• 제목/요약/키워드: In-situ precipitation

검색결과 72건 처리시간 0.028초

탄산칼슘 in-situ precipitation 처리된 신문고지의 형태와 물성변화 (Morphological and Physical Properties of ONP Treated by CaCO3 In-situ Precipitation Method)

  • 이영호;정재권;이기승;서영범
    • 펄프종이기술
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    • 제45권6호
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    • pp.44-54
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    • 2013
  • Replacing OMG (old magazine) to ONP (old newspaper) by raising optical property through $CaCO_3$ in-situ precipitation method in white duplex board presents cost reduction and possible drying energy saving. The strength property impairment by the presence of $CaCO_3$ could be supplemented by the fiber furnish treatment or strength polymer addition. In $CaCO_3$ in-situ precipitation of ONP, it was found from morphological study using FlowCAM, an image analyzer, that most of calcium carbonate were formed on the fines, and made the size of the fines larger. For the case of forming calcium carbonate only on the fractionated fines, the size of the fines were the biggest, and there were more clean surface areas available for bonding for the fractionated long fibers when fractionated fibers and fines were regrouped to make paper.

타이타니아 단섬유상의 석출이 결정화유리의 마모특성에 미치는 영향 (Effects of Titania Whisker Precipitation on Wear Property of the Glass-Ceramic)

  • 이경호
    • 한국세라믹학회지
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    • 제33권2호
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    • pp.192-202
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    • 1996
  • In Li0.4Ca0.05AlP0.5Si0.75O4.5 composition glass, glass-ceramic having a near 100% crystallinity after nucleation heat treatment of 74$0^{\circ}C$/2 h and crystallization heat treatment of 90$0^{\circ}C$/2 h and in-situ TiO2 whisker reinforced glass-ceramic after heat treatment of 105$0^{\circ}C$ for 20 h were fabricated with the addition of 4% TiO2 as a nucleating agent. With these materials a ball-on-disc type wear test was conducted in order to examine the effect of TiO2 whisker prepcipitation on ambient and high temperature wear properties of the glass-ceramic. Wear test results indicated that all specimens exhibited micro-fracture wear mechanism in ambient temperature. As temperature increased the wear rates of the materials were increased. However the in-situ TiO2 whisker reinforced glass-ceramic exhibited the lowest wear rate over the test temperature range. This resulted from the improvement of harness and fracture toughness of the material as the glass converted into the glass-ceramic followed by precipitation of TiO2 whiskers throughout the glass-ceramic matrix.

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Microcontact Printing을 이용한 미세패턴 ZnO 박막 제조 (Preparation of in situ Patterned ZnO Thin Films by Microcontact Printing)

  • 임예진;윤기현;오영제
    • 한국세라믹학회지
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    • 제39권7호
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    • pp.649-656
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    • 2002
  • Zn(NO$_3$)$_2$ 수용액과 urea[CO(NH$_2$)$_2$]를 이용한 침전법과 Self-Assembled Monolayers(SAMs)를 이용한 microcontact printing 방법으로 미세 패턴화된 ZnO 박막을 Al/si0$_2$/si 기판 위에 제조하였다. Zn(NO$_3$)$_2$와 urea를 혼합하여 제조한 Zn(OH)$_2$ 박막은 침전온도와 urea 량이 증가할수록 Zn(OH)$_2$의 침전량이 증가하였고 Zn(NO$_3$)$_2$와 urea의 반응 시간이 증가함에 따라, Zn(OH)$_2$ 박막의 두께와 입자 크기가 증가하였다. Zn(NO$_3$)$_2$와 urea의 혼합비를 1 : 8, 용액의 침전 온도를 오일 bath내에서 8$0^{\circ}C$, 반응시간을 1시간으로 하여 Al/SiO$_2$/Si 기판 위에 침전된 Zn(OH)$_2$ 박막을 $600^{\circ}C$에서 1시간 동안 열처리하여, 미세 패턴을 형성하기 위한 균질한 크기의 ZnO 박막을 제조할 수 있었다. Microcontact printing방법으로 소수성과 친수성 SAMs인 Octadecylphosphonic Acid(OPA)와 2-Carboxyethylphosphonic Acid(CPA)를 각각 Al/SiO$_2$/Si 기판 위에 선택적으로 흡착한 후에 친수성 SAM인 CPA위에 Zn(OH)$_2$를 침전시켜 미세 패턴화된 ZnO 박막을 제조할 수 있었다

풍화화강토 사면에서 강우로 인한 모관흡수력 변화에 대한 실험 연구 (In-situ Monitoring of Matric Suctions in a Weathered Granite Soil Slope)

