• Transactions on Electrical and Electronic Materials
• /
• v.8 no.2
• /
• pp.73-78
• /
• 2007

The crystallization temperature in GeTe solid electrolyte films was improved by in situ-nitrogen doping by rf magnetron co-sputtering technique at room temperature. The crystallization temperature of $250\;^{\circ}C$ in electrolyte films without nitrogen doping increased by approximately $300\;^{\circ}C$, $350\;^{\circ}C$, and above $400\;^{\circ}C$ in films deposited with nitrogen/argon flow ratios of 10, 20, and 30 %, respectively. A PMC memory device with $Ge_{45}Te_{55}$ solid electrolytes deposited with nitrogen/argon flow ratios of 20 % shows reproducible memory switching characteristics based on resistive switching at threshold voltage of 1.2 V with high $R_{off}/R_{on}$ ratios. Nitrogen doping into the silver saturated GeTe electrolyte films improves the crystallization temperature of electrolyte films and does not appear to have a negative impact on the switching characteristics of PMC memory devices.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.18 no.6
• /
• pp.536-544
• /
• 2012

It is necessary to study the material circulation of coastal ecosystem according to aquacultural activity in order to induce the sustainable production of aquaculture and the fishery environment for the useful use. Hence, it is essential to make an exact assessment for the sedimentation release flux at the sediment-water interface in the aquafarm. Sediment oxygen demand and dissolved inorganic nitrogen release fluxes were compared using in-situ and laboratory incubational examination. Sediment oxygen demands were 116, 34, and $31\;mmol\;O_2\;m^{-2}\;d^{-1}$ (in-situ incubation), 52, 17, and $15\;mmol\;O_2\;m^{-2}\;d^{-1}$ (Core incubation) and dissolved inorganic nitrogen release fluxes were 7.18, 7.98, and $1.78\;mmol\;m^{-2}\;d^{-1}$ (in-situ incubation), 3.33, 3.74, and $1.96\;mmol\;m^{-2}\;d^{-1}$ (Core incubation) at Tongyeong finfish, Yeosu finfish, and Wando abalone cage farms, respectively. Consequently, in-situ incubation results showed two times higher than laboratory examination. We compared the material flux at the sediment-water interface of each farm and the characteristics between two different kinds of material flux examination.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2009.06a
• /
• pp.199-200
• /
• 2009

This paper describes the electrical properties of polycrystalline (poly) 3C-SiC thin films with different nitrogen doping concentrations. The in-situ-doped poly 3C-SiC thin films were deposited by using atmospheric-pressure chemical vapor deposition (APCVD) at $1200^{\circ}C$ with hexamethyldisilane (HMDS: $Si_2$ $(CH_3)_6)$ as a single precursor and 0 ~ 100 sccm of $N_2$ as the dopant source gas. The peaks of the SiC (111) and the Si-C bonding were observed for the poly 3C-SiC thin films grown on $SiO_2/Si$ substrates by using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) analyses, respectively. The resistivity of the poly 3C-SiC thin films decreased from $8.35\;{\Omega}{\cdot}cm$ for $N_2$ of 0 sccm to $0.014\;{\Omega}{\cdot}cm$ with $N_2$ of 100 sccm. The carrier concentration of the poly 3C-SiC films increased with doping from $3.0819\;{\times}\;10^{17}$ to $2.2994\;{\times}\;10^{19}\;cm^{-3}$, and their electronic mobilities increased from 2.433 to $29.299\;cm^2/V{\cdot}S$.

• Asian-Australasian Journal of Animal Sciences
• /
• v.15 no.6
• /
• pp.793-799
• /
• 2002

Four feeds, three concentrates (rice bran, soybean meal and flaked corn) and one forage (corn silage) were incubated in four ruminally fistulated Holstein steers over three one week periods in a 3${\times}$4 incomplete latin square design where steers served as blocks and feeds as treatment. The objectives of the study were to investigate in situ DM, N and P degradability characteristics of feeds in order to assess availability of these nutrients by ruminants. In each period, all feeds were incubated in quadruplets (corn silage in triplicates) in the rumen of each steer in a reverse order for 3, 6, 9, 12, 18, 24 and 48 h. The DM 'a' fraction was higher and lower (p<0.001) in corn silage and rice bran respectively. Although corn silage contained the lowest (p<0.01) DM 'b' fraction, flaked corn contained the highest. Rate of DM degradation of flaked corn and corn silage were half (p<0.05) of the rate of DM degradation of either rice bran or soybean meal. Potential or effective DM degradability (p<0.05 to 0.001) at various passage rates were the lowest for rice bran and the highest for soybean meal. Corn silage N 'a' and 'b' was the highest and lowest, respectively (p<0.01). N 'c' of corn silage and rice bran was higher (p<0.001) than other feeds. Potential N degradability was the lowest in flaked corn (p<0.05). P 'a' was high (p<0.01) for corn silage and rice bran. P 'b' fraction was very high (p<0.001) in soybean meal but was absent in corn silage. Availability of DM (p<0.01 or 0.001), N (p<0.001) and P (p<0.05) differed between feeds at various passage rates except P availability at k=0.02 per h (p>0.05). The results demonstrate that the availability of DM, N and P by ruminants depends on feed as well as categories of animal.

