• 제목/요약/키워드: In-Situ 혼합

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Effect of Mixing Process on the Wear Properties of UHMWPE/Kaolin Composite (입자충전 초고분자량 폴리에틸렌의 마모특성 : 입자충전 방법의 효과)

  • Ki, Nam;Lee, Geon-Woong;Yoon, Ho-Gyu;Park, Hong-Jo;Kwak, Soon-Jong;Kim, Jun-Kyung;Park, Min
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.803-811
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    • 2002
  • In this study the wear behavior of ultra high molecular polyethylene (UHMWPE) filled with kaolin particles by different methods was investigated. UHMWPE/kaolin composites were prepared by two different methods: polymerization-filling and powder mixing. Particularly in a powder mixing method. Particle dispersion and wear property according to powder mining method were examined. It was found from wear test that filling of inorganic filler into UHMWPE by polymerization filling was more effective way than by powder mixing method in improving Wear resistance of UHMWPE. It was also confirmed that abrasive wear was dominant wear mechanism and particle dispersion in the composite as well as interface property was an important factor in controlling the wear behavior of the resulting composites.

Reliability Analysis of a Quay Wall Constructed on the Deep-Cement-Mixed Ground (Part II: Internal Stability of the Improved Soil System) (심층혼합처리지반에 설치된 안벽의 신뢰성해석 (Part II: 개량지반의 내부안정))

  • Huh, Jung-won;Park, Ock-Joo;Kim, Young-Sang;Hur, Dong-Soo
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.2
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    • pp.88-94
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    • 2010
  • A reliability analysis method is proposed in this paper to quantitatively evaluate the risk for internal stability of a quay wall constructed on the deep cement mixed ground, differentiating from the companion paper that mainly describes the external stability. Failure modes for toe pressure, shear strength of improved ground and extrusion of unimproved soft soil are investigated and compared in the risk estimation of internal stability using MVFOSM, FORM, and MCS. From the reliability analysis results for internal stability of a quay wall, the variance and distribution type of the compressive strength of Deep Mixed Soil-Cement appear to be very affective to the failure probability. On the other hand, other random variables seem to be relatively very insensitive to the probability of failure. It is therefore very important to rationally and accurately determine the probabilistic properties of the in-site compressive strength of Deep Mixed Soil-Cement.

Compatibilization of PC/SAN Blends via Ultrasound-irradiated Melt Mixing (초음파가 조사되는 용융 혼합에 의한 폴리카보네이트/스티렌-아크릴로니트릴 혼합물의 상용화)

  • 김형수
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.225-231
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    • 2004
  • High intensity ultrasound was irradiated to induce mechano-chemical degradation during melt processing of polycarbonate (PC) and styrene-co-acrylonitrile (SAN) in an intensive mixer. It was found that macroradicals of PC and SAM can be generated during ultrasound assisted melt processing; which, in turn, provides a useful route to achieve in-situ compatibilization for the blends of PC and SAM by their mutual coupling. Effectiveness of compatibilization was assessed by investigating phase morphology and mechanical properties of the blends. It was observed that domain size was reduced and the stability of morphology was well maintained even after annealing treatment of the blends. In audition, the enhancement of mechanical properties such as elongation at break and tensile strength was evident, which added further confirmation on the desirable feature that sonication of melt-blends is able to enhance intermolecular interaction by promoting chemical bonds between dissimilar polymers without use of any compatibilizers.

A Study on the Effect of Turbulent Combustion upon Soot Formation in Premixed Constant-Volume Propane Flames (정적 예혼합 프로판 화염의 매연생성에 미치는 난류연소 영향에 관한 연구)

  • 배명환;안수환
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.7
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    • pp.889-898
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    • 2003
  • The soot yield is studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effect of turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures and high temperatures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. It is found that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.

