• Journal of Korean Society of Water and Wastewater
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• v.28 no.3
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• pp.287-297
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• 2014

It is important to predict chlorine decay with different water purification processes and distribution pipeline materials, especially because chlorine decay is in direct relationship with the stability of water quality. The degree of chlorine decay may affect the water quality at the end of the pipeline: it may produce disinfection by-products or cause unpleasant odor and taste. Sand filtrate and dual media filtrate were used as influents in this study, and cast iron (CI), polyvinyl chloride (PVC), and stainless steel (SS) were used as pipeline materials. The results were analyzed via chlorine decay models by comparing the experimental and model parameters. The models were then used to estimate rechlorination time and chlorine decay time. The results indicated that water quality (e.g. organic matter and alkalinity) and pipeline materials were important factors influencing bulk decay and sand filtrate exhibited greater chlorine decay than dual media filtrate. The two-component second-order model was more applicable than the first decay model, and it enabled the estimation of chlorine decay time. These results are expected to provide the basis for modeling chlorine decay of different water purification processes and pipeline materials.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.106-110
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• 2001

Formation of stoichiometric lithium-, nickel-, and zinc- ferrites by calcining organo-metallic precursors a temperature below 40$0^{\circ}C$ is examined using DTA/TG, and XRD techniques. It attempts to simulate th immobilization of metal ions in industrial liquid influents (waste) through the synthesis of stoichiometric spinel ferrites (SSF). Two steps of the SSF formation during thermal treatments are noted. The transformation of magnetite to ${\gamma}$ - Fe$_2$O$_3$and subsequent first formation of SSF were observed at temperatures ranging from 200 to 45$0^{\circ}C$. Th formation of cation-containing ${\gamma}$-Fe$_2$O$_3$and subsequent second formation of the ferrite occurred at temperature ranges of < 45$0^{\circ}C$ and 500 to $650^{\circ}C$, depending on the heating rate used. Then the temperature range of 200t 45$0^{\circ}C$ is critical to the performance of the technique, because a calcination at the range would lead to a complete formation of SSF, avoiding the occurrences of ${\gamma}$-Fe$_2$O$_3$and ion-containing ${\gamma}$-Fe$_2$O$_3$. If not, so $\alpha$-Fe$_2$O$_3$would occur. And annealing at temperature above $650^{\circ}C$ must be employed by which solid-state reactio of $\alpha$-Fe$_2$O$_3$with metal ions (possibly metal oxides) to form SSF can be conducted.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.1
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• pp.84-98
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• 2000

Control of Trihalomethanes(THMs) is a major concern of many water treatment plants. A number of researchers have studied the effectiveness of activated carbon adsorption process in removing THMs or organic halogen compounds. Recently, attention has been paid to the biological activated carbon (BAC) treatment of THM precursors as an alternative to the carbon adsorption treatment because of its effectiveness as well as its low running cost. In this study, changes of THM formation potential(THMFP) and removal of substrates in the SBR effluent were investigated in an attempt to clarify the mechanisms of the decrease/increase of THMFP in the BAC treatment. The increase and decrease of THMFP concentrations were observed in effluents during prolonged operation. When PCP or DBS was feeded as substrate contained in SBR effluent, the THMFPs were easyly removed with TOCs removal. But the case of SBR effluent containing SDS or glycine was introduced, and when microbial growth came to its near steady state, the THMFPs of treated effluents were increased more or less in comparison to those in the influents. Such increases of THMFP coincided with the increase in microbial growth within the activated carbon fiber(ACF) column. In the case of only sucrose was feeded as substrate on ACF colume, THMFP concentrations of effluent were higher than those of influent. The THMFP concentration was significantly increased on inlet part of ACF column, which biomass inhabits abundantly, then they were decreased gradually. These increases mean production of the secondary THM precursors by biological activities, which can be removed by adsorption and biological degradation on ACF column.

• Analytical Science and Technology
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• v.23 no.5
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• pp.477-484
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• 2010

Personal care products are a diverse group of synthetic organic chemicals such as antimicrobial compounds, UV filters and organo-phosphate flame retardants and derived from individual usages of soaps, toothpaste and cosmetics. It has been detected in municipal sewage effluent and various environmental samples such as surface water, marine, soil, sediment and aquatic biota in many countries. The occurrence of personal care products in environmental samples could negatively impact the health of the ecosystem and humans, due to persistent, long-term chronic exposure of aquatic organisms. In this study, fifteen personal care products in aquatic environmental samples were determined by gas chromatography-mass spectrometry (GC-MS) with liquidliquid extraction (LLE). Method detection limits were in the range of $0.004\sim0.273\;{\mu}g/L$. Two compounds (TCEP, TCPP) were detected in surface waters and seven compounds (triclosan, 4-MBC, EHMC, BP-3, TCEP, TPP, TBEP) were detected in sewage treatment plants (STP) influents or effluents.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.250-257
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• 2006

