• 한국수자원학회논문집
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• 제54권10호
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• pp.835-848
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• 2021

제주도는 지질 및 수문계의 특이성으로 인해 수문기상인자 분석을 통한 수문 분석 및 효율적인 물관리가 필수적이다. 하지만 수문기상인자의 지상관측자료는 주변 환경에 의한 영향이 크게 작용하여 공간적인 대표성을 띄기 힘들며, 이를 극복하기 위해 원격탐사 방법이 사용된다. 본 연구에서는 제주도에서 기존에 다른 지역들에서 적용성이 검증된 바 있는 MOD16 증발산량, Global Land Data Assimilation System (GLDAS) 증발산량, GLDAS 토양수분, Advanced SCATerometer(ASCAT) 토양수분 산출물들의 적용성을 평가하였다. 증발산의 경우 강수량과의 총량 비교 및 플럭스타워 증발산량 관측자료와의 비교를 시행하였고, 토양수분의 경우 6개 토양수분 관측소의 관측자료와 비교하였다. 그 결과 증발산량의 경우 연 강수량의 57%가 증발산량으로 산출되었고, MOD16 증발산량과 GLDAS 증발산량의 상관계수는 0.759로 양호한 값이 산출되었으나, 플럭스타워 증발산량 데이터와 MOD16 증발산량의 상관계수는 0.289, GLDAS 증발산량과의 상관계수는 0.434로 상대적으로 적합성이 낮게 나타났다. 토양수분의 경우 GLDAS 자료의 경우 모든 지점에서 지점자료와 비교하였을 때 RMSE 값은 0.05 미만의 값을 나타냈고, 상관계수의 유의성 검정 결과 통계적으로 유의미한 결과를 얻었다. 하지만 위성자료의 경우 월각지점에서 0.05 이상의 RMSE 값이 나타났고, 세화, 한동 지점에서 상관성이 없다는 상관계수의 유의성 검정 결과를 확인하였다. 이는 제주도에 설치된 증발산량 및 토양수분 센서의 품질관리 및 공간대표성을 띄는 면단위 센서가 충분히 제공되지 않아 위와 같은 결과가 나타나는 것으로 판단된며 더불어 지점 자료의 관리 및 위성, 재분석 자료의 경우 관측 픽셀이 해안과 인접할 시 나타나는 오차로 추정된다. 본 연구를 통해 기존 수문기상인자 지상관측 자료의 개선 필요성을 역셜하고, 이를 통해 제주도에서의 효율적인 물관리 를 위한 기반을 구축하고자 한다.

• International Journal of Advanced Culture Technology
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• 제8권2호
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• pp.283-288
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• 2020

This study investigated the purification process of groundwater contaminated with zinc and arsenic using a permeable reactive barrier with a zero-valent iron/pumice mixture. We determined the removal rates of the contaminants for 30 days. In this study, column reactor filled with the zero-valent iron/pumice reactive mixture was used. Experimental results showed that the mixture exhibited an almost complete removal of the zinc and arsenic ions. Arsenic was removed via co-precipitation and adsorption processes while zinc ions were asorbed in active sites.The purification process of water from the metal ionscontinued for 30 days with constant hydraulic conductivity because of the enhanced porosity of the pumice and interparticle distance between the zero-valent iron and pumice. Contaminants removal rates and the remediation mechanism for each reactive system are described in this paper.

• 한국지하수토양환경학회지:지하수토양환경
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• 제25권2호
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• pp.9-15
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• 2020

This study was conducted to investigate the in situ formation of amorphous Fe oxides as a stabilization technology in As-contaminated soil. After addition of ferric nitrate and the neutralizing agent, most of extractable fractions of As in soil (i.e., SO₄^2- and PO₄^3--extractable As) was converted into As bound to amorphous Fe oxides. In addition, results of solubility bioavailability research consortium (SBRC) test indicated that a significant amount of As in untreated soil changed to a non-bioaccessible form after stabilization. The reason was attributed to the newly formed amorphous Fe oxides in the stabilized soil, which was confirmed by linear combination of fitting (LCF) using X-ray absorption spectroscopy (XAS) analysis. Interestingly, after five months of aging of the stabilized soil, ferrihydrite and schwertmannite newly formed in the soil were transformed to crystalline Fe oxides such as goethite, and further decrease in SBRC extractable fraction of As was observed. The results suggest that co-precipitated As with amorphous Fe oxides can be further immobilized with time, due to the crystallization of amorphous Fe oxides.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.60-60
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• 2015

