• 제목/요약/키워드: Infrared diode

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Effects of variety, region and season on near infrared reflectance spectroscopic analysis of quality parameters in red wine grapes

  • Esler, Michael B.;Gishen, Mark;Francis, I.Leigh;Dambergs, Robert G.;Kambouris, Ambrosias;Cynkar, Wies U.;Boehm, David R.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1523-1523
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    • 2001
  • The wine industry requires practical methods for objectively measuring the composition of both red wine grapes on the vine to determine optimal harvest time; and of freshly harvested grapes for efficient allocation to vinery process streams for particular red wine products, and to determine payment of contract grapegrowers. To be practical for industry application these methods must be rapid, inexpensive and accurate. In most cases this restricts the analyses available to measurement of TSS (total soluble solids, predominantly sugars) by refractometry and pH by electropotentiometry. These two parameters, however, do not provide a comprehensive compositional characterization for the purpose of winemaking. The concentration of anthocyanin pigment in red wine grapes is an accepted indicator of potential wine quality and price. However, routine analysis for total anthocyanins is not considered as a practical option by the wider wine industry because of the high cost and slow turnaround time of this multi-step wet chemical laboratory analysis. Recent work by this ${group}^{l,2}$ has established the capability of near infrared (NIR) spectroscopy to provide rapid, accurate and simultaneous measurement of total anthocyanins, TSS and pH in red wine grapes. The analyses may be carried out equally well using either research grade scanning spectrometers or much simpler reduced spectral range portable diode-array based instrumentation. We have recently expanded on this work by collecting thousands of red wine grape samples in Australia. The sample set spans two vintages (1999 and 2000), five distinct geographical winegrowing regions and three main red wine grape varieties used in Australia (Cabernet Sauvignon, Shiraz and Merlot). Homogenized grape samples were scanned in diffuse reflectance mode on a FOSE NIR Systems6500 spectrometer and subject to laboratory analysis by the traditional methods for total anthocyanins, TSS and pH. We report here an analysis of the correlations between the NIR spectra and the laboratory data using standard chemometric algorithms within The Unscrambler software package. In particular, various subsets of the total data set are considered in turn to elucidate the effects of vintage, geographical area and grape variety on the measurement of grape composition by NIR spectroscopy. The relative ability of discrete calibrations to predict within and across these differences is considered. The results are then used to propose an optimal calibration strategy for red wine grape analysis.

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USE OF NEAR-INFRARED SPECTROSCOPY TO PREDICT OIL CONTENT COMPONENTS AND FATTY ACID COMPOSITION IN OLIVE FRUIT

  • Lorenzo, Leon-Moreno;Ana, Garrido-Varo;Luis, Rallo-Romero
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1512-1512
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    • 2001
  • The University of Cordoba conducts since 1991 a breeding program to obtain new olive cultivars from intraspecific crosses. The objective is to obtain new early bearing and high-quality cultivars. In plant breeding, many seedlings must be tested to increased the chance of getting desirable genotypes. Therefore, fast, cheap and accurate methods of analysis are necessary. The conventional laboratory techniques are costly and time-consuming. Near Infrared Spectroscopy (NIRS) can satisfy the characteristics requested by plant breeders and offers many advantages such as the simultaneous analysis of many traits and cheap cost. The objective of this work was to asses the performance of NIRS to estimate oil fruit components (fruit weight, flesh moisture, flesh/stone ratio and oil flesh content in dry weight basis) and fatty acid composition in olive fruit. Genotypes from reciprocal crosses between ‘Arbequina’, ‘Frantoio’ and ‘Picual’ cultivars have been used in this study. A total of 287 samples, each from a single plant, were scanned using a DA-7000 Diode Array VIS/NIR Analysis System (Perten Instruments), which covers the visible and NIR range from 400-1700 nm. All samples were analysed for fatty acid composition (gas chromatography) and 220 for oil fruit components (oil content by nuclear magnetic resonance), 70% and 30% of samples were randomly assign for the calibration and validation sets respectively. The preliminary results shows that calibration for palmitic, oleic and linoleic acids were highly accurate with calibration and validation values of $r^2$ from 0.85 to 0.95 and 0.76 to 0.91 respectively. Calibration for palmitoleic and estearic acids were less accurate, probably because of the narrow range of variability available for these fatty acids. For the oil fruit components, calibration were high accurate for flesh moisture and oil flesh content in dry weight basis ($r^2$ higher than 0.90 in both calibration and validation sets) and less accurate for the other characteristics evaluated. The first results obtained indicate that NIRS analysis could be an ideal technique to reduce the cost, time and chemical wasted necessary to evaluate a large number of genotypes and it is accurate enough to use for pre-selecting genotypes in a breeding program.