• Korean Journal of Remote Sensing
• /
• v.40 no.1
• /
• pp.1-8
• /
• 2024

Busan is the 6th largest port city in the world, where nitrogen dioxide (NO₂) emissions from transportation and port industries are significant. This study aims to assess the NO₂ products of the Geostationary Environment Monitoring Spectrometer (GEMS) over Busan using ground-based instruments (i.e., surface in-situ network and Pandora). The GEMS vertical column densities of NO₂ showed reasonable consistency in the spatiotemporal variations, comparable to the previous studies. The GEMS data showed a consistent seasonal trend of NO₂ with the Korea Ministry of Environment network and Pandora in 2022, which is higher in winter and lower in summer. These agreements prove the capability of the GEMS data to monitor the air quality in Busan. The correlation coefficient and the mean bias error between the GEMS and Pandora NO₂ over Busan in 2022 were 0.53 and 0.023 DU, respectively. The GEMS NO₂ data were also positively correlated with the ground-based in-situ network with a correlation coefficient of 0.42. However, due to the significant spatiotemporal variabilities of the NO₂, the GEMS footprint size can hardly resolve small-scale variabilities such as the emissions from the road and point sources. In addition, relative biases of the GEMS NO₂ retrievals to the Pandora data showed seasonal variabilities, which is attributable to the air mass factor estimation of the GEMS. Further studies with more measurement locations for longer periods of data can better contribute to assessing the GEMS NO₂ data. Reliable GEMS data can further help us understand the Asian air quality with the diurnal variabilities.

• Journal of Microbiology and Biotechnology
• /
• v.17 no.2
• /
• pp.305-312
• /
• 2007

This study focused on the involvement of the unusual nucleotide (p)ppGpp, a stringent factor, during the morphological and physiological differentiation of Streptomyces coelicolor. Two genes, relA and rshA, were disrupted to demonstrate the roles of the stringent factor in the differentiation. The intracellular concentration of (p)ppGpp in the wild-type (M600) and disrupted mutants was measured in relation to the intentional starvation of a specific nutrient, such as carbon, nitrogen, and phosphate or the in situ depletion of nutrients in a batch culture. As a result, it was found that the morphological characteristic of the ${\Delta}relA$ mutant was a bld phenotype forming condensed mycelia, whereas the ${\Delta}rshA$ mutant grew fast-forming spores and straightforward mycelia. In both mutants, the production of actinorhodin (Act) was completely abolished, yet the undecylprodigiosin (Red) production was increased. Intracellular (p)ppGpp was detected in the ${\Delta}relA$ mutant in the case of limited phosphate, yet not with limited carbon or nitrogen sources. In contrast, (p)ppGpp was produced in the ${\Delta}rshA$ mutant under limited carbon and nitrogen conditions. Therefore, (p)ppGpp in S. coelicolor was found to be selectively regulated by either the RelA or RshA protein, which was differentially expressed in response to the specific nutrient limitation. These results were also supported by the in situ ppGpp production during a batch culture. Furthermore, it is suggested that RelA and RshA are bifunctional proteins that possess the ability to both synthesize and hydrolyze (p)ppGpp.

• Journal of Microbiology and Biotechnology
• /
• v.12 no.6
• /
• pp.929-935
• /
• 2002

The 5-stage biological nutrient removal (BNR) process with step feed system showed a very stable organic carbon and nutrient removal efficiency ($87\%\;COD\,;79\%\;nitrogen,\;and\;87\%$ phosphorus) for an operation period of 2 years. In each stage at the pilot plant, microbial communities, which are important in removing nitrogen and phosphorus, were investigated using fluorescence in-situ hybridization (FISH) and 165 rDNA characterization. All tanks of 5-stage sludge had a similar composition of bacterial communities. The totat cell numbers of each reactor were found to be around $2.36-2.83{\times}10^9$ cells/ml. About $56.5-62.0\%$ of total 4,6-diamidino-2-phenylindol (DAPI) cells were hybridized to the bacterial-specific probe EUB388. Members of ${\beta}$-proteobacteria were the most abundant proteobacterial group, accounting for up to $20.6-26.7\%$. The high G+C Gram-positive bacterial group and Cytophaga-Flexibacter cluster counts were also found to be relatively high. The beta subclass proteobacteria did not accumulate a large amount of polyphosphate. The proportion of phosphorus-accumulating organisms (PAOs) in the total population of the sludge was almost $50\%$ in anoxic-1 tank. The high G+C Gram-positive bacteria and Cytophaga-Flexibacter cluster indicate a key role of denitrifying phosphorus-accumulating organisms (dPAOs). Both groups might be correlated with some other subclass of proteobacteria for enhancing nitrogen and phosphorus removal in this process.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.15 no.7
• /
• pp.576-582
• /
• 2002

