• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.119-119
• /
• 2015

Ion beam sputtering has been widely used in Secondary Ion Mass Spectrometry (SIMS), X-ray Photoelectron Spectroscopy (XPS), and Auger Electron Spectroscopy (AES) for depth profile or surface cleaning. However, mainly due to severe matrix effects such as surface composition change from its original composition and damage of the surface generated by ion beam bombardment, conventional sputtering skills using mono-atomic primary ions with energy ranging from a few hundred to a thousand volts are not sufficient for the practical surface analysis of next-generation organic/inorganic device materials characterization. Therefore, minimization of the surface matrix effects caused by the ion beam sputtering is one of the key factors in surface analysis. In this work, the electronic structure of a $Ta_2O_5$ thin film on $SiO_2/Si$ (100) after Ar Gas Cluster Ion Beam (GCIB) sputtering was investigated using X-ray photoemission spectroscopy and compared with those obtained via mono-atomic Ar ion beam sputtering. The Ar ion sputtering had a great deal of influence on the electronic structure of the oxide thin film. Ar GCIB sputtering without sample rotation also affected the electronic structure of the oxide thin film. However, Ar GCIB sputtering during sample rotation did not exhibit any significant transition of the electronic structure of the $Ta_2O_5$ thin films. Our results showed that Ar GCIB can be useful for potential applications of oxide materials with sample rotation.

• Journal of Astronomy and Space Sciences
• /
• v.13 no.1
• /
• pp.63-71
• /
• 1996

A total of 546 UBV photoelectric observations of AG Per was carried out from January to December in 1993 at Chungbuk National University Observatory. With our observations, UBV light curves were constructed, three minimum times of JDHel. 2449284.213, JDHel. 2449360.060, and JDHel. 2449363.192 were determined. The phase displacement of secondary minimum time $\delta$=-0.046 were determined and orbital eccentricity e=0.071 was calculated. Forty-five times of minimum light (including ours) were collected from the literature and plotted on O-C diagram. We analyzed these data and apsidal motion period of U=76.17 (years) was obtained. Using e and U for AG Per, the internal structure constant, log k2, was found to be -2.13.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.16 no.2
• /
• pp.302-312
• /
• 1992

Three dimensional velocity measurements of a 35.deg. inclined jet issuing into turbulent boundary layer on both concave and convex surfaces have been conducted. To investigate solely the effect of each curvature on the flow field, streamwise pressure variations are minimized by adjusting the shape of the opposite wall in the curved region. From the measured velocity components, streamwise mean vorticities are calculated to determine jet-crossflow interface. The results on convex surface show that the injected jet is separated from the wall and the bound vortex maintains its structure far downstream. On concave surface, the secondary flow in the jet cross-sections are enhanced and in some downstream region from the jet exit, the flow on the concave surface has been developed to Taylor-Gortler vortices

• Bulletin of the Korean Chemical Society
• /
• v.35 no.12
• /
• pp.3495-3501
• /
• 2014

A novel crystal, the mono-protonated metformin acetate (1), was obtained and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. It was found that one of the imino group in the metformin cation was protonated along with the proton transfer from the secondary amino group to the other imino group. Its crystal structure was then compared with the previously reported diprotonated metformin oxalate (2). The difference between them is that the mono-protonated metformin cations can be linked by hydrogen bonding to form dimers while the diprotonated metformin cations cannot. Both of them are stabilized by intermolecular hydrogen bonds to assemble a 3-D supermolecular structure. The four potential tautomer of the mono-protonated metformin cation (tautomers 1a, 1b, 1c and 1d) were optimized and their single point energies were calculated by Density Functional Theory (DFT) B3LYP method based on the Polarized Continuum Model (PCM) in water, which shows that the most likely existed tautomer in human cells is the same in the crystal structure. Based on the optimized structure, their Wiberg bond orders, Natural Population Analysis (NPA) atomic charges, molecular electrostatic potential (MEP) maps were calculated to analyze their electronic structures, which were then compared with the corresponding values of the diprotonated metformin cation (cation 2) and the neutral metformin (compound 3). Finally, the possible tautomeric mechanism of the mono-protonated metformin cation was discussed based on the observed phenomena.

• Applied Chemistry for Engineering
• /
• v.10 no.1
• /
• pp.80-84
• /
• 1999

$Li_{4/3}Mn_{5/3}O_4$ having a defect structure was prepared by sol-gel process using lithium acetate and manganese acetate as starting materials, and their electrode characteristics in the lithium secondary battery was investigated. The reaction mole ratio was determined as $AA/Mn(OAc)_2$ of 0.2 and $NH_4OH/Mn(OAc)_2$ to $H_2O/Mn(OAc)_2$ of 0.4. The product was obtained through heat treatment at $350^{\circ}C$ for 12hrs after 1'st heat treatment at $150^{\circ}C$ of xerogel under oxygen atmosphere. When the charge and discharge cycles were performed between 2.0 V and 3.2 V, $Li/Li_{4/3}Mn_{5/3}O_4$ cell showed the dicharge capacity of 84.23 mAh/g and the good cycleability was obtained in the plateau region.