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저출력레이저조사가 배양섬유아세포의 생존력에 끼치는 영향에 관한 실험적 연구 (An Experimental Study on the Effects of Low Level Laser Irradiation on the Cell Viability of Cultured Fibroblast)

  • Keun-Young Yang;Kyung-Soo Han;Sae-Sook Kang
    • Journal of Oral Medicine and Pain
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    • 제18권2호
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    • pp.97-106
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    • 1993
  • This study was performed to investigate the effects of infrared and visible light laser irradiation on cell viability of human gingival fibroblast. For the present study, the author used cultured fibroblast originated from sound gingiva which were fifth of sixth passage. Laser machine utilized here were stomalaser which irradiate infrared (GaAs diode) and red (HeNe) laser in turn with pulse wave pattern or continuous wave pattern, and the machine had several frequency mode presented by regeneration, relaxation and analgesic modalities. Cultured fibroblast samples were divided by this modalities of cell counts and laser exposure time which were 7-seconds of 150 seconds, respectively. 1 day after laser irradiation, each cell-well was treated with MTT and measured optical density with ELISA. The obtained results were as follows : 1. There was a tendency of increasing optical density in proportion to irradiation time in groups of $1\times10^4$ cell per well but in groups of $5\times10^3$ cell per well, reverse phenomena were observed. 2. The difference of optical density according to frequency modalities were not showed significantly except several cases in groups of $5\times10^3$ cell per well. 3. In general, cell viability of cultured human gingival fibroblast wer not showed consistent feature by low level laser irradiation.

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ASSESSING CALIBRATION ROBUSTNESS FOR INTACT FRUIT

  • Guthrie, John A.;Walsh, Kerry B.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1154-1154
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    • 2001
  • Near infra-red (NIR) spectroscopy has been used for the non-invasive assessment of intact fruit for eating quality attributes such as total soluble solids (TSS) content. However, little information is available in the literature with respect to the robustness of such calibration models validated against independent populations (however, see Peiris et al. 1998 and Guthrie et al. 1998). Many studies report ‘prediction’ statistics in which the calibration and prediction sets are subsets of the same population (e. g. a three year calibration validated against a set from the same population, Peiris et al. 1998; calibration and validation subsets of the same initial population, Guthrie and Walsh 1997 and McGlone and Kawano 1998). In this study, a calibration was developed across 84 melon fruit (R$^2$= 0.86$^{\circ}$Brix, SECV = 0.38$^{\circ}$Brix), which predicted well on fruit excluded from the calibration set but taken from the same population (n = 24, SEP = 0.38$^{\circ}$Brix with 0.1$^{\circ}$Brix bias), relative to an independent group (same variety and farm but different harvest date) (n = 24, SEP= 0.66$^{\circ}$ Brix with 0.1$^{\circ}$Brix bias). Prediction on a different variety, different growing district and time was worse (n = 24, SEP = 1.2$^{\circ}$Brix with 0.9$^{\circ}$Brix bias). Using an ‘in-line’ unit based on a silicon diode array spectrometer, as described in Walsh et al. (2000), we collected spectra from fruit populations covering different varieties, growing districts and time. The calibration procedure was optimized in terms of spectral window, derivative function and scatter correction. Performance of a calibration across new populations of fruit (different varieties, growing districts and harvest date) is reported. Various calibration sample selection techniques (primarily based on Mahalanobis distances), were trialled to structure the calibration population to improve robustness of prediction on independent sets. Optimization of calibration population structure (using the ISI protocols of neighbourhood and global distances) resulted in the elimination of over 50% of the initial data set. The use of the ISI Local Calibration routine was also investigated.