  • 이인모;조우성;김영욱;성상규
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 봄 학술발표회 논문집
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    • pp.509-516
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    • 2002
  • Rainfall-induced landslides in a weathered granite soil slope have mostly relative shallow slip surfaces above the groundwater table The pore-water pressure of soil above the groundwater table is usually negative. This negative pore-water pressure(or matric suction) has been found to make a large contribution to the slope stability. Therefore, the variation of in-situ matric suction profiles with time in a soil slope should be understood. In this study, a field measurement program was carried out from June to August, 2001 to monitor in-situ matric suctions and volumetric water contents in a weathered granite soil slope. The influence of climatic conditions on the variation of in-situ matric suctions could be found to decrease rapidly with depth. It could be found that decrement of matric suction induced by precipitation is affected not only by the amount and duration of rainfalls but also by the initial matric suction just prior to rainstorms. The soil-water characteristic from the field monitoring tends toward the wetting path of SWCC obtained from the laboratory test.

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미생물학적 황산염 환원에 의한 토양 내 비소와 구리의 원위치 침전 (In-situ Precipitation of Arsenic and Copper in Soil by Microbiological Sulfate Reduction)

  • 장해영;전효택;이종운
    • 자원환경지질
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    • 제42권5호
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    • pp.445-455
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    • 2009
  • 미생물학적 황산염 환원은 황산염을 전자수용체로 이용하는 황산염 환원 박테리아에 의해 황산염이 황화이온으로 변환되는 과정이다. 형성된 황화이온은 주변의 용존 금속 이온과 결합하여 용해도가 낮은 금속 황화물로 침전된다. 이 연구에서는 비소와 중금속으로 오염된 송천 금은광산 일대 토양을 대상으로 하여 토착 박테리아에 의한 황산염 환원을 유도함으로써 독성 원소의 원위치 고정화 기술의 효율성을 평가하였다. 왕수 분해 결과, 대상 토양 내 비소, 구리, 납의 함량은 각각 1,311 mg/kg, 146 mg/kg, 294 mg/kg 등으로 나타나 특히 비소의 오염이 심각한 상태였다. 회분식 실험 결과, 미생물학적 황산염 환원에 의하여 pH 증가, 산화환원전위 감소, 황산염 함량 감소, 비소와 구리 함량 감소 등이 관찰되었다. 이 때 가장 높은 중금속 침전 효율을 유도하는 탄소원과 황산염의 농도 범위는 각각 0.2~0.5%, 100~200 mg/L로 나타났다. 미생물학적 또는 화학적으로 황화물 침전을 유도하게 고안된 컬럼 실험 수행 결과, 비소와 구리는 두 컬럼에서 모두 98% 이상 제거되었다. 그러나 산소를 다량 포함한 용액을 주입한 후, 화학적으로 황화물 침전을 유도한 컬럼에서는 즉각적인 비소와 구리의 재용출 현상이 나타났으나, 미생물학적 황산염 환원을 유도한 컬럼에서는 침전물이 30일 이상 장기간 안정성을 보였다. 미생물학적 컬럼 내에 형성된 검은색 침전물을 분석한 결과 FeS와 CuS로 나타났으며 비소는 대부분 철 황화물에 흡착되어 있는 것으로 확인되었다.

Satellite monitoring and prediction for the occurrence of the red tide in the coastal areas in the South Sea of Korea - I. The relationship between the occurrence of red tide and the meteorological factors

  • Yoon, Hong-Joo;Kim, Young-Seup;Kim, Sang-Woo
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2002년도 Proceedings of International Symposium on Remote Sensing
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    • pp.656-656
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    • 2002
  • It is studied on the relationship between the occurrence of red tide(Chlorophyll-a concentration by the in-situ and satellite data) and the meteorological factors (precipitation, air temperature, sunshine and winds) in the coastal areas in the South Sea of Korea. In summer and early-fall which frequently occurred the red tide, the precipitation above 213mm had directly influence on the occurrence of red tide because it carried the nutritive substance which originated from the land into the coastal areas. Then air temperature kept up generally high values as 23~26$^{\circ}C$, and sunshine with 187~198hours and wind velocity with 3.1~7.9m/s showed not directly the relationship on the occurrence of red tide.

