• Korea Journal of Cosmetic Science
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• 제2권1호
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• pp.21-31
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• 2020

The aim of this study is to develop a sunscreen stick formulation technology with excellent water resistance and washability. Consumers' needs for sunscreen products are diversifying. Water resistance and ease of washing are both important factors in sunscreen products. However, it is difficult to develop a sunscreen formulation that satisfies these two factors at the same time, because these two elements are in conflict. Fatty acid has a hydrophobic property against the water with low or neutral pH, but when it contacts with soapy water which has high pH, saponification occurs and the fatty acids become surfactants and can be dispersed in the water. Using the reaction characteristics of fatty acids, we can make sunscreen that is highly resistant to water or sweat, but is only selectively removed from soapy water. We found that the sunscreen stick containing fatty acids had better water resistance and washability than the sunscreen sticks without fatty acid. The sunscreen stick containing fatty acids showed a tendency to improve water resistance by scattering ultraviolet rays of long wavelength area by forming insoluble precipitation with divalent ions in tap water after immersion. In addition, an increase in the fatty acid content tended to also increase the ease of cleaning the sunscreen stick. Solid fatty acid was advantageous in improving water resistance than liquid fatty acid, but there was no difference between solid fatty acids and liquid fatty acid in washability. When it comes to stability, the sunscreen stick using liquid fatty acids maintained a high hardness and melting point, and showed no sweating. Based on this study, it is possible to develop an easy washable sunscreen stick formulation technology that has excellent water resistance but is selectively removed only in soapy water.

• 한국해양환경ㆍ에너지학회지
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• 제5권2호
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• pp.62-67
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• 2002

본 연구는 '천수용 다기능 해양폐기물 수거시스템 개발(PART I 초기 개념설계)'의 후속연구로서, 천수용 다기능 해양폐기물 수거시스템의 시스템 구성 및 성능시험 결과에 대하여 논한다(조[2003]). 수거깊이 15미터 이내의 항내 침적폐기물의 수거를 위한 다관절 수거시스템과 100미터 이내의 예인식 수거시스템이 개발되었다(해양수산부[2001]). 다관절 수거시스템은 부유폐기물, 침적 잔여폐기물의 수거, 작업의 고효율화를 위한 스틸와이어커터 시스템도 포함이 되어 다기능화 되어있다. 이 시스템의 시제품을 제작하여 수심이 낮은 해역에서 실해역 시운전을 수행, 시스템의 성능검증을 수행하였다. 결과로서, 개발된 시스템은 안전하고 원활하게 작동되어 시스템의 타당성을 입증하였다.

• 한국산학기술학회논문지
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• 제18권4호
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• pp.641-647
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• 2017

디젤 엔진은 가솔린기관에 비해 강력한 파워와 연료의 경제성 및 $CO_2$ 배출양이 적어 상용차뿐만 아니라 일반승용차에서도 시장의 수요가 지속적으로 증가하고 있다. 디젤 엔진의 연소특성상 국부적인 고온반응 영역에서 질소산화물과 확산연소 영역에서 입자상물질이 많이 배출되므로 엄격해진 배기규제를 충족시키기 위해서 자동차와 선박등 촉매후처리장치 장착의 비중이 점차 증가하고 있다. 그 중 입자상물질 저감장치로써 입자상물질필터가 장착되어 왔으나 PM중 약 50%가 연료와 엔진오일에서 석출된 재 성분이 침적되면 필터를 손상시키므로 고온의 연소방식이 아닌 세정제를 이용한 제거기술이 절실히 필요하다. 이 연구의 목적은 디젤 엔진용 촉매코팅된 디젤입자상물질필터에 침적된 재를 세정을 함에 있어서 촉매의 물질의 물리화학적인 특성을 연구하는 것이다. 30분 동안 세정제에 담근 S4 샘플은 침투력이 강한 성분으로 인하여 입자들끼리 응집되고 수축되었다. 재에 침투력이 강한 침투제와 물과 기름을 혼합시켜주는 계면활성제 성분이 적절하게 제조된 S1 샘플의 세정특성이 가장 좋았다. 침투제인 수산화칼륨과 규산나트륨 성분이 첨가된 S4 샘플의 와쉬코트 손실률은 약 13%로 증가하였다. 촉매코팅된 디젤입자상물질필터의 와쉬코트 손실률이 약 13% 이하조건에서 유해가스 성분을 저감시킬 수 있었다.