A Study on Soot Formation of Turbulent Premixed Propane Flames in n Constant-Volume Combustor at High Temperatures and High Pressures (고온ㆍ고압 정적 연소기내 난류 프로판 예혼합 화염의 매연생성에 관한 연구)

  • 배명환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.4
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    • pp.1-9
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    • 2001
  • The soot yield has been studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effects of pressure, temperature and turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. The pressure and temperature during soot formation are changed by varying the initial charge pressure and the volume fraction of inert gas compositions, respectively. It is found that the soot yield increases with dropping temperature and rising pressure at constant equivalence ratio, and that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.

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A Study on the Measurement of Burnet Gas Temperature in Premized Combustion by Modified Two-Color Method (변형 2색법에 의한 예혼합기 연소의 연소가스온도 측정에 관한 연구)

  • 배명환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.8
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    • pp.43-54
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    • 1999
  • The effects of equivalence ratio and pressure on burnt gas temperature in premixed fuel rich propane-oxygen-inert gas combustion are investigated over the wide ranges of equivalence ration from 1.5 to 2.7 and pressure from 0.1 to 7 MPa by using a specially designed disk -type constant-voume combustion chamber, The premixtures are simultaneously ignited by eight spark plugs located on the circumference of combustion chamber with 45 degree interals. The eight converging flames compress the end gases to high pressures. The burnt gas temperature is meausured by the nmodifie dtow-colr pyrometry method. The transmissivity in the chamber center during the final stage of combustion at the hightest pressure is meausred by in situ laser extinction method. It is found that a temperature difference between the burnt gas temperature measured by mofidied and conventrational two-color method is 10 to 20 K, but the accuracy of the modified two-color methdo is higher if the local transmissivity in observed region is uniform , and the combustion at higher pressures results gas density conditions and the burnt gas temperature increases as the volume fraction of argon is increased because the specific heat of argon is lower compared to that of nitrogen with a constant equivalence ratio.

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Continuous Bio-hydrogen Production from Food Waste and Waste Activated Sludge (음식물 쓰레기와 폐활성 슬러지를 이용한 생물학적 수소생산 및 수소생산 미생물 군집분석)

  • Kim, Dong-Kun;Lee, Yun-Jie;Kim, Dong-Im;Kim, Ji-Seong;Yu, Myong-Jin;Pak, Dae-Won;Kim, Mi-Sun;Sang, Byoung-In
    • KSBB Journal
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    • v.20 no.6
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    • pp.438-442
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    • 2005
  • Batch experiments were performed to investigate the effects of volumetric mixing ratio(v/v) of two substrates, food wastes(FW) and waste activated sludge(WAS). In batch experiments, optimum mixing ratio for hydrogen production was found at $10{\sim}20$ v/v % addition of WAS. CSTR(Continuous Stirred tank reactor) was operated to investigate the hydrogen productivity and the microbial community under various HRTs and volumetric mixing ratio(v/v) of two substrates. The maximum yield of specific hydrogen production, 140 mL/g VSS, was found at HRT of 2 day and the volumetric mixing ratio of 20:80(WAS:FW). The spatial distribution of hydrogen producing bacteria was observed in anaerobic fermentative reactor using fluorescent in situ hybridization(FISH) method.

Fermentative Hydrogen Production under Various $SO_4^{2-}$ Concentration using Anaerobic Mixed Microflora (혐기 혼합균주에서 황산염 농도변화에 따른 수소 발효 특성)