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가시통신용 LED 드라이버 전력 효율 성능 향상을 위한 연구 (Visible Light Communication LED driver For research to improve power)

  • 권재현;박건준;김효준;최길상;김용갑
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2012년도 추계학술대회
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    • pp.15-16
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    • 2012
  • LED(Light Emitting Diode)는 기존 광원보다 고효율, 저전력, 장수명으로 인해 일반 조명들을 모두 대체될 것으로 전망되며, 또한 기본적으로 반도체 소자이기 때문에 전기에서 빛으로 바꾸는 속도가 매우 빠르며, 이와 같은 특성을 이용하여 고속 ON-OFF 스위칭을 통한 통신 변조를 수행 할 수 있다. 최근에는 이러한 특징을 이용한 가시광 통신(VLC: Visible Light Communication)기술이 주목받고 있으며, 많은 연구가 진행 되고 있다. 본 논문에서는 LED와 가시광 통신을 융합하여 송신부에는 LED 발광소자와 수신부에는 적외선센서를 사용하여, 미디어 신호 전송을 구현하였다. 미디어 전송 속도를 개선하기위해 가시광 통신에 적용되는 기존 가시광 통신용 LED 드라이버의 전력 변환 효율 및 발열 문제를 개선하고자 통신 시스템의 효율 증대를 위해 새로운 방식의 LED 드라이버를 연구하고자 한다.

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LED용 실리콘 봉지재의 경화방법이 신뢰성에 미치는 영향 (Effect of Curing Method on the Reliability of Silicone Encapsulant for Light Emitting Diode)

  • 김완호;장민석;강영래;김기현;송상빈;여인선;김재필
    • 한국전기전자재료학회논문지
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    • 제25권10호
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    • pp.844-848
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    • 2012
  • Encapsulant curing in terms of convection oven leads to thermal induced stress due to nonuniform thermal conductivity in LED package. We have adopted infrared (IR) light for silicone curing in order to release the stress. The light uniformity irradiated on an encapsulant surface is confirmed to be uniform by optical simulation. Shear strength of die paste using IR compared to convection oven is increased 19.2% at the same curing time, which indicates curing time can be shortened. The indentation depth difference between center and edge of silicone encapsulant in terms of convection oven and IR are 14.8% and 3.4%, respectively. Curing by IR also shows 2.3% better radiant flux persistency rate of LED at $85^{\circ}C$ after 1,000 h reliability test compared to convection curing.

SAVITZKY-GOLAY DERIVATIVES : A SYSTEMATIC APPROACH TO REMOVING VARIABILITY BEFORE APPLYING CHEMOMETRICS

  • Hopkins, David W.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1041-1041
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    • 2001
  • Removal of variability in spectra data before the application of chemometric modeling will generally result in simpler (and presumably more robust) models. Particularly for sparsely sampled data, such as typically encountered in diode array instruments, the use of Savitzky-Golay (S-G) derivatives offers an effective method to remove effects of shifting baselines and sloping or curving apparent baselines often observed with scattering samples. The application of these convolution functions is equivalent to fitting a selected polynomial to a number of points in the spectrum, usually 5 to 25 points. The value of the polynomial evaluated at its mid-point, or its derivative, is taken as the (smoothed) spectrum or its derivative at the mid-point of the wavelength window. The process is continued for successive windows along the spectrum. The original paper, published in 1964 [1] presented these convolution functions as integers to be used as multipliers for the spectral values at equal intervals in the window, with a normalization integer to divide the sum of the products, to determine the result for each point. Steinier et al. [2] published corrections to errors in the original presentation [1], and a vector formulation for obtaining the coefficients. The actual selection of the degree of polynomial and number of points in the window determines whether closely situated bands and shoulders are resolved in the derivatives. Furthermore, the actual noise reduction in the derivatives may be estimated from the square root of the sums of the coefficients, divided by the NORM value. A simple technique to evaluate the actual convolution factors employed in the calculation by the software will be presented. It has been found that some software packages do not properly account for the sampling interval of the spectral data (Equation Ⅶ in [1]). While this is not a problem in the construction and implementation of chemometric models, it may be noticed in comparing models at differing spectral resolutions. Also, the effects on parameters of PLS models of choosing various polynomials and numbers of points in the window will be presented.