• 한국환경과학회지
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• 제18권12호
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• pp.1339-1347
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• 2009

This study tried to investigate and analyze the actual state such as the regional, classified, and material characteristics of the water quality in order to research the several factors by which the filtrated water of the total 250 cases can be polluted in the water tank. The 215 points (86%) clean the water tanks twice a year regularly and J-city has done the best job of cleaning the water tanks. The fifty points (20%) of the total 250 investigation points examine the water quality of the water tanks every year, however, the 175 investigation points (70%) do not execute the inspection of water quality. In the case of the regional characteristics in the water quality, the 23 points (46%) in H-county, the 17 points (34%) in S-county, and the 16 points (32%) in G-city are incongruent in the standard, and the incongruity ratio of the water quality in J-city is the lowest. The result of the classified incongruity shows that total coliforms were found at the 61 investigation points, mesophilic bacteria were found at the 27 points, and turbidity was found at the 12 points. In the case of the material incongruity, concrete was found at the 63 investigation points as the most distinguished factor, and FRP (fiberglass reinforced plastic) at the 23 points, SMC (sheet molding compound) at the 12 points, and stainless steel was found at the 2 points.

• 상하수도학회지
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• 제32권5호
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• pp.453-460
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• 2018

The impact of sodium hydroxide, which is one of chemicals of clean in place (CIP) for removing membrane fouling, on the PVDF membrane is reviewed with respect to physical/chemical structural change, the permeability affected therefrom. Based on the cleaning concentration applied in membrane water treatment facilities, 10% of accumulated defluorination was confirmed up to 166g.hr/L which reflects the exposure time. However, membrane resistance was confirmed to be reduced by about 10%. Through FT-IR and EDS analysis, reduction of F and change of are confirmed as factors that affect the permeability of membrane. Membrane resistance, which affects permeability, is affected by loss of additives for hydrophilicity, rather than defluorination of PVDF material. Therefore, in order to check membrane degradation degree, an accelerated test by NaOH was carried out, loss of additives was confirmed, and then PVDF inherent characteristic was observed.

• 한국표면공학회지
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• 제49권6호
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• pp.513-520
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• 2016

Many surface protection methods have been developed to apply to constructional steels which have been used under severe corrosive environments. One of these methods, hot dip galvanizing is being widely used to the numerous constructional steels such as a guard rail of high way, various types of structural steel for manufacturing ship and for some other industrial fields etc.. Recently, the cost of zinc is getting higher and higher, thus, it is considered that improvement of hot dip galvanizing process to reduce the cost of production should be developed possibly. In this study, additives such as acid cleaning solution, $NH_4OH$, $Al(OH)_3$ and $H_2O_2$ were added to flux solution, and omission of water washing treatment after acid cleaning was investigated with some types of flux solutions added with some additives mentioned above. The decrement of pH by adding the acid cleaning solution could be controlled due to neutralization reaction with addition of $NH_4OH$. The flux solution added with both $NH_4OH$ and $Al(OH)_3$ exhibited nearly the same color and pH value as those of orignal flux solution with no added, and the sample dipped to the flux solution which was added with additives mentioned above indicated a relatively good corrosion resistance compared to other samples. However, the flux solution added with $NH_4OH$, $Al(OH)_3$ and $H_2O_2$ exhibited a different color, sediment and a bad corrosion resistance. Consequently, it is considered that omission of water washing treatment may be able to perform by adding optimum additives to the original flux solution.

• 상하수도학회지
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• 제31권5호
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• pp.389-395
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• 2017

In this paper, we investigate the characteristics of membrane fouling caused by water temperature in the Membrane bioreactor(MBR) process and try to derive the membrane fouling control by chemical enhanced backwashing(CEB). The extracellular polymeric substances(EPS) concentration was analyzed according to the water temperature in the MBR, and the membrane fouling characteristics were investigated according to the conditions, with sludge & without sludge, through a lab-scale reactor. As shown in the existing literature the fouling resistance rate was increased within sludge with the water temperature was lowered. However, in the lab-scale test using the synthetic wastewater, the fouling resistance increased with the water temperature. This is because that the protein of the EPS was more easily adsorbed on the membrane surface due to the increase of entropy due to the structural rearrangement of the protein inside the protein as the water temperature increases. In order to control membrane fouling, we tried to derive the cleaning characteristics of CEB by using sodium hypochlorite(NaOCl). We selected the condition with the chemicals and the retention time, and the higher the water temperature and the chemical concentration are the higher the efficiencies. It is considered that the increasing temperature accelerated the chemical reaction such as protein peptide binding and hydrolysis, so that the attached proteinaceous structure was dissolved and the frequency of the reaction collision with the protein with the chemical agent becomes higher. These results suggest that the MBRs operation focus on the fouling control of cake layer on membrane surface in low temperatures. On the other hand, the higher the water temperature is the more the operation strategies of fouling control by soluble EPS adsorption are needed.