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석회석을 원료로 사용한 재생용지의 친환경 In-situ Filler로서의 광학적 특성 연구 (Optical Characteristics of Eco-friendly In-situ Recycled Paper with Limestone as Filler)

  • 이현재;이로운;김춘식;남성영;서영범;안지환
    • 한국세라믹학회지
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    • 제51권2호
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    • pp.132-137
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    • 2014
  • The study was performed with low-grade limestone, which is used to make cement or is disposed of due to its low CaO content. In this study, the optimal condition of limestone with which to manufacture precipitated calcium carbonate (PCC) and limestone in fiber was determined through in-situ reactions. The best firing condition is with slaked lime with rapid cooling after 2 h of firing at $1000^{\circ}C$. In addition, the content of CaO can be increased by sorting the low-grade limestone using a 200 mesh filter, and the optical quality of old newspaper (ONP) was similar when using both low-grade and high-grade limestone. Also, controlling the particle size of PCC is an important factor pertaining to the optical characteristics of paper.

Continuous Preconcentration of Sn2+/Sn4+ by the On-line Sulfide Precipitation-Dissolution

  • Yeon, Pyung-Heum;Yoon, Young-Suk;Oh, Se-Woung;Nam, Sang-Ho;Par, Yong-Nam
    • Bulletin of the Korean Chemical Society
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    • 제25권8호
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    • pp.1156-1160
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    • 2004
  • The technique of an on-line preconcentration by the direct sulfide precipitation has been developed. Sn was homogeneously precipitated by sulfide, which was generated in situ from the hydrolysis of thioaceteamide. Precipitate was collected on a filter in the line and dissolved out instantaneously by KOH to be sent to an ICP. The enrichment factor was 4 with the sampling speed of 15/hr for 1.0 mL of sample. It was increased to more than 40 times when the sampling volume was increased to 10 mL with the sampling speed of 5/hr. $Sn^{2+}/Sn^{4+}$ could be separately determined with the on-line precipitation technique. The method was applied to the analysis of NIST SRM 1566 Oyster sample and yielded good agreement with the certified value.

Temporal Variation of Air Temperature in Ice-Valley at Milyang in Association with Ice Formation

  • Lee, Soon-Hwan;Hwang, Soo-Jin
    • 한국지구과학회지
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    • 제28권5호
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    • pp.598-602
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    • 2007
  • A long-term in situ observation was carried out in the Ice-valley at Milyang in order to explain the factors and processes associated with the summertime ice formation. The variation of temperature inside Ice-valley in relation with ice formation in summer time was found to depend on precipitation rate in spring and cold air sinking in autumn and winter. The rate of temperature rising tends to correspond to sensible heat release depending on the precipitation amount at the freezing location. The reason of the cold air accumulation in a talus in the Ice-valley is the cold air sinking over the surface of talus due to the occurrence of outside clod air mass and the accumulated cold air from autumn to spring flow outside at the bottom of talus. The out-flowing cold air can result in the ice formation in the hot summer.

강우자료의 스케일 효과가 비선형수문반응에 미치는 영향 (Investigating the scaling effect of the nonlinear response to precipitation forcing in a physically based hydrologic model)

  • 오남선;이길하
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2006년도 학술발표회 논문집
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    • pp.149-153
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    • 2006
  • 강우는 물과 에너지 순환에서 가장 중요한 역할을 한다. 이 연구에서는 원격탐사를 이용하여 추출한 강우자료의 불확실성 (uncertainty)이 수치수문모형에서 수문인자 (토양함수, 토양온도, 유출, 증발산, 열전도 등)를 모의할 때 공간 스케일의 영향을 검토해 보았다. 지상강우관측을 이용하여 보정된 WSR-88D (NEXRAD)에 의해 추출한 강우자료와 현장에서 측정된 기상자료를 입력 자료로 사용하여, 오프라인 CLM(Community Land Model) 수문모형을 세 가지의 다른 공간 스케일 $0.25^{\circ},\;0.5^{\circ}\;and\;1.0^{\circ}$에 대하여 수행하였다. 이어서 현장에서 측정된 기상자료는 고정시키고 동시공간에 해당하는 IR (Infrared) 밴드를 기반으로 하는 인공위성 강우자료로 대치시켜 같은 모형을 수행하여 비교 검토하였다. 이 연구에서는 물리적 이론을 기반으로 하는 CLM수문모형의 매개변수는 지표면-대기의 수문반응 (land-atmosphere interaction)을 적절하게 묘사하도록 정의되었다고 가정한다. 모형의 실험결과는 강우입력의 불확실성이 수문반응의 공간분포 결과에 어떻게 영향을 미치는지를 보여준다. 이 연구는 수문모형을 수행할 때 수문반응의 불확실성에 대한 정보를 제공해 주며, 결국은 기후 변화에 따른 수자원의 재분배를 이해하는데 이바지 할 것이다.

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