The objective of this study is to propose an alternative process for the small sewage treatment plants in rural communities. A biofilter has been used for biological wastewater treatment, which is becoming the alternative to the conventional activated sludge system. The proposed process used in this study, which is packed with floating media (i.e. expanded polystylene), has advantages of biofilter system and alternative flow system and they are incorporated into one process. Pilot and bench scale studies were performed using domestic wastewater. In the results of pilot plant study, it was observed that the stable effluent water quality was achieved and it met the present effluent criteria of suspended solid (SS), organic matters, T-N and T-P. In the study for determination of the cycle of backwashing, it was observed that the cycle of backwashing depended on BOD loading rates of influents. In the BOD loading rates of $0.5kg\;BOD/m^3{\cdot}day$ and $1.0kg\;BOD/m^3{\cdot}day$, the backwashing cycle of 28 hour and 16 hour were needed, respectively. The optimum backwashing time was 120~80 seconds at the media expansion rate of 50%. In the removal of SS, organic matters, T-N and T-P, SS removal was rather achieved by physical filtration than biological mechanism and the removal of organic matters except for SS, T-N and T-P were mainly rather achieved by biological mechanism than physical filtration. In bench-scale study, the effects of recirculation rate was investigated on removal of SS, TCOD, T-N and T-P. It was observed that the recirculation made removal efficiencies of SS, TCOD, T-N and T-P increased. Especially, in T-N removal, the increase of T-N removal efficiency of 40% was observed in the reicirculation rate of 1Q compared with 0Q.

• Membrane and Water Treatment
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• v.6 no.1
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• pp.77-94
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• 2015

Ultrafiltration membranes have several advantages over conventional drinking-water treatment. However, this technology presents major limitations, such as irreversible fouling and low removal of natural organic matter. Fouling depends heavily on the raw-water quality as well as on the operating conditions of the process, including flux, permeate recovery, pre-treatment, chemical cleaning, and backwashing. Starting with the premise that the optimisation of operating variables can improve membrane performance, different experiments were conducted in a pilot plant located in Granada (Spain). Several combinations of permeate and backwashing flow rates, backwashing frequencies, and aeration flow rates were tested for low-quality water coming from Genil River with the following results: the effluent quality did not depend on the combination of operating conditions chosen; and the membrane was effective for the removal of microorganisms, turbidity and suspended solids but the yields for the removal of dissolved organic carbon were extremely low. In addition, the threshold transmembrane pressure (-0.7 bar) was reached within a few hours and it was difficult to recover due to the low efficiency of the chemical cleanings. Moreover, greater transmembrane pressure due to fouling also increased the energy consumption, and it was not possible to lower it without compromising the permeate recovery. Finally, the intensification of aeration contributed positively to lengthening the operation times but again raised energy consumption. In light of these findings, the feasibility of ultrafiltration as a single treatment is questioned for low-quality influents.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.6
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• pp.559-572
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• 2018

The aim of this study was to evaluate pretreatment methods for 27 pharmaceuticals and personal care products (PPCPs) in various sewage samples using a modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) and online solid-phase extraction with LC-MS/MS. Extraction efficiencies of PPCPs in the solid phase under different experimental conditions were evaluated, showing that the highest recoveries were obtained with the addition of sodium sulfate and ethylenediaminetetraacetic acid disodium salt dehydrate in acidified conditions. The recoveries of target compounds ranged from 91 to 117.2% for liquid samples and from 61.3 to 137.2% for solid samples, with a good precision. The methods under development were applied to sewage samples collected in two sewage treatment plants (STPs) to determine PPCPs in liquid and solid phases. Out of 27 PPCPs, more than 19 compounds were detected in liquid samples (i.e., influent and effluent) of two STPs, with concentration ranges of LOQ-33,152 ng/L in influents and LOQ-4,523 ng/L in effluents, respectively. In addition, some PPCPs such as acetylsalicylic acid, ibuprofen, and ofloxacin were detected at high concentrations in activated sludge as well as in excess sludge. This methodology was successfully applied to sewage samples for the determination of the target compounds in STPs.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.277-287
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• 2006

