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Kinetics of pH Changes during Thermal Degradation of MSG under Model System (Model System 하에서 MSG 열분해 중 pH 변화의 속도론적 연구)

  • Cha, Bo-Sook;Han, Min-Soo;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.24 no.3
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    • pp.232-235
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    • 1992
  • Effect of temperature and initial pH were studied on the pH change of MSG solution during heating. The heating temperature and initial pH of 2% MSG solution were in the range of $100{\sim}120^{\circ}C$ and $pH\;2{\sim}9$, respectively. The results showed that the pH of MSG solution was more rapidly decreased as the temperature increased and the initial pH decreased due to pyroglutamic acid formation from MSG thermal degradation. A linear relationship was obtained between pH decreased and logarithmic value of heating time and the decreasing rate constant of pH were calculated from the slope. The pH decreased$({\Delta}pH)$ after 3 hrs of heating was 1.2 at the initial pH 4 and $120^{\circ}C$ and 0.33 at pH 5 and $120^{\circ}C$ while little pH change measured at the range of $pH\;6{\sim}9$. Activation energy calculated for pH decrease during heating was 11.77 and 22.26 kcal/mole at pH 4 and pH 5, respectively.

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Phosphate sorption to quintinite in aqueous solutions: Kinetic, thermodynamic and equilibrium analyses

  • Kim, Jae-Hyun;Park, Jeong-Ann;Kang, Jin-Kyu;Kim, Song-Bae;Lee, Chang-Gu;Lee, Sang-Hyup;Choi, Jae-Woo
    • Environmental Engineering Research
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    • v.20 no.1
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    • pp.73-78
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    • 2015
  • The aim of this study was to examine the phosphate (P) removal by quintinite from aqueous solutions. Batch experiments were performed to examine the effects of reaction time, temperature, initial phosphate concentration, initial solution pH and stream water on the phosphate adsorption to quintinite. Kinetic, thermodynamic and equilibrium isotherm models were used to analyze the experimental data. Results showed that the maximum P adsorption capacity was 4.77 mgP/g under given conditions (initial P concentration = 2-20 mgP/L; adsorbent dose = 1.2 g/L; reaction time = 4 hr). Kinetic model analysis showed that the pseudo second-order model was the most suitable for describing the kinetic data. Thermodynamic analysis indicated that phosphate sorption to quintinite increased with increasing temperature from 15 to $45^{\circ}C$, indicating the spontaneous and endothermic nature of sorption process (${\Delta}H^0=487.08\;kJ/mol$; ${\Delta}S^0=1,696.12\;J/(K{\cdot}mol)$; ${\Delta}G^0=-1.67$ to -52.56 kJ/mol). Equilibrium isotherm analysis demonstrated that both Freundlich and Redlich-Peterson models were suitable for describing the equilibrium data. In the pH experiments, the phosphate adsorption to quintinite was not varied at pH 3.0-7.1 (1.50-1.55 mgP/g) but decreased considerably at a highly alkaline solution (0.70 mgP/g at pH 11.0). Results also indicated that under given conditions (initial P concentration=2 mgP/L; adsorbent dose=0.8 g/L; reaction time=4 hr), phosphate removal in the stream water (1.88 mgP/g) was lower than that in the synthetic solution (2.07 mgP/g), possibly due to the presence of anions such as (bi)carbonate and sulfate in the stream water.

A Basic Study for Removal of Heavy Metal Elements from Wastewater using Spent Lithium-Aluminum-Silicate(LAS) Glass Ceramics (사용 후 유리세라믹(Lithium-Aluminum-Silicate)을 활용한 중금속 제거 기초 연구)

  • Go, Min-Seok;Wang, Jei-Pil
    • Resources Recycling
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    • v.31 no.4
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    • pp.49-55
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    • 2022
  • In this study, the heavy metal ions (of Pb, Cd, Cr, and Hg) in wastewater were removed using a spent Li2O-Al2O3-SiO2-based crystallized glass previously used as an induction top plate material. Changes in the removal efficiency of heavy metals according to different reaction parameters, such as the amount of zeolite used as a heavy-metal adsorbent, adsorption time, initial concentration of the heavy metals, and pH of the initial solution, were investigated. As the amount of zeolite added increased, the heavy-metal removal efficiency also increased. Adsorption time had a considerable influence on adsorption characteristics, and the removal efficiency of all heavy metals increased with increasing adsorption time. In the case of Cd, the removal efficiency was greatly improved depending on the adsorption time. The initial concentration of the heavy-metal solution did not affect the removal efficiency; however, the initial pH of the heavy-metal solution affected the removal efficiency. More specifically, the removal efficiency of Cd increased while that of Pb and Cr decreased with increasing pH. The adsorption characteristics of Hg were not significantly affected by pH.

