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Investigation of Stereo-dynamic Properties for the Reaction H+HLi by Quasi-classical Trajectory Approach

  • Wang, Yuliang;Zhang, Jinchun;Jiang, Yanlan;Wang, Kun;Zhou, Mingyu;Liang, Xiaorui
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2873-2877
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    • 2012
  • Quasi-classical trajectory (QCT) calculations of H+HLi reaction have been carried out on a new potential energy surface of the ground state reported by Prudente et al. [Chem. Phys. Lett. 2009, 474, 18]. The four polarization-dependent differential cross sections have been carried out in the center of mass (CM) frame at various collision energies. The reaction probability for the depletion channel has been studied over a wide collision energy range. It has been found that the collision energy decreases remarkably reaction probability, which shows the expected behavior of the title reaction belonging to an exothermic barrierless reaction. The results are in good agreement with previous RMP results. The P(${\theta}_r$), P(${\phi}_r$) and P(${\theta}_r,\;{\phi}_r$) distributions, the k-k'-j' correlation and the angular distribution of product rotational vectors are presented in the form of polar plots. The average rotational alignment factor <$P_2(j{\prime}{\cdot}k)$> as a function of collision energy is also calculated. The results indicate that the collision energy has a great influence on the polarization of the product rotational angular momentum vector j'.

A Case Study on the Field Investigation and Stability Analysis of the Collapsed Cut-Slope in Tunnel Portal, Danyang (단양 지역 터널입구부 붕괴절토사면 현장조사 및 안정성 해석 사례 연구)

  • Kim, Seung-Hyun;Koo, Ho-Bon;Kim, Seung-Hee
    • The Journal of Engineering Geology
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    • v.19 no.3
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    • pp.401-408
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    • 2009
  • Old national Road No. 59 that connects Danyang and Gagok has 35 dangerous cut slopes. It is relatively narrow and has a poor alignment. The torrential rains in 2002 and 2006 has caused numerous slope collapses, landslides and road settlements in this area. The old road's high risk level lead to the planning and construction of a new national road. During the construction of the new road in December 2006, the right side of Dugcheon Tunnel entrance has collapsed and tension cracks were observed on the district road above the tunnel. In order to determine the cause of failure, intensive field investigation and monitoring cracks were performed together with Lower Hemisphere Projection Analysis, Limit Equilibrium Analysis and Finite Difference Analysis.

An Activity-Based Analysis of Contextual Information of Activity Patterns and Profiles (활동기반 접근법에 의한 활동패턴의 맥락적 정보분석과 프로파일)

  • Jo, Chang-Hyeon
    • Journal of Korean Society of Transportation
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    • v.25 no.6
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    • pp.171-183
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    • 2007
  • Urban transport demand is derived from activity participation. A variety of individual daily activities based on the decisions on activity participation result in collective spatial behavior. The travel derived from the effort to overcome the spatially distributed locations of adjacent activities represents the detailed structural relationships among activities. An activity-based approach provides an important framework of analyzing contemporary urban daily life in the sense that it studies the interaction between individuals' daily decision making and social practice in time and space, on the one hand, and socio-spatial environment on the other. The current study identifies representative patterns of urban daily activity implementations and analyzes the correlation between representative patterns and individuals' characteristics and contextual characteristics. The study shows that urban daily activity patterns can be grouped in a limited number of representative patterns, which are systematically correlated with socio-spatial characteristics. The results provide related transportation policy implications.

The Change of Sagittal Alignment of the Lumbar Spine after Dynesys Stabilization and Proposal of a Refinement