Production loads of the contaminants near the Nakdong-river are, BOD : $1,006ton{\cdot}day^{-1}$, TN : $117ton{\cdot}day^{-1}$, and TP : $21ton{\cdot}day^{-1}$. Among the sources of contamination, the biggest contribution to the production load was shared by the human population, which maintains 40.7% of BOD, 44.2% of TN, and 52.5% of TP production. Similarly, among the sources of discharge load, the human population contributed 45.0% of BOD, 34.5% of TN, and 45.8% of TP. Results of flow investigation in 2001 and 2002 indicate that among the side streams, Nam-river showed the greatest average flow. In case of main stream flow, it was increased in the downstream due to the increase of the influents from the side streams. In case of BOD, COD, TOC and SS, high values were detected at Keumho-river where industrial wastewater was discharged as high level concentration. In case of the main stream, Koryoung point where direct influence of Keumho-river and Seongseo industrial complex is evident showed high BOD, COD and TOC. Oxidized nitrogen compounds and total nitrogen showed similar patterns of BOD, COD, and TOC. Especially, nitrate nitrogen was relatively high at all points. However, in case of Chlorophyll-a, relatively high values were observed at mid- and downstream areas such as Koryoung, Namjee, Soosan, Moolkeum and Hakooeun. This could be caused by the slow flow rate and the abundant nutrient salts attributed by the side streams. Relatively better water quality was observed in 2002 when the flow was relatively abundant than that in 2001. Results of investigation during 2001-2002 showed that delivery load increased as the flow reaches downstream. In 2001, delivery loads at the downstream Soosan-bridge were BOD $22,152ton{\cdot}day^{-1}$, COD $45,467ton{\cdot}day^{-1}$, TN $22,062ton{\cdot}day^{-1}$, TP $926ton{\cdot}day^{-1}$. Delivery loads in 2002 were increased due to the increase of the rainfall. They are BOD $25,876ton{\cdot}day^{-1}$, COD $64,200ton{\cdot}day^{-1}$, TN $41,101ton{\cdot}day^{-1}$, and TP $1,362ton{\cdot}day^{-1}$.

• Korean Journal of Environmental Agriculture
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• v.22 no.2
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• pp.124-129
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• 2003

The objectives of this study are to manufacture an efficient $TiO_2$, photocatalyst and to delineate optimum operational parameters for TCE (trichloroethylene) degradation in a photocatalytic oxidative reactor. The $TiO_2$ photocatalyst irradiated by 365 nm UV light is expected to increase degradation of TCE in solution by a series of photocatalytic oxidations in the reactor. A new membrane $TiO_2$ photocatalyst wns eventually developed by coating a mixture of Davan-C(0.24 wt%) and PVA(0.16 wt%) on the surface of slips using the slip-casting method. Results show that increase in the number of coating of $TiO_2$ sol on surface of photocatalysts and in the surface thickness improved the endurance and photocatalysts, but these physical modifications caused significant decrease in the overall degradation efficiency of TCE. Pre-aeration or recirculation of the influents to the reactors containing TCE increased degradation efficiency of TCE. The optimum operational conditions far the surface area of photocatalysts and UV light intensity appeared to be $1.47\;mL/cm^2$ and $225\;W/cm^2{\times}100$, respectively, in the reactor. Based on the overall experimental results, the photocatalytic oxidation of TCE with the new membrane $TiO_2$ photocatalyst is found to be very effective under the operational conditions delineated in this study.

• Korean Journal of Ecology and Environment
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• v.39 no.4 s.118
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• pp.471-480
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• 2006

The field scale experiment was performed to examine the performance of the constructed wetland for nonpoint source (NPS) pollution loading reduction. Four sets (each set of 0.88 ha) of wetland (0.8 ha) and pond (0.08 ha) systems were used. Water flowing into the Seokmoon estuarine reservoir from the Dangjin stream was pumped into wetland systems. Water depth was maintained at 0.3-0.5 m and hydraulic retention time was managed to about 2-5 days; emergent plants were allowed to grow in the wetland. The wetland effluent concentrations of $BOD_5$, TSS, and T-N were higher in winter than in the growing season excepting the T-P, and effluent $BOD_5$ concentration was higher than influents in winter. Mass retention of T-N and T-P was stable throughout the year, whereas mass retention of $BOD_5$ and TSS was decreased in winter. $BOD_5$, TSS, T-N, and T-P performance of the experi-mental system was compared with the existing database (North American Treatment Wetland Database), and was within the range of general system performance. From the first-order analysis, T-P was virtually not temperature dependent, and $BOD_5$ and TSS were more temperature dependent than T-N. Overall, the wetland system was found to be an adequate alternative for treating polluted stream water with stable removal efficiency and recommended as a NPS control measures.