Phosphate removing by graphene oxide in aqueous solution

  • Jun, Tae-Sung;Park, No-Hyung;So, Dea-Sup;Lee, Joon-Woo;Shim, Kwang Bo;Ham, Heon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.6
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    • pp.325-328
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    • 2013
  • Phosphate has been removed in waste water by chemically synthesized graphene oxide. Removing efficiency of phosphate was investigated using phosphate dispersion aqueous solution, and 70 % of phosphate was removed in phosphate dispersion solution by chemically synthesized graphene oxide solution. Removing efficiency of phosphate was increased from 70 % to 80 % with assistant of iron nano-particle in chemically synthesized graphene oxide solution. Phosphate removing capacity was up to 89.37 mg/g at initial phosphate concentration of 100 mg/l and temperature of 303 K. The Freundlich was applied to describe the equilibrium isotherms and the isotherm constants were determined.

Anatomical Features Affecting Safranine Solution Permeability in Anthocephalus chinensis (Lam.) Rich. ex Walp

  • Ahmed, Sheikh Ali;Chun, Su-Kyoung
    • Journal of the Korea Furniture Society
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    • v.18 no.4
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    • pp.261-267
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    • 2007
  • This report describes the wood anatomy and 1% safranine solution penetration depth in radial and longitudinal directions of Anthocephalus chinensis belonging to the family Rubiaceae native to Bangladesh. The wood of this species was mostly characterized by diffuse porous, vessel with simple perforation plate, vestured alternate intervessel pittings, relatively medium vessel elements and fiber, and nonseptate fiber with distinctly bordered pits at radial wall. The body ray cell was procumbent with 2 to over 4 rows of upright and square marginal cells. Sometimes, the rays with procumbent, square and upright cells were mixed. Latewood fiber was thin to thick walled while it was very thin walled in earlywood. Axial parenchyma was diffuse, vasicentric, 5-8 cells per parenchyma strand dominantly present. Liquid penetration depth was observed in radial and longitudinal directions at moisture level of 7.42%. Longitudinal penetration was found 6.3 times higher than radial penetration. The initial penetration rate of safranine solution was high, but gradually decreased during the course of time. Different anatomical features were found to be responsible for the variation of safranine solution penetration depth compared to Gmelina arborea.

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Nanofiltration of multi-ionic solutions: prediction of ions transport using the SEDE model

  • Cavaco Morao, A.I.;Szymczyk, A.;Fievet, P.;Brites Alves, A.M.
    • Membrane and Water Treatment
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    • v.1 no.2
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    • pp.139-158
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    • 2010
  • This work focuses on the application of nanofiltration (NF) to the concentration of a pharmaceutical product, Clavulanate ($CA^-$), from clarified fermentation broths, which show a complex composition with six main identified ions ($K^+$, $Cl^-$, ${NH_4}^+$, $H_2{PO_4}^-$, ${SO_4}^{2-}$ and $CA^-$), glucose and glycerol. The solutes transport through the NF membrane pores was investigated using the SEDE (Steric, Electric and Dielectric Exclusion) model. This model was applied to predict the rejection rates of the initial feed solution and the final concentrated solution (10-fold concentrated solution). The best results were achieved with a single fitted parameter, ${\varepsilon}_p$ (the dielectric constant of the solution inside pores) and considering that the membrane selectivity is governed by steric, electric (Donnan) and Born dielectric exclusion mechanisms. While the predicted intrinsic rejections of solutions comprising up to six ions and uncharged solutes were in good agreement with the experimental values, the deviations were much larger for the 10-fold concentrated solution.

Non-stationary mixed problem of elasticity for a semi-strip

  • Reut, Viktor;Vaysfeld, Natalya;Zhuravlova, Zinaida
    • Coupled systems mechanics
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    • v.9 no.1
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    • pp.77-89
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    • 2020
  • This study is dedicated to the dynamic elasticity problem for a semi-strip. The semi-strip is loaded by the dynamic load at the center of its short edge. The conditions of fixing are given on the lateral sides of the semi-strip. The initial problem is reduced to one-dimensional problem with the help of Laplace's and Fourier's integral transforms. The one-dimensional boundary problem is formulated as the vector boundary problem in the transform's domain. Its solution is constructed as the superposition of the general solution for the homogeneous vector equation and the partial solution for the inhomogeneous vector equation. The matrix differential calculation is used for the deriving of the general solution. The partial solution is constructed with the help of Green's matrix-function, which is searched as the bilinear expansion. The case of steady-state oscillations is considered. The problem is reduced to the solving of the singular integral equation. The orthogonalization method is applied for the calculations. The stress state of the semi-strip is investigated for the different values of the frequency.