  • Park, Won Man;Kim, Chi Heon;Kim, Yoon Hyuk;Chung, Chun Kee;Jahng, Tae-Ahn
    • Journal of Korean Neurosurgical Society
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    • v.58 no.1
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    • pp.43-49
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    • 2015
  • Objective : $Dynesys^{(R)}$ is one of the pedicle-based dynamic lumbar stabilization systems and good clinical outcome has been reported. However, the cylindrical spacer between the heads of the screws undergoes deformation during assembly of the system. The pre-strain probably change the angle of instrumented spine with time and oblique-shaped spacer may reduce the pre-strain. We analyzed patients with single-level stabilization with $Dynesys^{(R)}$ and simulated oblique-shaped spacer with finite element (FE) model analysis. Methods : Consecutive 14 patients, who underwent surgery for single-level lumbar spinal stenosis and were followed-up more than 24 months (M : F=6 : 8; age, $58.7{\pm}8.0$ years), were analyzed. Lumbar lordosis and segmental angle at the index level were compared between preoperation and postoperative month 24. The von Mises stresses on the obliquely-cut spacer ($5^{\circ}$, $10^{\circ}$, $15^{\circ}$, $20^{\circ}$, $25^{\circ}$, and $30^{\circ}$) were calculated under the compressive force of 400 N and 10 Nm of moment with validated FE model of the L4-5 spinal motion segment with segmental angle of $16^{\circ}$. Results : Lumbar lordosis was not changed, while segmental angle was changed significantly from $-8.1{\pm}7.2^{\circ}$ to $-5.9{\pm}6.7^{\circ}$ (p<0.01) at postoperative month 24. The maximum von Mises stresses were markedly decreased with increased angle of the spacer up to $20^{\circ}$. The stress on the spacer was uneven with cylindrical spacer but it became even with the $15^{\circ}$ oblique spacer. Conclusion : The decreased segmental lordosis may be partially related to the pre-strain of Dynesys. Further clinical and biomechanical studies are required for relevant use of the system.

Full Duplex Robot System for Transferring Flat Panel Display Glass (디스플레이용 판유리 이송을 위한 양방향 이송 로봇장치)

  • Lee, Dong Hun;Lee, Chibum;Kim, Sung Dong;Cho, Young Hak
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.6
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    • pp.996-1002
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    • 2013
  • This study addresses the development of a full duplex robotic system for transferring flat-panel display glass. We propose to accomplish this using a bidirectional linear transfer mechanism in place of the conventional rotary transfer mechanism. The developed full duplex robot comprises a driving part that carries the glass panel laterally, vertical part that can be moved up and down by means of a ball screw and linear motion guide arrangement, and hand part that slides by the cylinder of the driving part along the guide rail with a V-guide bearing attached to the bottom of the support. In addition, an alignment part prevents the hand part from derailing and holds the hand part while the driving part moves horizontally. The full duplex robot lifts and drives a glass panel directly while transferring it to the buffer and does not require rotational motion. Therefore, both transferring and stacking are realized with a single device. This device can be used in existing industrial facilities as an alternative to existing industrial robots in current as well as future process lines. The proposed full duplex robot is expected to save considerable amounts of time and space, and increase product throughput.

Adhesion Characteristics between Stamp and Polymer Materials Used in Thermal Nanoimprint Lithography (열 나노임프린트 리소그래피에서 사용되는 스탬프와 폴리머 재료 사이의 점착 특성)

  • Kim Kwang-Seop;Kang Ji-Hoon;Kim Kyung-Woong
    • Tribology and Lubricants
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    • v.22 no.4
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    • pp.182-189
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    • 2006
  • In this paper, the adhesion characteristics between a fused silica without or with an anti-sticking layer and a thermoplastic polymer film used in thermal NIL were investigated experimentally in order to identify the release performance of the anti-sticking layer. The anti-sticking layers were derived from fluoroalkylsilanes, (1H, 1 H, 2H, 2H-perfluorooctyl)trichlorosilane ($F_{13}-OTS$) and (3, 3, 3-trifluoropropyl)trichlorosilane (FPTS), and coated on the silica surface in vapor phase. The commercial polymers, mr-I 7020 and 8020 (micro resist technology, GmbH), for thermal NIL were spin-coated on Si substrate with a rectangular island which was fabricated by conventional microfabrication process to achieve small contact area and easy alignment of flat contact sur- faces. Experimental conditions were similar to the process conditions of thermal NIL. When the polymer film on the island was separated from the silica surface after imprint process, the adhesion force between the silica surface and the polymer film was measured and the surfaces of the silica and the polymer film after the separation were observed. As a result, the anti-sticking layers remarkably reduced the adhesion force and the surface damage of polymer film and the chain length of silane affects the adhesion characteristics. The anti-sticking layers derived from FPTS and $F_{13}-OTS$ reduced the adhesion force per unit area to 38% and 16% of the silica sur-faces without an anti-sticking layer, respectively. The anti-sticking layer derived from $F_{13}-OTS$ was more effective to reduce the adhesion, while both of the anti-sticking layers prevented the surface damages of the polymer film. Finally, it is also found that the adhesion characteristics of mr-I 7020 and mr-I 8020 polymer films were similar with each other.

