• Title/Summary/Keyword: Improvement of Surface Layer

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Surface Characterization and Morphology in Ar-Plasma-Treated Polypropylene Blend

  • Weon, Jong-Il;Choi, Kil-Yeong
    • Macromolecular Research
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    • v.17 no.11
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    • pp.886-893
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    • 2009
  • Surface modifications using a radio frequency Ar-plasma treatment were performed on a polypropylene (PP) blend used for automotive bumper fascia. The surface characterization and morphology were examined. With increasing aging time, there was an increase in wettability, oxygen containing polar functional groups (i.e., C-O, C=O and O-C=O) due to oxidation, the amount of tale, and bearing depth and roughness on the PP surface, while there was a decrease in the number of hydrocarbon groups (i.e., C-C and C-H). AFM indicated that the Ar-plasma-treatment on a PP blend surface transforms the wholly annular surface into a locally dimpled surface, leading to an improvement in wettability. SEM showed that the PP layer observed in the non-plasma-treated sample was removed after the Ar-plasma treatment and the rubber particles were exposed to the surface. The observed surface characterization and morphologies are responsible for the improved wettability and interfacial adhesion between the PP blend substrate and bumper coating layers.

Cathode Microstructure Control and Performance Improvement for Low Temperature Solid Oxide Fuel Cells (저온 고체산화물 연료전지용 공기극 미세구조 제어 및 성능개선)

  • Kang, Jung-Koo;Kim, Jin-Soo;Yoon, Sung-Pil
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.727-732
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    • 2007
  • In order to fabricate a highly performing cathode for low-temperature type solid oxide fuel cells working at below $700^{\circ}C$, electrode microstructure control and electrode polarization measurement were performed with an electronic conductor, $La_{0.8}Sr_{0.2}MnO_3$ (LSM) and a mixed conductor, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$(LSCF). For both cathode materials, when $Sm_{0.2}Ce_{0.8}O_2$ (SDC) buffer layer was formed between the cathode and yttria-stabilized zirconia (YSZ) electrolyte, interfacial reaction products were effectively prevented at the high temperature of cathode sintering and the electrode polarization was also reduced. Moreover, cathode polarization was greatly reduced by applying the SDC sol-gel coating on the cathode pore surface, which can increase triple phase boundary from the electrolyte interface to the electrode surface. For the LSCF cathode with the SDC buffer layer and modified by the SDC sol-gel coating on the cathode pore surface, the cathode resistance was as low as 0.11 ${\Omega}{\cdot}cm^2$ measured at $700^{\circ}C$ in air atmosphere.

Potential of Argo Drifters for Estimating Biological Production within the Water Column

  • Son, Seung-Hyun;Boss, Emmanuel;Noh, Jae-Hoon
    • Ocean Science Journal
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    • v.41 no.2
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    • pp.121-124
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    • 2006
  • Argo drifters provide information of the vertical structure in the water column and have a potential for the improvement of understanding phytoplankton primary production and biogeochemical cycles in combination with ocean color satellite data, which can obtain the horizontal distribution of phytoplankton biomass in the surface layer. Our examples show that using Argo drifters with satellite-measured horizontal distribution of phytoplankton biomass at the sea surface allow an improved understanding of the development of the spring bloom. The other possible uses of Argo drifter are discussed.

Heat dissipation of Al2O3 Insulation layer Prepared by Anodizing Process for Metal PCB (Metal PCB에 있어서 양극산화법으로 제작한 Al2O3절연막의 방열특성)

