• Korean Journal of Agricultural Science
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• v.32 no.1
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• pp.1-8
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• 2005

This study was carried out to examine the effect of heavy traffic on chemical properties of soil in roadside trees of Daejeon city. Soil samples at 0~10cm and 10~30cm depths were collected from soil of the roadside trees, Platanus occidentalis, and Ginko biloba, Soil pH in heavy traffic regions were around 7.0 at 0~10cm and 10~30cm soil depths because of spraying of calcium chloride for snow moving. The concentrations of Fe, Cd, Cu, Zn, and Pb in soil were higher in heavy traffic regions(Daejeon Station and Daehwa Industrial Complex) than in light traffic region (Chungnam National University). The result could be from rubbing and wear of car tire and metals when they travel.

• Analytical Science and Technology
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• v.32 no.3
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• pp.77-87
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• 2019

High viscosity carbon black dispersions are used in various industrial fields such as color cosmetics, rubber, tire, plastic and color filter ink. However, carbon black particles are unstable to heat due to inherent characteristics, and it is very difficult to keep the quality of the product constant due to agglomeration of particles. In general, particle size analysis is performed by dynamic light scattering (DLS) during the dispersion process in order to select the optimum dispersant in the carbon black dispersion process. However, the existing low viscosity analysis provides reproducible particle distribution analysis results, but it is difficult to select the optimum dispersant because it is difficult to analyze the reproducible particle distribution at high viscosity. In this study, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) analysis methods were compared for reproducible particle size analysis of high viscosity carbon black. First, the stability of carbon black dispersion was investigated by particle size analysis by DLS and AsFlFFF according to milling time, and the validity of analytical method for the selection of the optimum dispersant useful for carbon black dispersion was confirmed. The correlation between color and particle size of particles in high viscosity carbon black dispersion was investigated by using colorimeter. The particle size distribution from AsFlFFF was consistent with the colorimetric results. As a result, the correlation between AsFlFFF and colorimetric results confirmed the possibility of a strong analytical method for determining the appropriate dispersant and milling time in high viscosity carbon black dispersions. In addition, for nanoparticles with relatively broad particle size distributions such as carbon black, AsFlFFF has been found to provide a more accurate particle size distribution than DLS. This is because AsFlFFF, unlike DLS, can analyze each fraction by separating particles by size.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.3
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• pp.306-311
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• 2017

This paper deals with the design optimization of the kinematic characteristics of an automotive suspension system. The kinematic characteristics of the suspension determine the attitude of the wheels, such as the toe and camber, which not only relates to tire wear during driving, but also greatly affects the control of the vehicle and its stability, which corresponds to the motion performance of the vehicle. Therefore, it is very important to determine the characteristics of the suspension mechanism at the initial stage of the design. In this study, a displacement analysis is performed to determine the kinematic properties of the suspension for the McPherson strut suspension. For this purpose, a set of constraint equations for the joints constituting the suspension mechanism was established and a program was developed to solve them. We also used ADS, a design optimization program, to obtain the desired kinematic characteristics of the suspension. As the design variables for optimization, we used the coordinates of the hard points, which are the points of attachment of the suspension to the vehicle body, and are defined as the summation of the toe-in for the up and down movement of the wheel as the objective function. As the constraint functions, the maximum camber angle and minimum roll center height, which are design requirements, are considered. As a result of this study, it was possible to determine the optimal locations of the hard points that satisfy both constraint functions and minimize the change of the toe-in.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.7
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• pp.2925-2930
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• 2011

A vehicle fuel economy is very important issue in the view of fuel cost and environmental regulation. The fuel economy is much improved according to the development of electric, electronic and mechanical technology, but up to now the measurement of it tests the given mode(LA-4, FTP-75, etc) within computer simulation program and engine dynamometer. This fuel economy is different with it of real road. The one of main reason is not considered the gradient of the road. To estimate the effects of fuel economy at highway with gradient in this paper, we measure the amount of fuel consumption and calculate the fuel economy of it with running the Youngdong highway with high gradient. Also this paper analysis and compares the fuel economy with gradient and without gradient when the vehicle runs the same driveway. Then we calculate the total energy created the difference of fuel consumption amount of the two cases and calculate the consumpted energy by tire driving force from the torque and power of engine in the simulation. This paper verifies the relation of the driving force and the total energy by creating the difference of fuel consumption amount. This paper also proposes the method of fuel economy improvement despite of gradient at the result.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.1
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• pp.1-8
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• 2021

This study developed low-cost and high-efficiency pavement condition monitoring technology to produce the key information required for pavement management. A noise and artificial intelligence-based monitoring system was devised to compensate for the shortcomings of existing high-end equipment that relies on visual information and high-end sensors. From idea establishment to system development, functional definition, information flow, architecture design, and finally, on-site field evaluations were carried out. As a result, confidence in the high level of artificial intelligence evaluation was secured. In addition, hardware and software elements and well-organized guidelines on system utilization were developed. The on-site evaluation process confirmed that non-experts could easily and quickly investigate and visualized the data. The evaluation results could support the management works of road managers. Furthermore, it could improve the completeness of the technologies, such as prior discriminating techniques for external conditions that are not considered in AI learning, system simplification, and variable speed response techniques. This paper presents a new paradigm for pavement monitoring technology that has lasted since the 1960s.

• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.837-845
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• 2017

A recirculating integrated system composed of a fluidized biofilter filled with waste-tire crumb media fixed with return sludge from wastewater treatment facility of D dyeing industrial center, and a UV/photocatalytic reactor packed with calcined $TiO_2$ coated-glass beads as photocatalyst-support, was constructed and was run to treat authentic textile-dyeing wastewater from D-dyeing industrial center, which was mixed with an alkaline polyester-weight-reducing wastewater and a wastewater from sizing process. As a result, its total removal efficiency(RE(tot)) of $COD_{cr}$ and colors were ca. 81% and 55%, respectively. The synergy effect of the recirculating integrated system to enhance total removal efficiency(RE(tot)) of $COD_{cr}$ and colors were evaluated at most ca. 7% and 3%, respectively. The fluidized biofilter and the UV/photocatalytic reactor were responsible for ca. 94% and 6% of the total $COD_{cr}$ removal efficiency, respectively, and were also responsible for ca. 86% and 14% of the total color-removal efficiency, respectively. Thus, the degree of the UV/photocatalytic reactor-unit process's contribution to RE(tot) of color, was about 2.4 times of that to RE(tot) of $COD_{cr}$. Therefore, the UV/photocatalytic reactor facilitated the more effective elimination of colors by breaking down the chemical bonds oriented from colors of dyes such as azo-bond, than $COD_{cr}$. In addition, the effect of the removal efficiency of each unit process(i.e., the fluidized biofilter or the UV/photocatalytic reactor) of the recirculating integrated system on RE(tot) of $COD_{cr}$ and colors, was analysed by establishing its model equation with an analytic correlation.

• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.310-316
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• 2020

Terpene-modified phenolic resins were used to improve the tires wet traction related to the driving safety and also rolling resistance related to fuel efficiency. In this work, alpha-pinene, beta pinene, and delta limonene resins, which constitute different basic structures of terpene-modified phenolic resins, were individually added to the tread compounds of tires and their physical properties were compared with those of the alkyl phenol resin compounds. Alkyl phenolic resins showed no significant difference in tangent delta from terpene-modified phenolic resins at 0 ℃, which is related to wet traction, but showed higher tangent delta at 80 ℃, which is related to rolling resistance, indicating smaller fuel efficiency improvement effects. Among the terpene-modified phenolic resins, beta pinene one showed improved wet traction and fuel efficiency compared to those of other resins. Delta limonene resin showed the best wet traction improvement effect, and alkyl phenolic resins showed relatively high tensile strength and abrasion property. All terpene-modified resins exhibited better rolling resistance than those of alkyl phenolic ones so that they can be said to have better fuel efficiency improvement effects and also to improve other properties compared to those of blanks. Terpene-modified phenolic resins could be used when mixing tire compounds referring to the properties of the phenolic resins revealed in this work, which could result in preparing compounds with improved wet traction and rolling resistance.

• Journal of Preventive Medicine and Public Health
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• v.35 no.4
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• pp.282-286
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• 2002

Objectives : The level of 4-hydroxyproline (4-Hyp) in human urine was measured using high performance liquid chromatography (HPLC) with a fluorescence detector. This method is useful for medical examinations and investigating the radicals induced by physical, chemical, mental stresses. This method is superior to many published several methods in terms of its low cost and ability to analyze many samples. Methods : The urine from workers in a tire manufacturing company (22 male pre- and post-shift workers) and 18 office-workers as controls were analyzed. Data concerning age, the cumulative drinking amount and the cumulative smoking amount was collected with a questionnaire. The optimum applied amount of dansyl-Cl, the optimum reaction temperature and time, the recoveries and the optimum pH of the eluent and buffer were determined.4-Hyp from human urine was derivatized with dansyl-Cl (dimethylamino-naphthalene-1-sulfonyl chloride) after removing the a-amino acid by a treatment with phthalic dicarboxaldehyde (OPA) and cleaned with Bond Elut C18 column. The 4-Hyp derivatives were separated on a reversed phase column by gradient elution with a phosphate buffer (5 mmol, pH 8.0) and acetonitrile, and detected by fluorescence measurements at 340 nm (excitation) and 538 nm (emission). Results : The detection limit for the urinary free 4-Hyp was $0.364{\mu}mol/l$. The recovery rate of 4-Hyp was 99.7%, and the effective pH of the phosphate buffer and borate buffer were 3.0 and 8.0, respectively. From statistical analysis, age, drinking and smoking did not affect the urinary free 4-Hyp in both the controls and workers. The range of urinary 4-Hyp in the controls, pre-shift, and post-shift workers were 0.33-16.44, N.D-49.06, and $0.32-56.27{\mu}mol/l$. From the pared-sample t-test, the urinary 4-Hyp levels in post-shift workers ($11.82{\pm}6.73\;nmmol/mg\;Cre$) were 2-fold higher than in pre-shift workers ($5.36{\pm}5.53\;nmol;/mg\;Cre$) and controls ($4.91{\pm}4.89\;nmol;/mg\;Cre$). Conclusions : This method was developed with high sensitivity, accuracy, and precision. The present method was effectively applied to analyze the urinary free 4-Hyp in both controls and workers.