Colossal Magnetoresistance in Chalcogenide Spinels $Ni_xFe_{1-x}Cr_2S_4(X = 0.05, 0.1, 0.2)$ (Spinel 유화물 $Ni_xFe_{1-x}Cr_2S_4(X = 0.05, 0.1, 0.2)$의 초거대자기저항(CMR)현상에 관한 연구)

  • 박재윤
    • Journal of the Korean Magnetics Society
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    • v.11 no.4
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    • pp.151-156
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    • 2001
  • Recently many studies on manganese oxides Ln$_{1-x}$A$_{x}$MnO$_3$(Ln=La, Pr, Nd lanthannide; A=Ca, Sr, Ba, Pb +2 ions) reported CMR properties. CMR have been also found in chalcogenide spinels. We have investigated that Ni ion substitutions for Fe ion have effects on CMR properties in chacogenide spinels Ni$_{x}$Fe$_{1-x}$Cr$_2$S$_4$. It was found that with increasing Ni concentration Jahn-Teller distortion was strengthened and Curie temperature T$_{c}$ was increased. CMR properties could be explained with Jahnl-Teller effect, half-metallic electronic structure, and the alignment of magnetic domain due to the strong magnetic field, which is different in that double exchange interactions dominate CMR properties in manganese oxides.

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Developing Expert System for Recovering the Original Form of Ancient Relics Based on Computer Graphics and Image Processing (컴퓨터 그래픽스 및 영상처리를 이용한 문화 원형 복원 전문가시스템 개발)

  • Moon, Ho-Seok;Sohn, Myung-Ho
    • Journal of the Korea Society of Computer and Information
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    • v.11 no.6 s.44
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    • pp.269-277
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    • 2006
  • We propose a new expert system for recovering the broken fragments of relics into an original form using computer graphics and image processing. This paper presents a system with an application to tombstones objects of flat plane with letters carved in for assembling the fragments by placing their respective fragments in the right position. The matching process contains three sub-processes: aligning the front and letters of an object, identifying the matching directions, and determining the detailed matching positions. We apply least squares fitting, vector inner product, and geometric and RGB errors to the matching process. It turned out that 2-D translations via fragments-alignment enable us to save the computational load significantly. Based on experimental results from the damaged cultural fragments, the performance of the proposed method is illustrated.

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A Method of Feature Extraction on Micro-Raman Spectra for Classification of Neuro-degenerative Disorders (마이크로 라만 스펙트럼에서 퇴행성 뇌신경질환 분류를 위한 특징 추출 방법 연구)

  • Park, Aa-Ron;Baek, Sung-June
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.48 no.2
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    • pp.80-85
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    • 2011
  • Alzheimer's disease and Parkinson's disease are the most common neurodegenerative disorders. In this paper, we proposed a feature extraction method for classification of AD and PD based on micro-Raman spectra from platelet. The first step of the preprocessing is a simple smoothing followed by background elimination to the original spectra to make it easy to measure the intensity of the peaks. The last step of the preprocessing was peak alignment with the reference peak. After the inspection of the preprocessed spectra, we found that proportion of two peak intensity at 743 and $757cm^{-1}$ and peak intensity at 1248 and $1448cm^{-1}$ are the most discriminative features. Then we apply mapstd method for normalization. The method returned data with means to 0 and deviation to 1. With these three features, the classification result involving 263 spectra showed about 95.8% true classification in case of MAP(maximum a posteriori probability).

Implementation on the Portable Blood Gas Analyzer and Performance Estimation/A Study on the Hydrometer Calibration System using Image Processing (영상처리 기법을 이용한 부액계 자동 교정 시스템 구현)

  • Lee, Yong-Jae;Chang, Kyung-Ho;Oh, Chae-Youn;Jung, Sang-Duk
    • Journal of Sensor Science and Technology
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    • v.12 no.6
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    • pp.258-264
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    • 2003
  • The present paper studies how to calibrate hydrometer using image process. The method aligns particular scales of hydrometer selected for calibrating the hydrometer with the horizontal plane of the reference liquid automatically without man's operation. Major parts composing the system are CCD camera, frame grabber, stepping motor and image process program. The image process program is composed of a part that locates the meniscus and aligns it with a scale and a part that controls the step motor. To verify the performance of the developed method, this study compares the meniscus and scale observed directly with the naked eye with the result of calibration by the manual calibration method. The differences between the corrections were less than $0.004\;kg/m^3$ with uncertainty of $0.06\;kg/m^3$. These showed that the calibration results of the developed hydrometer calibration using image process nearly equal to manual method.