• Advances in materials Research
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• v.2 no.4
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• pp.209-219
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• 2013

We have described primary studies on conductivity and molecular weight of polyaniline separately in the electric and magnetic fields when it is used in a field effect experimental configuration. We report further studies on doped in-situ deposited polyaniline. First we have chemically synthesized polyaniline by ammonium peroxodisulfate in acidic aques and organic solutions at different times. Then we measured mass and conductivity and obtained the best time of polymerizations. In continue, we repeated these reactions separately under different electric and magnetic fields in constant time and measured mass and conductivity. The polyaniline is characterized by gel permeation chromatography (GPC), UV-Visible spectroscopy and electrical conductivity. High molecular weight polyanilines are synthesized under electric field, $M_w$ = 520000-680000 g/mol, with $M_w/M_n$ = 2-2.5. The UV-Visible spectra of polyanilines oxidized by ammonium peroxodisulfate and protonated with dodecylbenzenesulfonic acid (PANi-DBSA), in N-methylpyrolidone (NMP), show a smeared polaron peak shifted into the visible. Electrical conductivity of polyanilines has been studied by four-probe method. The conductivity of the films of emeraldine protonated by DBSA cast from NMP are higher than 500 and 25 S/cm under 10 KV/m of potential) electric field and 0.1 T magnetic field, respectively. It shows an enhanced resistance to ageing too. By the next steps, we carried chemical polymerization at the best electric and magnetic fields at different times. Finally, resulted in finding the best time and amount of the fields. The longer polymerization time and the higher magnetic field can lead to degradation of polyaniline films and decrease conductivity and molecular mass.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.17-20
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• 2001

Nonvolatile semiconductor memory devices with reoxidized nitrided oxide(RONO) gate dielectric were fabricated, and nitrogen distribution and bonding species which contributing memory characteristics were analyzed. Also, memory characteristics of devices according to anneal temperatures were investigated. The devices were fabricated by 0.35$\mu\textrm{m}$ retrograde twin well CMOS processes. The processes could be simple by in-situ process of nitridation anneal and reoxidation. The nitrogen distribution and bonding state of gate dielectric were investigated by Dynamic Secondary Ion Mass Spectrometry(D-SIMS), Time-of-Flight Secondary ton Mass Spectrometry(ToF-SIMS), and X-ray Photoelectron Spectroscopy(XPS). Nitrogen concentrations are proportional to nitridation anneal temperatures and the more time was required to form the same reoxidized layer thickness. ToF-SIMS results show that SiON species are detected at the initial oxide interface and Si$_2$NO species near the new Si-SiO$_2$ interface that formed after reoxidation. As the anneal temperatures increased, the device showed worse retention and degradation properties. These could be said that nitrogen concentration near initial interface is limited to a certain quantity, so excess nitrogen are redistributed near the Si-SiO$_2$ interface and contributed to electron trap generation.

• Journal of Industrial Technology
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• v.24 no.B
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• pp.3-17
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• 2004

Overbreak, underbreak and range of disturbed rock zone (DRZ) are the most important factors in evaluating the results of tunnel blasting. These factors, which depend on the discontinuities in rock mass, the blasting patterns and drilling conditions, have been studied. The range of DRZ can be estimated by relationships between vibration velocity and associated tensile stress. A new computerized rocket jumbo drill has been adopted to reduce overbreak based on the analysis of drilling accuracy. In-situ blasting tests were also performed by varying initiating systems. Overbreak can be reduce from 34.5cm to 20cm. The range of DRZ is 0.2m with stoping holes and 0.4m with wall holes respectively. In addition, some methods to reduce DRZ have been presented in this study.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.03a
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• pp.494-505
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• 2006

In this study, using constant normal stiffness(CNS) direct shear tests, side shear load distribution were analyzed by the influencing parameters of unconfined compressive strength, surface roughness, confining stress, and material properties. Based on the CNS tests, side shear load transfer function of drilled shafts in rock is proposed using geological strength index(GSI), which indicates discontinuity and surface condition of rock mass in Hoek-Brown criterion. Though comparisons with results of nine drilled shafts's load tests, it is found that the load-transfer curve by this study is in good agreement with the general trend observed by in situ measurements, and thus represents a significant improvement in the prediction of bearing capacity of drilled shaft.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.09c
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• pp.140-145
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• 2010

Consolidation in cohesive soils mainly focuses on compressibility of soils, but it affects solute transport in some cases. The consolidation process takes on particular significance for fine grained soils at high water content, such as dredged sediments, but has also been shown to be important for compacted clay liners during waste filling operation. Numerical investigation using CST1 and CST2 was reviewed on consolidation-induced solute transport in this paper, especially with the development of CST2 model, verification by comparing experimental results with numerical simulations, and cases studies regarding transport in a confined disposal facility (CDF) and during in-situ capping. The importance of the consolidation process on solute transport is accessed based on simulated concentration or mass breakthrough curves. Results indicate that neglecting transient consolidation effects may lead to significant errors in transport analyses, especially with soft contaminated cohesive soils undergoing large volume change.