  • Jo, Jae-Seung;Kim, Jeong-Ho;Ko, Sang-Won;Lim, Sil-Mook
    • Journal of the Korean institute of surface engineering
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    • v.48 no.2
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    • pp.33-37
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    • 2015
  • High efficiency LED device is being concerned due to its high heat loss, and such heat loss will cause a shorter lifespan and lower efficiency. Since there is a demand for the materials that can release heat quickly into the external air, the organic insulating layer was required to be replaced with high thermal conductive materials such as metal or ceramics. Through anodizing the upper layer of Al, the Breakdown Voltage of 3kV was obtained by using an uniform thickness of $60{\mu}M$ aluminum oxide($Al_2O_3$) and was carried out to determine the optimum process conditions when thermal cracking does not occur. Two Ni layers were formed above the layer of $Al_2O_3$ by sputtering deposition and electroplating process, and saccharin was added for the purpose of minimizing the remain stress in electroplating process. The results presented that the 3-layer film including the Ni layer has an adhesive force of 10N and the thermal conductivity for heat dissipation is achieved by 150W/mK level, and leads to improvement about 7 times or above in thermal conductivity, as opposed to the organic insulation layer.

Density and Corrosion Property Improvement of Zn-Mg Coatings by Controlling the Substrate Temperature during the Deposition (증착 기판 온도 제어에 따른 Zn-Mg 박막의 치밀도 및 내식성 향상에 관한 연구)

  • Song, Myeon-Kyu;La, Joung-Hyun;Kim, Hoe-Kun;Lee, Sang-Yul
    • Journal of the Korean institute of surface engineering
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    • v.50 no.4
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    • pp.266-271
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    • 2017
  • In this study, the corrosion resistance of Zn-3wt.%Mg coating was enhanced by controlling the density of coating. During the deposition the substrate temperature was controlled via an intermittent deposition process, resulting in the improvement of coating density. The maximum substrate temperature during this intermittent deposition process could be controlled from $200^{\circ}C$ to $80^{\circ}C$, depending upon the number of coating layer. The density of Zn-3 wt.%Mg coating increased from 76.1 % to 95.8 % as the substrate temperature was controlled. The salt spray test results revealed that the corrosion resistance of Zn-Mg coated steel could increase 3 times by increasing the density in coatings, while adhesion strength of coating was not changed significantly during 0-T bending test.

Improvement of Surface Hardness of 2205 Duplex Stainless Steel by Laser Shock Peening and Observations of Surface Changes (레이저 쇼크 피닝에 의한 2205 듀플렉스 스테인리스강의 표면 경도 향상과 표면 변화 관찰)

  • Lim, H.T.;Jeong, H.M.;Kim, P.K.;Jeong, Sung-Ho
    • Laser Solutions
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    • v.14 no.1
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    • pp.19-24
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    • 2011
  • This work reports the results for laser shock peening of duplex stainless steel (22% Chromium - 5% Nickel) using a pulsed Nd:YAG laser (wavelength = 532nm, pulse width = 8ns). for the application to high-capacity pumps for seawater desalination plants. By properly selecting the process parameters such as laser intensity of 10GW/$cm^2$, laser pulse density of 75pulse/$mm^2$, and $100{\mu}m$ thick aluminum foil as an absorbent coating layer, the surface hardness of duplex stainless steel could be enhanced by 26%, from 256HV to 323HV with little changes in surface morphology and roughness. The depth of laser shock peened layer was measured to be around 2mm. The large enhancement of surface hardness is considered to have high practical importance in minimizing abrasive and corrosive deterioration of pump parts.

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A study on the plastic polishing process of cylindrical rods (봉재의 표면소성 연마가공에 관한 연구)

  • 최재찬;김병민
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.3
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    • pp.488-500
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    • 1987
  • The improvement of surface roughness of machined cylindrical rods through the plastic polishing process was studied in this paper. The criterion and limits for the plastic polishing process due to the wave motion of the ridge were established with respect to process variables: ridge shape and size, semi-cone die angle as well as friction factor, by the application of the upper-bound approach. The surface roughness of the plastic polished products was measured, and compared with that of the original specimen. Also the depth of the surface deformation layer was tested, and compared those of the theoretical values. Qualitative agreement exists between the experimental plastic polishing loads and theoretical loads. The wave motion of the ridge was mostly occurred within the established limits. The surface roughness of specimens was sufficiently improved through the present process. Also the predicted depth of the surface deformation layer was in good agreement with experimental results.