Nanosheets of graphene and related 2D materials have attracted much attention due to excellent physical, chemical and mechanical properties. Single-layer graphene (SLG) was first synthesized by Blakely et al in 1974 [1]. Following his achievements, we initiated the growth and characterization of graphene and h-BN on metal substrates using surface segregation and precipitation in 1980s [2,3]. There are three important steps for nanosheet growth; surface segregation of dopants, surface reaction for monolayer phase, and subsequent 3-D growth (surface precipitation). Surface phase transition was clearly demonstrated on C-doped Ni(111) by in situ XPS at elevated temperatures [4]. The growth mode was clarified by inelastic background analysis [5]. The surface segregation approach has been applied to C-doped Pt(111) and Pd(111), and controllable growth of SLG has been demonstrated successfully [6]. Recently we proposed a promising method for producing SLG fully covering an entire substrate using Ni films deposited on graphite substrates [7]. A universal method for layer counting has been proposed [8]. In this paper, we will focus on the effect of competitive surface-site occupation between carbon and other surface-active impurities on the graphene growth. It is known that S is a typical impurity of metals and the most surface-active element. The surface sites shall be occupied by S through surface segregation. In the case of Ni(110), it is confirmed by AES and STM that the available surface sites is nearly occupied by S with a centered $2{\times}2$ arrangement. When Ni(110) is doped with C, surface segregation of C may be interfered by surface active elements like S. In this case, nanoscopic characterization has discovered a preferred directional growth of SLG, exhibiting a square-like shape (Fig. 1). Also the detailed characterization methodologies for graphene and h-BN nanosheets, including AFM, STM, KPFM, AES, HIM and XPS shall be discussed.

• 한국농공학회논문집
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• 제64권2호
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• pp.37-45
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• 2022

In-situ pilot experiment was carried out to establish a countermeasure on the soil loss from the hill side uplands that was rehabilitated by soil remediation method nearby abandoned mine sites for 2 years. It was considered that the affect of an inclination of cover surface, a stabilization treatment of cover layer by lime and steel refining slag (SRS) and a vegetation of soil surface as an effect factors in the experiment. It was constructed 4 lysimeters (plots, 22 m long, 4 m width) on the hilly side (37% inclination). One plot was control and two plots was treated by 1% lime and SRS. A remind one plot was modified a inclination to 27% to compare the affect of inclination on the amount of cover soil loss. It was attached a reservior tank and water level gauge in the end of lysimeters to measure the amount of the surface water flow and soil loss. It was also installed the automated sensors that could be collect the precipitation, soil moisture content, tension of cover layer in each plots. It was observed that the event of precipitation were caused the soil loss and it were related the physical and chemical properties of cover soil and inclination of surface layer of plots. During the experiment, it was exceeded the national regulation (50 t/ha/yr) in 37% inclination plots even though it was vegetated on the cover soil surface. However, in 27% inclination plot, it was shown that the amount of soil loss was maintained below the national regulation and, more ever, vegetation could reduce the the amount of soil loss. Therefore it was expected that such results could be applied to the future design of rehabilitation projects on the polluted farmland nearby abandoned mine sites.

• 자원환경지질
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• 제27권3호
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• pp.295-311
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• 1994

A comprehensive in-situ tests are performed to define the hydrogeologic and hydrodispersive characteristics such as hydraulic conductivities, longitudinal dispersivity, and average linear velocities as well as conducting flow-net analysis at the study area. The results show that the study area is very heterogeneous so that hydraulic conductivities range from $6.45{\times}10^{-7}$ to $1.15{\times}10^{-5}m/s$ with average linear velocities of 0.34~0.62m/day. Whole groundwater in upper-most aquifer is discharging into the sea with specific discharge rate of $7.2{\times}10^{-3}$ to $1.3{\times}10^{-2}m/day$. The longitudinal dispersivity of the aquifer is estimated about 4.8m through In-situ injection phase test. The area is highly vulnerable to potential contaminant sources due to it's high value of DRASTIC index ranging from 139 to 155 and also under water table condition with very shallow groundwater level. To delineate contaminant plumes of toxic NaOH and carcinogenic benzene when these substances are assumed to be leaked through existing TSDF at the study area by unexpected accidents or spill, Aquifer Simulation Model (ASM) including Flow and Transport Model is used. Te simulated results reveal that the size of NaOH plume after 5 years continuous leak is about $250{\times}100m$ and benzene after 10 years, $490{\times}100m$. When the groundwater is abstracted about 50 days, which is maximum continuously sustained no-precipitation period during 30 years, with pumping rate of $100m^3/day$, THWELL program shows that the groundwater is adversly affected by sea water intrusion.