• Korean Journal of Radiology
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• v.25 no.2
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• pp.134-145
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• 2024

Abnormalities on breast ultrasound (US) images which do not meet the criteria for masses are referred to as nonmass lesions. These features and outcomes have been investigated in several studies conducted by Asian researchers. However, the term "nonmass" is not included in the American College of Radiology (ACR) Breast Imaging Reporting and Data System (BI-RADS) 5th edition for US. According to the Japan Association of Breast and Thyroid Sonology guidelines, breast lesions are divided into mass and nonmass. US findings of nonmass abnormalities are classified into five subtypes: abnormalities of the ducts, hypoechoic areas in the mammary glands, architectural distortion, multiple small cysts, and echogenic foci without a hypoechoic area. These findings can be benign or malignant; however, focal or segmental distributions and presence of calcifications suggest malignancy. Intraductal, invasive ductal, and lobular carcinomas can present as nonmass abnormalities. For the nonmass concept to be included in the next BI-RADS and be widely accepted in clinical practice, standardized terminologies, an interpretation algorithm, and outcome-based evidence are required for both screening and diagnostic US.

• Biotechnology and Bioprocess Engineering:BBE
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• v.7 no.6
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• pp.331-334
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• 2002

Culture conductivity and on-line NADH fluorescence were used to measure cellular growth in plant cell suspension cultures of Podophyllum hexandrum. An inverse correlation between dry cell weight and medium conductivity was observed during shake flask cultivation. A linear relationship between dry cell weight and culture NADH fluorescence was obtained during the exponential phase of batch cultivation In a bioreactor under the pH stat (pH 6) conditions. It was observed that conductivity measurement were suitable for biomass characterisation under highly dynamic uncontrolled shake flask cultivation conditions. However, if the acid/alkali feeding is done for pH control the conductivity measurement could not be applied. On the other hand the NADH fluorescence measurement allowed online-in situ biomass monitoring of rather heterogenous plant cell suspension cultures in bioreactor even under the most desirable pH stat conditions.

• Tunnel and Underground Space
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• v.6 no.1
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• pp.10-18
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• 1996

Arched openings are generally excavated in underground construction works. Since stress distribution around openings depends on geological structure in rock mass, any shape of arched openings fully conformed with in-situ stress condition should be recommended to maintain mechanical safety of structures. Shape of arched openings is specified by both roof curvature and height-width ratio, and especially this report presents deformation behaviors related with roof curvature. Scale model tests and numerical studies of various shaped openings are conducted, where rectangular opening shows the greatest convergence. Through the anlayses of various arched opengings, as radius of roof curvature is increased, roof lowering and sidewall closure are remarkably increased, whereas floor heaving is increased little by little. By the way, it is useful that displacements of openings are roughly estimated in the stage of preliminary investigation. To find out elastic displacements of arched openings with any roof curvature, regressional formula and charts by least square method are represented. In addition elastoplastic deformation behavoirs of arched openings concerning associated adn non-associated flow rule are discussed.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.57-64
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• 2005

Since the allowable bearing capacities of piles in weathered/fractured rock are mainly governed by settlement, the load-displacement behavior of the rock socketed pile should be well known. To predict pile head settlement at the design stage, the exact understanding of the load-transfer mechanisms is essential. Therefore, in this research, the load-transfer mechanisms of drilled shaft socketed into weathered rock was investigated. For that, 5 cast-in-place concrete piles with diameters of 1,000 mm were socketed into weathered gneiss. The static axial load tests and the load-transfer measurements were performed to examine the axial resistant behavior of the piles. A comprehensive field/laboratory testing program on weathered rock at the field test sites was also performed to describe the in situ rock mass conditions quantitatively. And then, the effect of rock mass condition on the load transfer mechanism was investigated. The side shear resistance of the pile in moderately weathered rock reached to yielding point at a few millimeter displacements, and after that, the rate of resistance increment dramatically decreased. However, that in the highly /completely weathered rock did not show the obvious yielding point, and gradually increased showing the hyperbolic pattern until with the relatively high displacement (>10 mm). The end bearing-displacement curves showed linear increase at least until with the base displacement of approximately 10 mm, regardless rock mass conditions.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.4C
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• pp.205-212
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• 2008

In this research, the effect of rock mass weathering on the side shear resistance of drilled shaft socketed into igneous-metamorphic rock was investigated. For that, 23 cast-in-place concrete piles with diameters varying from 400mm to 1,500mm were constructed at four different sites, and the static axial load tests were performed to examine the resistant behavior of the piles. A comprehensive field/laboratory testing program at the field test site was also performed to describe the in situ rock mass conditions quantitatively. The side shear resistance of rock socketed piles was found to have no intimate correlation with the compressive strength of the intact rock. However, the global rock mass strength, which was calculated by the Hoek and Brown criteria, was found to closely correlate to the side shear resistance. The ground investigation data regarding the rock mass conditions (e.g. $E_m$, $E_{ur}$, $p_{lm}$, RMR, RQD, j) were also found to be highly correlated with the side shear resistance, showing the coefficients of correlation greater than 0.75 in most cases. Additionally, the applicability of existing methods for the side shear resistance of weathered granite-gneiss was verified by comparison with the field test data. The existing methods which consider the effect of rock mass condition were modified and/or extended for weathered rock mass where mass factor j is lower than 0.15, and RQD is below 50%.