• 한국지반환경공학회 논문집
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• 제14권2호
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• pp.13-17
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• 2013

배수공의 막힘 현상은 노후화된 터널의 가장 큰 문제점으로 보수 책 공법이 시급한 실정이며 장기적으로 보아 상승된 지하수위는 터널의 구조에 악영향을 미칠 수 있다. 현재까지의 유지 관리 방식은 Water Jet Cleaning과 배수공 내 초고압수를 분사하는 방식 등으로 배수공 내 생성된 스케일을 제거하고 있지만, 이러한 공법은 비용이 비싸고 주기적으로 관리가 필요한 단점이 있다. 본 연구에서는 이러한 문제점을 해결하고 반영구적으로 배수공 내 침전물 생성을 방지하기 위한 기술 중 자화장치를 사용하였다. 자화장치를 상하 내부(CASE I), 상내부 하외부(CASE II), 좌우 내부 배열(CASE III)로 배치하여 무게 분석과 육안 분석을 통하여 각 배열별 스케일 생성 억제 효과를 살펴보았다. 그 결과, 상내부 하외부 배열에서 가장 스케일이 적게 생성된 것을 발견할 수 있었으며 좌우 내부 배열, 상하 내부 배열 순으로 스케일의 생성을 억제하는 데 효과가 있는 것으로 나타났다.

• 자원리싸이클링
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• 제29권6호
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• pp.57-64
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• 2020

본 연구에서는 LCD 터치 패널 유리의 재활용을 위해 기계적 방법과 화학적 용해법을 혼용하여 OCA 및 유기 불순물을 제거하는 실험을 진행하였다. 터치 패널의 기계적 파분쇄를 위해 cut mill과 oscillation mill을 이용하였으며, OCA와 유기 불순물의 제거를 위해 물, 에탄올, 디클로로메탄을 이용하여 터치 패널 파쇄물을 세정하였다. 세정 이후 TGA를 통해 유기 불순물의 제거 효율을 평가한 결과 디클로로메탄 단일 용매를 사용한 경우 세정 효과가 가장 뛰어났으며, 세정 온도가 증가함에 따라 유기 불순물의 제거 효과가 증가함을 확인하였다. 제타 전위 측정을 통해 터치 패널 유리 파쇄물의 용매 내 분산도를 평가한 결과, 세정 효과가 가장 낮은 물의 제타 전위 절대값이 타용매에 비해 낮았으며, 유기물의 제거 효과는 화학적인 용해 특성뿐 아니라 용매 내 물리적인 분산 특성에 의해서도 영향을 받을 수 있음을 확인하였다.

• Environmental Engineering Research
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• 제12권5호
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• pp.203-210
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• 2007

Since the emissions composition from the household products have potentially been associated with health risks for building occupants, the chemical composition emitted from the products should be surveyed. The current study identified the emission composition for 42 liquid household products, using a purge-and-trap method. This evaluation was done by classifying the household products into five product classes (deodorizers, household cleaners, color removers, pesticides, and polishes). Nineteen compounds were chosen on the basis of selection criteria. The quality control program for purge-and-trap and analytical systems included tests of laboratory blank Tenax traps and blank water samples, and the determination of calibration equation, measurement precision, method detection limit (MDL), and recovery. The number of chemicals varied according to the product categories, ranging from 4 for the product category of bleaches to 12 for the product categories of air fresheners and nail color removers. For all product categories, the emission composition and concentrations varied broadly according to product. It is noteworthy that most household products emit limonene: 19 of 25 cleaning products; 5 of 6 deodorizers; 1 of 3 pesticides; 3 of 3 color removers; and 4 of 5 polishes. It was suggested that the use of household products sold in Korea could elevate the formation of secondary toxic pollutants in indoor environments, by the reaction of limonene with ozone, which entered indoor environments or might be generated by indoor sources such as electronic air cleaning devices and copying machines.