• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.5 no.3
• /
• pp.221-227
• /
• 2007

Fenton's reagent is applied to directly decompose the ion-exchange resins, IRN-78 and the mixed resin with IRN-77. The newly applied procedures is to dry the resin first and the catalyst solution is completely absorbed into the resin, then a limited dose of $H_2O_2$ is introduced for an effective reaction between the reagents within the resin. As a characteristic on the decomposition of IRN-78, the resin mixture should be heated to $40^{\circ}C$ to induce the initial reaction and lag time is also needed for about 20 minutes until the main reaction occurs. The effectiveness of the decomposition is investigated using $CuSO_4,\;Cu(NO_3)_2\;and\;FeSO_4$ as a catalyst and the decomposition rate is compared depending on the concentration of each catalyst and the amount of $H_2O_2$. The most effective catalyst was found to be $FeSO_4$ for IRN-78 alone and the mixed resin with IRN-77, and $FeSO_4$ showed a special effect that the reaction was initiated without heating and a lag time. Furthermore, the optimum concentration of the catalyst for each resin and the mixed one is suggested in the view point of the amount of $H_2O_2$ needed and the stability of the decomposition reaction.

• Proceedings of the Korean Nuclear Society Conference
• /
• 1997.05b
• /
• pp.345-349
• /
• 1997

고준위 방사성 액체폐기물에서 얻어지는 백금족 금속(Pd, Rh, Ru) 들의 분리 및 정제방법으로 강염기성 음이온교환수지를 사용하여본 결과 상용 수지중에서 Dowex 1 $\times$ 8 이 IRN-78 에 비하여 저 농도의 질산 농도에서 Pd(II) 의 분리 및 정제시 우수한 흡착성을 보여 주었으며 Rh(III) 의 흡착은 Pd(II) 의 것보다 훨씬 낮은 값을 보여 주었다. 이 수지들의 백금족 금속에 대한 흡착성을 문헌에 보고된 실험 결과들과 비교 검토하여 본 바 이온 그룹으로 3급 및 4급 Benzimidazole을 가지는 수지에 비하여 훨씬 낮은 값을 나타내었다. 따라서 실용성이 큰 강염기성 음이온수지로서는 Benzimidazole과 같은 혼합 아민 그룹을 지닌 수지가 가장 접합할 것으로 전망되었다.

• Nuclear Engineering and Technology
• /
• v.55 no.7
• /
• pp.2547-2555
• /
• 2023

Amberlite IRN-78 resin was incorporated with iron to make a hybrid resin for the removal of silica from the borated water of nuclear power plants. The hybrid resin contained 0.84 wt % iron compounds upon pyrolysis. In batch experiments carried out at room temperature, 1 g of the hybrid resin removed ~60 ㎍ silica from 1 ppm borated water in ~120 min. The efficiency of the hybrid material increased with the resin quantity, decreased with silica concentration, and remained unchanged at different pH values. Freundlich and Temkin isothermal adsorption dominated the silica removal process and followed the pseudo-first-order and intra-particle diffusion mechanism simultaneously. The concentration of the leached iron remained appreciably under the safe limits of 200 ㎍/l during the experiments. This detailed study suggests the use of hybrid resin for the removal of silica from borated water streams and other similar systems.

• Preventive Nutrition and Food Science
• /
• v.7 no.1
• /
• pp.18-21
• /
• 2002

The extract of Ginkgo biloba leaves was measured for inhibitory activity against xanthine oxidase. Aceton extract of G. biloba leaves showed strong inhibitory activity. Inhibitory activities of the fractionated extract were in the order of water > ethyl acetate fractions. Two fractions exhibiting strong inhibitory activities ware further purified via repeated silica gel, Amberlite IRN-78, Polyclar AT, and Sephadex LH-20 column chromatographies. Active components were isolated and identified through $^1$H-NMR and $^{13}$ C-NMR. The compounds were characterized as kaempferol 3-Ο-$\alpha$-(6$^{"′}$-p-coumaroylglucosyl-$\beta$-1,4-rhamnoside), and quercertin 3-Ο-$\alpha$-(6$^{′}$-p-coumaroylglucosyl-$\beta$-1,4-rhamnoside).

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.7 no.1
• /
• pp.71-78
• /
• 1969

To study the varietal differences of vegetative organs, yield and yield components along the periodical changes of rice variety in korea, this experiment was conducted in 1968. Eighteen used varieties were grouped into 6 varietal groups by the cultivated period as follow.: 1) Group I - Korean local varieties cultivated about 1907, 2) Group II - introduced varieties cultivated in 1907 - 1930, 3) Group III - introduced varieties cultivated in 1930-1960, 4) Group IV - improved varieties cultivated in 1930-1960, 5) Group V - introduced varieties cultivated after 1960 and 6) Group VI - improved varieties cultivated after 1960. 1. Varietal Group I showed the longest leaves, the largest leaf area, the lowest value of leaf area index and the highest value of flag leaf angle. Along the periodical changes of rice varieties the leaf length, the total leaf area and the flag leaf angle were decreased, and the leaf area index was increased. 2. Varietal Group I showed higher value of the length and the weight of leaf sheath than those of Group II, III, IV, V and VI. The length of every internode was longer in Group I than in the other varietal groups. The weight of every internode was shown higher value in Group 1. The length and the weight of every internode were decreased along the periodical changes of rice variety. 3. Varietal Group I and Group III showed the higher value of culm length, panicle length and the number of grain per panicle length and groups. Group IV, V and VI had the higher value of the number of panicle, the maturing rate and the 1, 000 grains weight. Varietal Group V and VI which are cultivated in recent years showed shorter culm and panicle length, higher value of the maturing rate and the 1, 000 grains weight, and intermediate in the number of panicle and the number of grain per panicle. 4. The lowest value of straw weight was found in Group I. The highest value of grain yield was shown in Group VI, intermediate in Group II, III, IV and V and lowest in Group I. Grain-straw ratio was shown highest in Group VI.