Browse > Article
http://dx.doi.org/10.5012/bkcs.2004.25.8.1156

Continuous Preconcentration of Sn2+/Sn4+ by the On-line Sulfide Precipitation-Dissolution  

Yeon, Pyung-Heum (Department of Chemistry, Korea National University of Education)
Yoon, Young-Suk (Department of Chemistry, Korea National University of Education)
Oh, Se-Woung (Department of Chemistry, College of Natural Sciences, Mokpo National University)
Nam, Sang-Ho (Department of Chemistry, College of Natural Sciences, Mokpo National University)
Par, Yong-Nam (Department of Chemistry, Korea National University of Education)
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.8, 2004 , pp. 1156-1160 More about this Journal
Abstract
The technique of an on-line preconcentration by the direct sulfide precipitation has been developed. Sn was homogeneously precipitated by sulfide, which was generated in situ from the hydrolysis of thioaceteamide. Precipitate was collected on a filter in the line and dissolved out instantaneously by KOH to be sent to an ICP. The enrichment factor was 4 with the sampling speed of 15/hr for 1.0 mL of sample. It was increased to more than 40 times when the sampling volume was increased to 10 mL with the sampling speed of 5/hr. $Sn^{2+}/Sn^{4+}$ could be separately determined with the on-line precipitation technique. The method was applied to the analysis of NIST SRM 1566 Oyster sample and yielded good agreement with the certified value.
Keywords
Preconcentration; $Sn^{2+}/Sn^{4+}$ speciation; ICP; Sulfide precipitation;
Citations & Related Records

Times Cited By Web Of Science : 0  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
연도 인용수 순위
  • Reference
1 Montero, R.; Gallego, M.; Valcarcel, M. J. Anal. At. Spectrom.1988, 3, 725.   DOI
2 Martinez-Jimenez, P.; Gallego, M.; Valcárcel, M. Anal. Chem.1987, 59, 69.   DOI
3 Ebdon, L.; Fisher, A.; Handley, H.; Jones, P. J. Anal. At. Spectrom.1993, 8, 979.   DOI
4 Im, G.; Pak, Y. N. J. of Korean Chem. Soc. 1999, 43, 644.
5 Valc rcel, M.; Gallego, M. Trends in Anal. Chem. 1989, 8, 34.   DOI   ScienceOn
6 Cho, Y. M.; Yeon, P.; Pak, Y. N. Bull. Korean Chem. Soc. 1998,19, 1009.
7 Cho, Y. M.; Pak, Y. N. Anal. Sci. 1997, 13, 41.
8 Zhuang, Z.; Wang, X.; Yang, P.; Yang, C.; Huang, B. J. Anal. At.Spectrom. 1994, 9, 779.   DOI
9 Hudnik, V.; Gomiscek, S.; Gorene, B. Anal. Chim. Acta 1978, 98,39.   DOI   ScienceOn
10 Pablo Rodriguez-Gonzalez, P.; Encinar, J. R.; Alonso, J. I.; Sanz-Medel, A. Analyst 2003, 128, 447.   DOI   ScienceOn
11 Park, K.; Pak, Y. N. Bull. Korean Chem. Soc. 1995, 16, 422.
12 Yang, L.; Mester, Z.; Sturgeon, R. E. J. Anal. At. Spectrom. 2003,18, 1365.   DOI   ScienceOn
13 Sherman, L. R.; Masters, J.; Peterson, R.; Levine, S. J. Anal.Toxicol. 1986, 10, 6.   DOI   ScienceOn
14 Monperrus, M.; Zuloaga, O.; Krupp, E.; Amouroux, D.; Wahlen,R.; Fairman, B.; Donard, O. J. Anal. At. Spectrom. 2003, 18, 247.   DOI   ScienceOn
15 Welz, B.; Xu, S.; Sperling, M. Appl. Spectrosc. 1991, 45, 1433.   DOI
16 Focus on IMO: Antifouling Systems Moving Towards the NontoxicSolution (April, 1999).
17 González, M. M.; Gallego, M.; Valcarcel, M. Talanta 2001, 55,135.   DOI   ScienceOn
18 Sant'Ana, O. D.; Wagener, A. L. R.; Santelli, R. E.; Cassella, R. J.;Gallego, M.; Valcárcel, M. Talanta 2002, 56, 673.   DOI   ScienceOn