  • Hwang, Jae-Hoon;Choi, Jeong-A;Lee, Jong-Hak;Jeong, Tae-Young;Cha, Gi-Cheol;Song, Ho-Cheol;Yong, Bo-Young;Kim, Dong-Jin;Jeon, Byong-Hun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.6
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    • pp.434-441
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    • 2009
  • The effect of varying sulfate concentration on continuous fermentative hydrogen production was studied using enriched mixed microflora in continuously fed reactor. Glucose was used as a model substrate for carbohydrates, and hydraulic retention time (HRT) was maintained at 1, 0.5, 0.25 day, respectively. Sulfate concentration was 0${\sim}$20,000 mg/L and the operating pH was maintained at 5.5. The experimental results indicate that hydrogen production is not affected by high sulfate concentration and shorter HRT of 0.25 day enhance hydrogen production. At HRT 1, 0.5, 0.25 day, the hydrogen production rate and hydrogen yield were 2.6, 4.6, 9.4 L/day, and 2.0, 1.8, 1.6 mol $H_2$/mol glucose, respectively. Residual sulfate content was 96${\sim}$98, 95${\sim}$97, and 94${\sim}$97% at HRT 1, 0.5, 0.25 day which show that no sulfate reduction occurred in the reactor during the experiments. Results of Fluorescence In Situ Hybridization (FISH) may indicate the presence of HPB (hydrogen producing bacteria) under all experimental conditions. However, SRB (sulfate reducing bacteria) were not found.

Thermal Properties and Microencapsulation of a Phosphate Flame Retardant with a Epoxy Resin (에폭시 수지를 이용한 인계 난연제의 마이크로캡슐화 및 열적 특성 연구)

  • Baek Kyung-Hyun;Lee Jun-Young;Hong Sang-Hyun;Kim Jung-Hyun
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.404-411
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    • 2004
  • The microcapsules containing triphenyl phosphate (TPP), a flame retardant, were prepared by phase-inversion emulsification technique using the epoxy resin (Novolac type) with excellent physical properties and network structure. This microencapsulation process was adopted for the protection of TPP evaporation and wetting of polymer composite during the polymer blend processing. The TPP, epoxy resin and mixed surfactants were emulsified to oil in water (O/W) by the phase inversion technology and then conducted on the crosslinking of epoxy resin by in-situ polymerization. The capsule size and size distribution of TPP capsules was controlled by mixed surfactant ratio, concentration and TPP contents, The formation and thermal property of TPP capsules were measured by differential scanning calorimetry and thermogravimetric analysis. The morphology and size of TPP capsules were also investigated by scanning and transmission electron microscopies. As the surfactant concentration increased, the TPP capsules were more spherical and mono-dispersed at the same weight ratio of mixed surfactants (F127: SDBS).

Estimation of Spatial Distribution Using the Gaussian Mixture Model with Multivariate Geoscience Data (다변량 지구과학 데이터와 가우시안 혼합 모델을 이용한 공간 분포 추정)

  • Kim, Ho-Rim;Yu, Soonyoung;Yun, Seong-Taek;Kim, Kyoung-Ho;Lee, Goon-Taek;Lee, Jeong-Ho;Heo, Chul-Ho;Ryu, Dong-Woo
    • Economic and Environmental Geology
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    • v.55 no.4
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    • pp.353-366
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    • 2022
  • Spatial estimation of geoscience data (geo-data) is challenging due to spatial heterogeneity, data scarcity, and high dimensionality. A novel spatial estimation method is needed to consider the characteristics of geo-data. In this study, we proposed the application of Gaussian Mixture Model (GMM) among machine learning algorithms with multivariate data for robust spatial predictions. The performance of the proposed approach was tested through soil chemical concentration data from a former smelting area. The concentrations of As and Pb determined by ex-situ ICP-AES were the primary variables to be interpolated, while the other metal concentrations by ICP-AES and all data determined by in-situ portable X-ray fluorescence (PXRF) were used as auxiliary variables in GMM and ordinary cokriging (OCK). Among the multidimensional auxiliary variables, important variables were selected using a variable selection method based on the random forest. The results of GMM with important multivariate auxiliary data decreased the root mean-squared error (RMSE) down to 0.11 for As and 0.33 for Pb and increased the correlations (r) up to 0.31 for As and 0.46 for Pb compared to those from ordinary kriging and OCK using univariate or bivariate data. The use of GMM improved the performance of spatial interpretation of anthropogenic metals in soil. The multivariate spatial approach can be applied to understand complex and heterogeneous geological and geochemical features.