PROPER ORTHOGONAL DECOMPOSITION OF DISCONTINUOUS SOLUTIONS WITH THE GEGENBAUER POST-PROCESSING

  • SHIN, BYEONG-CHUN;JUNG, JAE-HUN
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.23 no.4
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    • pp.301-327
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    • 2019
  • The proper orthogonal decomposition (POD) method for time-dependent problems significantly reduces the computational time as it reduces the original problem to the lower dimensional space. Even a higher degree of reduction can be reached if the solution is smooth in space and time. However, if the solution is discontinuous and the discontinuity is parameterized e.g. with time, the POD approximations are not accurate in the reduced space due to the lack of ability to represent the discontinuous solution as a finite linear combination of smooth bases. In this paper, we propose to post-process the sample solutions and re-initialize the POD approximations to deal with discontinuous solutions and provide accurate approximations while the computational time is reduced. For the post-processing, we use the Gegenbauer reconstruction method. Then we regularize the Gegenbauer reconstruction for the construction of POD bases. With the constructed POD bases, we solve the given PDE in the reduced space. For the POD approximation, we re-initialize the POD solution so that the post-processed sample solution is used as the initial condition at each sampling time. As a proof-of-concept, we solve both one-dimensional linear and nonlinear hyperbolic problems. The numerical results show that the proposed method is efficient and accurate.

The Clinical Experience of 610 Cases Open Heart Surgery (개심술 610례에 관한 임상적 고찰)

  • 정황규
    • Journal of Chest Surgery
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    • v.21 no.1
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    • pp.36-47
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    • 1988
  • 610 cases of open heart surgery was performed in the Department of Thoracic and Cardiovascular Surgery, Pusan National University Hospital from July 1981 to September 1987. The clinical data was summarized as follows: 1. The age distribution of congenital heart surgery patients was 2 to 41 years old [mean; 13.2 years] and surgery for acquired heart disease was 10 to 57 years old [mean: 32.8 years]. 2. There were 389 cases [63.8%] of acyanotic congenital heart anomalies, 63 cases [10.3%] of cyanotic congenital anomalies and 158 cases [25.9%] of acquired heart disease. 3. For myocardial protection, Bretschneider and potassium glucose solution had been used as cardioplegic solution and then since 1983, GIK solution has been used with repeated infusion method once for every 20 to 30 minutes of time interval after starting initial cardioplegia during operation with excellent results. 4. The ingredient of the priming solution is Hartmann`s solution, sodium bicarbonate, mannitol, potassium chloride, fresh ACD whole blood, calcium chloride, heparin and dexamethasone. 5. There were 96 cases [15.7%] of mild hypothermia, 333 cases [54.6%] of moderate hypothermia and 181 cases [29.7%] of intermediate hypothermia. 6. The mortality rate was 2.3% [9 out of 389 cases] in acyanotic congenital heart disease, 36.5% [23 out of 63 cases] in cyanotic congenital heart disease and 10.8% [17 out of 158 cases] in acquired heart disease, with overall mortality rate of 8.0% [49 out of 610 cases].

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Real-Time Forward Kinematics of the 6-6 Stewart Platform with One Extra Linear Sensor (한 개의 선형 여유센서를 갖는 스튜어트 플랫폼의 실시간 순기구학)

  • Sim, Jae-Gyeong;Lee, Tae-Yeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.9
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    • pp.1384-1390
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    • 2001
  • This paper deals with the forward kinematics of the 6-6 Stewart platform of planar base and moving platform using one extra linear sensor. Based on algebraic elimination method, it first derives an 8th-degree univariate equation and then finds tentative solution sets out of which the actual solution is to be selected. In order to provide more exact solution despite the error between measured sensor value and the theoretic alone, a correction method is also used in this paper. The overall procedure requires so little computation time that it can be efficiently used for real-time applications. In addition, unlike the iterative scheme e.g. Newton-Raphson, the algorithm does not require initial estimates of solution and is free of the problems that it does not converge to actual solution within limited time. The presented method has been implemented in C language and a numerical example is given to confirm the effectiveness and accuracy of the developed algorithm.