• Molecules and Cells
• /
• v.26 no.2
• /
• pp.206-211
• /
• 2008

HI0381 of Haemophilus influenzae was investigated by circular dichroism (CD) and nuclear magnetic resonance (NMR) spectroscopy. HI0381 is a 153-residue peptidoglycan-associated outer membrane lipoprotein, and a part of the larger Tol/Pal network. Here, we report its backbone $^1H$, $^{15}N$, and $^{13}C$ resonance assignments, and secondary structure predictions. About 97% of all of the $^1HN$, $^{15}N$, $^{13}CO$, $^{13}C{\alpha}$, and $^{13}C{\beta}$ resonances covering 131 non-proline residues of the 134 residue, mature protein, were clarified by sequential and specific assignments. CSI and TALOS analyses revealed that HI0381 contains five ${\alpha}$-helices and five ${\beta}$-strands. To characterize the structure of HI0381, the effects of pH and salt concentration were investigated by CD. In addition, the structural changes occurring when HI0381 was in a membranous environment were investigated by comparing its HSQC spectra and CD data in buffer and in DPC micelles; the results showed that helix ${\alpha}4$ and strand ${\beta}4$ became aligned with the membrane. We conclude that the conformation of HI0381 is affected by the membrane environment, implying that its folded state is directly related to its function.

• Health Policy and Management
• /
• v.28 no.3
• /
• pp.197-201
• /
• 2018

There is a general consensus that many health care problems are attributable to the structural defects of the health care delivery system in Korea. The basic policy aimed to address these problems is to reform the delivery system so as that it incorporates two core principles: (1) stratification of medical care institutions into primary, secondary, and tertiary care providers according to the capability to perform specialized and complex services; (2) patients seeking care starting from the primary care provider and, if necessary, to be referred to the other provider step by step. This policy has been consistently pursued for about 30 years, but the achievement is far from success. Thus it is believed that the feasibility of the policy should be questioned. Starting from this question, based upon the observation of the current structure of the delivery system and its expected changes, the reform policy was discussed focusing on the assessment of its feasibility from both practical and theoretical viewpoints. The discussion leads to cast doubt on the policy for its possibility of making planned changes and producing expected desirable effects. Therefore it is advisable to investigate a wide range of alternative strategies and models for improving health care delivery.

• Computational Structural Engineering
• /
• v.10 no.4
• /
• pp.327-336
• /
• 1997

When a structure is built on the consolidation ground, the instant elastic deflection occures according to the characteristics of the ground and the load on it. And the corresponding contact pressure is established. But, as time passes, the secondary consolidating deflection is added to the instant elastic deflection, the upper structure, due to its flexural rigidity, resist to the additional curvature. So the variation of the contact pressure occurs. And this new contact pressure exerts influence on the consolidation form again. The new consolidation form exerts influence on the contact pressure in return. This kind of interaction continues till all the consolidation of the ground is finished. So the consolidation problem can not be definded as the linear problem. This paper intends to scheme an approximate iteration method to analyse this non-linear interaction problem between the upper structure and the lower consolidation ground which supports the former.

• BMB Reports
• /
• v.51 no.2
• /
• pp.73-78
• /
• 2018

Vascular endothelial growth factor and its receptor (VEGF-VEGFR) system play a critical role in the regulation of angiogenesis and lymphangiogenesis in vertebrates. Each of the VEGF has specific receptors, which it activates by binding to the extracellular domain of the receptors, and, thus, regulates the angiogenic balance in the early embryonic and adult stages. However, de-regulation of the VEGF-VEGFR implicates directly in various diseases, particularly cancer. Moreover, tumor growth needs a dedicated blood supply to provide oxygen and other essential nutrients. Tumor metastasis requires blood vessels to carry tumors to distant sites, where they can implant and begin the growth of secondary tumors. Thus, investigation of signaling systems related to the human disease, such as VEGF-VEGFR, will facilitate the development of treatments for such illnesses.

• Korean Journal of Environmental Biology
• /
• v.38 no.2
• /
• pp.216-221
• /
• 2020

A eukaryotic marine microalga was isolated from Jungmun Saekdal Beach, Jeju Island, Korea and an integrated approach, including molecular phylogeny and morphology, was used to determine its taxonomical status. Molecular phylogenetic evidence inferred from the small subunit (SSU) 18S rRNA sequence and internal transcribed spacer (ITS) secondary structure analysis clearly showed that the isolate belonged to the recently described species, Jaagichlorella roystonensis. Distinctive morphological keys of the species were also observed by light microscopy and scanning/transmission electron microscopy(S/TEM). In this study, a Korean marine J. roystonensis species was described for the first time and was subsequently added to the national culture collections in Korea.