is to fill this gap. In this paper, based on the nonlocal strain gradient theory (NSGT), the nonlinear resonances of functionally graded (FG) nanoplates with initial geometric imperfection under different boundary conditions are established. In order to consider the small size effect of plates, nonlocal parameters and strain gradient parameters are introduced to expand the assumptions of the first-order shear deformation theory. Subsequently, the equations of motion are derived using the Euler-Lagrange principle and solved with the help of perturbation method. In addition, the effects of initial geometrical imperfection, functionally graded index, strain gradient parameter, nonlocal parameter and porosity on the nonlinear forced vibration behavior of nanoplates under different boundary conditions are discussed.

Application of the Leak Before Break(LBB) Concept to a Heat Exchanger in a Nuclear Power Plant

  • Kwon, Jae-Do;Lee, Choon-Yeol;Lee, Yong-Son;Sul, Il-Chan
    • Journal of Mechanical Science and Technology
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    • 제15권1호
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    • pp.10-20
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    • 2001
  • The leak before break(LBB) concept is difficult to apply to a structure with a thin tube that is immersed in a water environment. A heat exchanger in a nuclear power plant is such a structure. The present paper addresses an application of the LBB concept to a heat exchanger in a nuclear power plant. The minimum leaked coolant amount(approximately 37.9 liters) containing the radioactive material which can activate the radiation detector device installed in near the heat exchanger is assumed. A postulated initial flaw size that can not grow to a critical flaw size within the time period to activate the radiation detector is justified. In this case, the radiation detector can activate the warning signal caused by coolant leakage from initially postulated flaws of the heat exchanger. The nuclear plant can safely shutdown when this occurs. Since the postulated initial flaw size can not grow to the critical flaw size, the structural integrity of the heat exchanger is not impeded. Particularly the informational scenario presented in this paper discusses an actual nuclear plant.

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