• Membrane and Water Treatment
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• 제8권4호
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• pp.311-321
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• 2017

Hydrophilic and high modulus PPTA molecules were incorporated into PVDF matrix via the in situ polymerization of PPD and TPC in PVDF solution. PPTA/PVDF/NWF blend membrane was prepared through the immersion precipitation phase inversion method and nonwoven coating technique. The membrane integrated technology including PPTA/PVDF/NWF blend membrane and reverse osmosis (RO) membrane was employed to treat the polyester/viscose spunlace nonwoven process wastewater. During the consecutive running of six months, the effects of membrane integrated technology on the COD, ammonia nitrogen, suspended substance and pH value of water were studied. The results showed that the removal rate of COD, ammonia nitrogen and suspended substance filtered by PPTA/PVDF blend membrane was kept above 90%. The pH value of the permeate water was about 7.1 and the relative water flux of blend membrane remained above 90%. After the deep treatment of RO membrane, the permeate water quality can meet the water circulation requirement of spunlace process.

• 대한원격탐사학회지
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• 제34권1호
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• pp.1-15
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• 2018

Passive microwave sea surface temperatures (SST) were validated in the Northwest Pacific using a total of 102,294 collocated matchup data between Global Precipitation Measurement (GPM) / GPM Microwave Sensor(GMI) data and oceanic in-situ temperature measurements from March 2014 to December 2016. A root-mean-square (RMS) error and a bias error of the GMI SST measurements were evaluated to $0.93^{\circ}C$ and $0.05^{\circ}C$, respectively. The SST differences between GMI and in-situ measurements were caused by various factors such as wind speed, columnar atmospheric water vapor, land contamination near coastline or islands. The GMI SSTs were found to be higher than the in-situ temperature measurements at low wind speed (<6 m/s) during the daytime. As the wind speed increased at night, SST errors showed positive bias. In addition, other factors, coming from atmospheric water vapor, sensitivity degradation at a low temperature range, and land contamination, also contributed to the errors. One of remarkable characteristics of the errors was their latitudinal dependence with large errors at high latitudes above $30^{\circ}N$. Seasonal characteristics revealed that the errors were most frequently observed in winter with a significant positive deviation. This implies that SST errors tend to be large under conditions of high wind speeds and low SSTs. Understanding of microwave SST errors in this study is anticipated to compensate less temporal capability of Infrared SSTs and to contribute to increase a satellite observation rate with time, especially in SST composite process.

• Corrosion Science and Technology
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• 제7권2호
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• pp.69-76
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• 2008

Common methods for large scale hydrogen production, such as steam reforming and coal gasification, also involve production of carbonaceous gases. It is therefore necessary to handle process gas streams involving various mixtures of hydrocarbons, $H_2$, $H_2O$, CO and $CO_2$ at moderate to high temperatures. These gases pose a variety of corrosion threats to the alloys used in plant construction. Carbon is a particularly aggressive corrodent, leading to carburisation and, at high carbon activities, to metal dusting. The behaviour of commercial heat resisting alloys 602CA and 800, together with that of 304 stainless steel, was studied during thermal cycling in $CO/CO_2$ at $650-750^{\circ}C$, and also in $CO/H_2/H_2O$ at $680^{\circ}C$. Thermal cycling caused repeated scale separation, which accelerated chromium depletion from the alloy subsurface regions. The $CO/H_2/H_2O$ gas, with $a_C=2.9$ and $p(O_2)=5\times10^{-23}$ atm, caused relatively rapid metal dusting, accompanied by some internal carburisation. In contrast, the $CO/CO_2$ gas, with $a_C=7$ and $p(O_2)=10^{-23}-10^{-24}$ atm caused internal precipitation in all three alloys, but no dusting. Inward diffusion of oxygen led to in situ oxidation of internal carbides. The very different reaction morphologies produced by the two gas mixtures are discussed in terms of competing gas-alloy reaction steps.

• 한국유체기계학회 논문집
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• 제3권4호
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• pp.7-14
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• 2000

This paper provides integrity evaluation and root cause analysis for defects observed at volute tongue, or cutwater, of the operating centrifugal pump in power plant. The cause of the cracks are analyzed and reviewed from the viewpoint of the operation and maintenance of the pumps, and the sample obtained from the cracked volute tongue of the pump are examined. At first, in-situ hardness test and microstructure examination were performed to understand the cause of cracking at volute tongue. The evaluation of structural integrity and the possibility of the crack propagation is also evaluated. Cracks were typical intergranular cracking and propagated along with prior austenite grain boundary. At easing volute tongue, the hardness was higher than ASTM requirement and a large amount of intergranular Cr carbide was precipitated. These were due to high C content in material. P content was also higher than ASTM requirement. Therefore, Cr carbide precipitation and P segregation at grain boundary, caused by higher C and P content in material, resulted in intergranular cracking of casing volute tongue. This procedure for integrity evaluation and root cause analysis is used to guide, and support the pump designer and manufacturer's material selection and process design to avoid a costly, unplanned outage of plant.