• 제목/요약/키워드: Improved materials

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고성능 아연-이온 전지의 고품질 집전체를 위한 그래핀 필름의 결함 제어 (Controlling Defects in Graphene Film for Enhanced-Quality Current Collector of Zinc-Ion Batteries with High Performance)

  • 이영근;안건형
    • 한국재료학회지
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    • 제33권4호
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    • pp.159-163
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    • 2023
  • Zinc-ion Batteries (ZIBs) are currently considered to be effective energy storage devices for wearable electronics because of their low cost and high safety. Indeed, ZIBs show high power density and safety compared with conventional lithium ion batteries (LIBs) and exhibit high energy density in comparison with supercapacitors (SCs). However, in spite of their advantages, further current collector development is needed to enhance the electrochemical performance of ZIBs. To design the optimized current collector for high performance ZIBs, a high quality graphene film is suggested here, with improved electrical conductivity by controlling the defects in the graphene film. The graphene film showed improved electrical conductivity and good electron transfer between the current collector and active material, which led to a high specific capacity of 346.3 mAh g-1 at a current density of 100 mA g-1, a high-rate performance with 116.3 mAh g-1 at a current density of 2,000 mA g-1, and good cycling stability (68.0 % after 100 cycles at a current density of 1,000 mA g-1). The improved electrochemical performance is firmly because of the defects-controlled graphene film, leading to improved electrical conductivity and thus more efficient electron transfer between the current collector and active material.

교차롤압연된 Ni-Cr 합금의 기계적 특성 발달 (Improved Mechanical Properties of Cross Roll Rolled Ni-Cr Alloy)

  • 송국현;김대근;손현택;이해진;김한솔;김원용
    • 한국재료학회지
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    • 제21권10호
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    • pp.556-562
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    • 2011
  • We carried out this study to evaluate the grain refining in and the mechanical properties of alloys that undergo severe plastic deformation (SPD). Conventional rolling (CR) and cross-roll rolling (CRR) as SPD methods were used with Ni-20Cr alloy as the experimental material. The materials were cold rolled to a thickness reduction of 90% and subsequently annealed at $700^{\circ}C$ for 30 min to obtain a fully recrystallized microstructure. For the annealed materials after the cold rolling, electron back-scattered diffraction (EBSD) analysis was carried out to investigate the grain boundary characteristic distributions (GBCDs). The CRR process was more effective when used to develop the grain refinement relative to the CR process; as a result, the grain size was refined from $70{\mu}m$ in the initial material to $4.2{\mu}m$ (CR) and $2.4{\mu}m$ (CRR). These grain refinements have a direct effect on improving the mechanical properties; in this case, the microhardness, yield and tensile strength showed significant increases compared to the initial material. In particular, the CRR-processed material showed more effective values relative to the CR-processed materials. The different texture distributions in the CR (001//ND) and CRR (111//ND) were likely the cause of the increase in the mechanical properties. These findings suggest that CRR can result in materials with a smaller grain size, improved texture development and improved mechanical properties after recrystallization by a subsequent annealing process.

나노크기 Ni-Fe 합금입자 분산${Al_2}{O_3}$ 나노복합재료의 합성 및 특성 (Synthesis and Properties of Nano-sized Ni-Fe Alloy Particle Dispersed ${Al_2}{O_3}$Nanocomposite)

  • 남궁석;오승탁;이재성;정영근;김형섭
    • 한국재료학회지
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    • 제11권11호
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    • pp.986-990
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    • 2001
  • An optimum route to fabricate the $A1_2O_3/Fe-Ni$ alloy nanocomposites with sound microstructure and enhanced mechanical properties as well as magnetism was investigated. To prepare homogeneous nanocomposite powders of Fe-Ni alloy and $Al_2O_3$, the solution-chemistry routes using $Al_2O_3 \; Ni(NO_3)_2{\cdot}6H_2O$ and $Fe(NO_3)_3{\cdot}9H_2O$ powders were applied. Microstructural observation of the powder mixture revealed that the Fe-Ni alloy particles of about 20 nm in size were homogeneously surrounded $A1_2O_3$, forming nanocomposite powder. The hot-pressed composite showed improved fracture toughness and magnetic response. These results suggest that the synergy materials with an improved mechanical properties and excellent functionality can be fabricated by controlled powder preparation and consolidation processing.