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Dynamic Quasi-Elastic Light Scattering Measurement of Biological Tissue

  • Youn, Jong-In;Lim, Do-Hyung
    • 대한의용생체공학회:의공학회지
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    • 제28권2호
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    • pp.169-173
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    • 2007
  • During laser irradiation, mechanically deformed cartilage undergoes a temperature dependent phase transformation resulting in accelerated stress relaxation. Clinically, laser-assisted cartilage reshaping may be used to recreate the underlying cartilaginous framework in structures such as ear, larynx, trachea, and nose. Therefore, research and identification of the biophysical transformations in cartilage accompanying laser heating are valuable to identify critical laser dosimetry and phase transformation of cartilage for many clinical applications. quasi-elastic light scattering was investigated using Ho : YAG laser $(\lambda=2.12{\mu}m\;;\;t_p\sim450{\mu}s)$ and Nd:YAG Laser $(\lambda=1.32{\mu}m\;;\;t_p\sim700{\mu}s)$ for heating sources and He : Ne $(\lambda=632.8nm)$ laser, high-power diode pumped laser $(\lambda=532nm)$, and Ti : $Al_2O_3$ femtosecond laser $(\lambda=850nm)$ for light scattering sources. A spectrometer and infrared radiometric sensor were used to monitor the backscattered light spectrum and transient temperature changes from cartilage following laser irradiation. Analysis of the optical, thermal, and quasi-elastic light scattering properties may indicate internal dynamics of proteoglycan movement within the cartilage framework during laser irradiation.

실내 가시광 통신 시스템에서 성능에 영향을 주는 요인에 관한 연구 (A Study About Fact Influence on Performance at Indoor Visible Light Communication)

  • 이창우;최덕재;김한필
    • 조명전기설비학회논문지
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    • 제27권10호
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    • pp.1-8
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    • 2013
  • Wireless Visible Light Communication is the technology that enables communication using LED illumination Infrastructure instead of existing illumination such as incandescent lamp or fluorescent light. Because VLC uses light for communication, it has no problem of frequency permission and is harmless to human body. It is also possible to check the communication through eye. So VLC can be used as a supplement to the Radio Frequency communication, Infrared in indoor environment. So far, researchers on the LED Visible light communication have focused on the increasing transmission speed, transmission distance, modulation method. However, there is few research of main factors that influence on system performance. System performance has been mainly predicted through simulation. In this paper, I recognized that these factors such as outside light noise, obstacle, LED panel position or emitted angle have a great impact on wireless communication system. So I experimented VLC system by changing distance and position to discover location suitable for BER regulation.

색온도 가변형 LED 조명제어시스템 (The Color Temperature Flexibility-typed LED Lighting Control System)

  • 김혜명;양우석;조영식;박대희
    • 전기학회논문지
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    • 제64권2호
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    • pp.284-288
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    • 2015
  • The color temperature flexibility-typed Lighting Emitting Diode(LED) lighting control system proposed in this thesis employs Pulse Width Modulation(PWM) technique to control the brightness of LED lighting. The LED lighting used as a light source has 20W downlight composed of two types of LED chips: one is Warm White and the other is Cool white. One multi-sensor module consisting an infrared sensor, an illumination sensor, and a temperature sensor was made, to which Bluetooth wireless communication technique was applied to enable a smartphone application to control lighting brightness and identify the information collected from the sensor. CS-1000, a spectroradiometer, was used to measure LED dimming control and the changing values of a color temperature in eight steps. According to a test, it was found that it was possible to change a color temperature from 3187K of Warm White LED to 5600K of Cool White LED.