Nonvolatile semiconductor memory devices with reoxidized nitrided oxide(RONO) gate dielectrics were fabricated, and nitrogen distribution and bonding species which contribute to memory characteristics were analyzed. Also, memory characteristics of devices depending on the anneal temperatures were investigated. The devices were fabricated by retrograde twin well CMOS processes with $0.35\mu m$ design rule. The processes could be simple by in-situ process in growing dielectric. The nitrogen distribution and bonding states of gate dielectrics were investigated by Dynamic Secondary Ion Mass Spectrometry(D-SIMS), Time-of-Flight Secondary Ion Mass Spectrometry(ToF-SIMS), and X-ray Photoelectron Spectroscopy(XPS). As the nitridation temperature increased, nitrogen concentration increased linearly, and more time was required to form the same reoxidized layer thickness. ToF-SIMS results showed that SiON species were detected at the initial oxide interface which had formed after NO annealing and $Si_2NO$ species within the reoxidized layer formed after reoxidation. As the anneal temperatures increased, the device showed worse retention and degradation properties. It could be said that nitrogen concentration near initial interface is limited to a certain quantity, so the excess nitrogen is redistributed within reoxidized layer and contribute to electron trap generation.

• Journal of Korean Society on Water Environment
• /
• v.21 no.5
• /
• pp.477-483
• /
• 2005

Anammox (Anaerobic Ammonium Oxidation) bacteria is recently discovered microorganism which can oxidize ammonium to nitrogen gas in the presence of nitrite under anaerobic conditions. The anammox process can save an energy for nitrification and need not require a carbon source for denitrification, however, the start-up periods takes a long time more than several months due to the long doubling time (approximately 11 days). In order to find the effects of seeding microorganisms, hydrazine, and nitrite concentration on the enhancement of the anammox activity, five kinds of microorganisms were selected. Among the several kinds of seeding microorganisms, the granule from acclimated microorganisms treating high concentration of ammonia nitrogen (A-1) and sludge from piggery wastewater treatment plant (A-2) were found to have a high anammox activity. In the case of A-1, the maximum nitrogen conversion rate represented 0.4 mg N/L-hr, and the amount of nitrite utilization was high compared to those of other seeding microorganisms. The A-4 represented a higher nitrogen conversion rate to 0.7 mg N/L-hr although the ammonium concentration in the serum bottle was high as 200 mg/L. Meanwhile, the anaerobic granule from UASB reactor treating distillery wastewater showed a low anammox activity due to the denitrification by the remained carbon sources in the granule. Hydrazine, intermediate product in anammox reaction, enhanced the anammox activity by representing 1.4 times of nitrogen gas was produced in the test bottle than that of control, when 0.4 mM of $N_2H_4$ was added to serum bottle which contains 5 mM of nitrite. The high concentration of nitrite (10 mM) resulted in the decrease of the anammox activity by showing lower production of nitrogen gas compared to that of 5 mM addition of nitrite concentration. As a result of FISH (Florescence In-Situ Hybridization) experiment, the Amx820 probe showed a more than 13% of anammox bacteria in a granule (A-1).

• The Korean Journal of Ecology
• /
• v.18 no.2
• /
• pp.219-230
• /
• 1995

Although many studies of nutrient cycling in forest ecosystems have reported that clearcutting creates increased organic matter decomposition and nitrogen (N) mineralization in soils, little is known about the change of these factors following various levels of canopy removal. A series of experimental plots with four levels of canopy cover, i.e., clearcut, 25％, 75％, and uncut, was established in northern red oak (Quercus rubra L.) stands in northern Lover Michigan, U.S.A. I examined decomposition of cellulose filter papers and N mineralization using an in situ soil incubation technique in the top 15cm of mineral soil during the second growing season (1992, May-October) following stand manipulation. Mass loss from cellulose filter papers was more rapid in the canopy removal treatments than in the uncut treatment. similarly, net N mineralization was significantly greater in the canopy removal treatments than in the uncut treatment. There was no significant difference in net N mineralization rates among the three levels of canopy removal. Net N mineralization for the growing season was 58 kg/ha for the clearcut, 54 kg/ha for the 25％ canopy cover, 51 kg/ha for the 75％ canopy cover, and 22 kg/ha for the uncut treatment. These results indicated that even only small amounts of canopy removal (leaving 75％ canopy cover) let to substantial increases of cellulose decomposition and the amount of available soil nitrogen.