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중ㆍ고등학생 대상 영양교육 프로그램 효과평가 (Effectiveness of Web-Based Nutritional Education Program for Junior and Senior High School Students)

  • 양일선;김혜영;이해영;강여화
    • Journal of Nutrition and Health
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    • 제37권7호
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    • pp.576-584
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    • 2004
  • The purpose of this study was to evaluate the effects of Web-based nutrition education program for junior and senior high school students. Three materials, which were printed materials on Group I, WBI (Web-Based Instruction) leaflet on Group II and the web-based nutrition education program developed in the antecedent research, were applied for 564 students in 3 junior high school and 4 senior high school in Seoul during 4 weeks. Pre-test was done from October 21 to October 26, 2002 and post-test was done from November 25 to December 13, 2002. The statistical data analysis was completed using SPSS WIN (ver. 11.0) for descriptive analysis, t-test and ANOVA. According to the evaluation of effectiveness for web-based nutrition education program, nutrition knowledge, food attitude, food habit and nutrient intake were not significantly improved but positively. And on the evaluation of effectiveness for nutrition education program by materials, WBI was more effective educational materials than WBI leaflet and printed materials. Consequently nutrition knowledge, food attitude, food habit and nutrient intake were improved positively but not significantly using WBI, which was due to the instructional period of the only 4 weeks. Therefore long-term instruction should be required for effective nutrition program, as well as more WBI nutrition education program for high school students would need to be developed in the near future in that WBI was effective material on nutrition education.

일축배향 기공채널과 향상된 압축강도를 갖는 다공질 알루미나/뮬라이트 층상 복합체 (Porous Alumina/Mullite Layered Composites with Unidirectional Pore Channels and Improved Compressive Strength)

  • 김규헌;김태림;김동현;윤석영;박홍채
    • 한국세라믹학회지
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    • 제51권1호
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    • pp.19-24
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    • 2014
  • Three-layer porous alumina-mullite composites with a symmetric gradient porosity are prepared using a controlled freeze/gel-casting method. In this work, tertiary-butyl alcohol (TBA) and coal fly ash with an appropriate addition of $Al_2O_3$ were used as the freezing vehicle and the starting material, respectively. When sintered at $1300-1500^{\circ}C$, unidirectional macro-pore channels aligned regularly along the growth direction of solid TBA were developed. Simultaneously, the pore channels were surrounded by less porous structured walls. A high degree of solid loading resulted in low porosity and a small pore size, leading to higher compressive strength. The sintered porous layered composite exhibited improved compressive strength with a slight decrease in its porosity. After sintering at $1500^{\circ}C$, the layered composite consisting of outer layers with a 50 wt% solid loading showed the highest compressive strength ($90.8{\pm}3.7MPa$) with porosity of approximately 26.4%.

BMW N53 직접분사식 가솔린 엔진의 초희박 연소특성에 관한 연구 (A Study on the Ultra Lean Combustion Characteristics of the BMW N53 GDI Engine)

  • 김홍석;오진우;김성대;박철웅;이석환;정용일
    • 한국자동차공학회논문집
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    • 제19권6호
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    • pp.82-89
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    • 2011
  • Ultra lean combustion with stratified air-fuel mixture is one of the methods that can improve fuel economy of gasoline engines. The aim of this study is to show that how much fuel economy is improved and what are differences in engine control of the ultra lean combustion compared with stoichiometric combustion. In this study, the BMW N53 GDI engine, which is one of ultra lean combustion GDI engines introduced in the market recently, was tested at various engine operating conditions. Results indicated that fuel consumption rates were improved by 11.9~25.8% by the ultra lean combustion compared with stoichiometric combustion. It was also found that multiple fuel injection, multiple spark, early intake valve opening, and large vlave overlap duration were the features of the ultra lean combustion for combustion stability and emission improvement.

Low-temperature Sintering Behavior of TiO2 Activated with CuO

  • Paek, Yeong-Kyeun;Shin, Chang-Keun;Oh, Kyung-Sik;Chung, Tai-Joo;Cho, Hyoung Jin
    • 한국세라믹학회지
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    • 제53권6호
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    • pp.682-688
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    • 2016
  • In $TiO_2$-CuO systems, low-temperature sinterability was investigated by a conventional sintering method. Sintering temperatures were set at under $950^{\circ}C$, at which the volume diffusion is inactive. The temperatures are less than the melting point of Ag ($961^{\circ}C$), which is often used as an internal conductor in low-temperature co-fired ceramic technology. To optimize the amount of CuO dopant, various dopant contents were added. The optimum level for enhanced densification was 2 wt% CuO. Excess dopants were segregated to the grain boundaries. The segregated dopants supplied a high diffusion path, by which grain boundary diffusion improved. At lower temperatures in the solid state region, grain boundary diffusion was the principal mass transport mechanism for densification. The enhanced grain boundary diffusion, therefore, improved densification. In this regard, the results of this study prove that the sintering mechanism was the same as that of activated sintering.