Adhesion and Electrical Performance by Roughness on Semiconductive-Insulation Interface Layer of Silicone Rubber (거칠기에 따른 반도전-절연 계면층에서 접착특성과 절연성능)

  • Lee, Ki-Taek;Hwang, Sun-Mook;Hong, Joo-Il;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.78-81
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    • 2004
  • In this paper, the effect of adhesion properties of semiconductive-insulating interface layer of silicone rubber on electrical properties was investigated. Surface structure and adhesion of semiconductive silicon rubber by surface asperity was obtained from SEM and T-peel test. In addition, ac breakdown test was carried out for elucidating the change of electrical property by roughness treatment. From the results, Adhesive strength of semiconductive-insulation interface was increased with surface asperity. Dielectric breakdown strength by surface asperity decreased than initial Specimen, but increased from Sand Paper #1200. According to the adhesional strength data unevenness and void formed on the silicone rubber interface expand the surface area and result in improvement of adhesion. Before treatment Sand Paper #1200, dielectric breakdown strength was decreased by unevenness and void which are causing to have electric field mitigation small. After the treatment, the effect of adhesion increased dielectric breakdown strength. It is found that ac dielectric breakdown strength was increased with improving the adhesion between the semiconductive and insulating interface.

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Emission Characteristics of White Organic Light-Emitting Diodes Using Micro Lens Array Film (Micro Lens Array Film을 이용한 백색 OLED의 발광 특성)

  • Chun, Hyun-Dong;Na, Hyunseok;Yang, Jae-Woong;Ju, Sung-Hoo
    • Journal of the Korean institute of surface engineering
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    • v.46 no.2
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    • pp.93-97
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    • 2013
  • We studied the emission characteristics of white phosphorescent organic light-emitting diodes (PHOLEDs), which were fabricated using a two-wavelength method. To optimize emission characteristics of white PHOLEDs, white PHOLEDs with co-doping and blue/co-doping emitting layer (EML) structures were fabricated using a host-dopant system. The total thickness of light-emitting layer was 25 nm and the dopant of blue and red was FIrpic and $Bt_2Ir(acac)$ in UGH3, respectively. In case of co-doping structure, applying micro lens array film showed efficiency improvement from the current efficiency 78.5 cd/A and power efficiency 40.4 lm/W to the current efficiency 131.1 cd/A and power efficiency 65 lm/W and blue / co-doping structure showed efficiency improvement from the current efficiency 43.8 cd/A and power efficiency 22 lm/W to the current efficiency 69 cd/A and power efficiency 32 lm/W.

A Study on the Improvement of the Interface Contact and the Prevention of the Charge Recombination by the Surface Treatment of Transparent Conductive Oxide in Dye-sensitized Solar Cell (염료감응형 태양전지 투명전도성 막의 표면처리를 통한 계면 접촉 향상 및 재결합 방지 연구)

  • Seo, Hyun-Woong;Hong, Ji-Tae;Son, Min-Kyu;Kim, Jin-Kyoung;Shin, In-Young;Kim, Hee-Je
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.11
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    • pp.2214-2218
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    • 2009
  • Dye-sensitized solar cell (DSC) has been considered as a possible alternative to current silicon based p-n junction photovoltaic devices due to its advantages of high efficiency, simple fabrication process and low production cost. Numerous researches for high efficient DSC in the various fields are under way even now. Among them, the compact layer, which prevents the back electron transfer between transparent conductive oxides and the redox electrolyte, is fabricated by various methods such as a ZnO dip-coating, $TiCl_4$ dip-coating, and Ti sputtering. In this study, we tried to fabricate the $TiO_2$ compact layer by the spin-coating method using aqueous $TiCl_4$ solution. The effect of the spin-coating method was checked as compared with conventional dip-coating method. As a result, DSC with a spin-coated compact layer had 33.4% and 6% better efficiency than standard DSC and DSC with a dip-coated compact layer.