• Title/Summary/Keyword: IR-29

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Particle Shapes and Optical Property of Synthesized ZnO with Amine Additives (아민첨가제를 사용하여 합성된 ZnO의 입자형상 및 광학적 특성)

  • Hyeon, Hye-Hyeon;Hyun, Mi-Ho;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.23-29
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    • 2016
  • Zinc oxide of hexagonal wurzite, is known as n-type semiconductor. It has a wide band gap energy of 3.37 eV and large exciton binding energy of 60 meV. It can be widely applied to gas sensors, laser diodes, dye-sensitized solar cells and degradation of dye waste. The use of microwave hydrothermal synthesis brings a rapid reaction rate, high yield, and energy saving. Amine additives control the different particle shapes because of the chelate effect and formation of hydroxide ion. In this study, zinc nitrate hexahydrate was used as zinc precursor. In addition, ethanolamine, ethylenediamine, diethylenetriamine, and hexamethylenetetramine are used as shape control agent. The pH value was controlled as 11 by NaOH. The shapes of zinc oxide are star-like, rod, flower-like, and circular cone. In order to analyze physical, chemical, and optical properties of ZnO with diverse amine additives, we used XRD, SEM, EDS, FT-IR, UV-Vis spectroscopy, and PL spectroscopy.

Near-IR Spectroscopic Studies of the Hydrogen Bonding between Thioacetamide and N,N-Dimethylpropionamide in Carbon Tetrachloride (사염화탄소 중에서 Thioacetamide와 N,N-Dimethylpropionamide간의 수소 결합에 관한 분광학적 연구)

  • Byung-Chul Kim;Seok-Kyu Song;Keon Kim;Young-Sang Choi
    • Journal of the Korean Chemical Society
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    • v.29 no.6
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    • pp.599-607
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    • 1985
  • Near-ir spectra have been obtained for the $ν_3$+ Amide II combination thioacetamide(TA) band in CC$l_4$ and TA-DMP in CC$l_4$ in the range of 5 to 55${\circ}C$. Absorbance of the weak bands of the DMP and solvent has been compensated. The spectra are analyzed by the computer resolution into two Lorentzian-Gaussian product bands which have been identified with monomeric TA and 1 : 1 TA-DMP complex. Equilibrium constants and thermodynamic parameters for the hydrogen bonding between TA and DMP have been evaluated by the analysis of the concentration and temperature dependent spectra for the very dilute CC$l_4$ solutions. The $ΔH{\circ} and ΔS{\circ}$ of TA and DMT have been found to be -14.6 kJmo$l^{-1}$ and -16.2 Jmo$l^{-1}$ de$g^{-1}$.

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STSAT-3 Operations Concept (과학기술위성 3호 운영개념)

  • Lee, Seung-Hun;Park, Jong-Oh;Rhee, Seung-Wu;Jung, Tae-Jin;Lee, Dae-Hee;Lee, Joon-Ho
    • Aerospace Engineering and Technology
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    • v.10 no.2
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    • pp.29-36
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    • 2011
  • The Science and Technology Satellite-3 (STSAT-3) is based on the KITSAT-1, 2, 3 and STSAT-1, 2 which were Korea micro-satellites for the mission of space and earth science. The objectives of the STSAT-3 are to support earth and space sciences in parallel with the demonstration of spacecraft technology. The STSAT-3 carries an infrared (IR) camera for space & earth observation and an imaging spectrometer for earth observation. The IR payload instrument of the STSAT-3, Multi-purpose Infrared Imaging System (MIRIS), will observe the Galactic plane and North/South Ecliptic poles to research the origin of universe. The secondary payload instrument, Compact Imaging Spectrometer (COMIS), images the Earth's surface. The data acquired from COMIS are expected to be used for various application fields such as monitoring of disaster management, water quality studies, and farmland assessment. In this paper we present the operations concept of STSAT-3 which will be launched into a sun-synchronous orbit at a nominal altitude of 600km in late 2012.

Syntheses and Characterization of PBO Precursors Containing Dimethylphenoxy and/or MPEG Pendant Groups (Dimethylphenoxy와 MPEG 팬던트 그룹을 갖는 폴리벤즈옥사졸 전구체의 합성 및 특성)

  • Yoon Doo-Soo;Choi Jae-Kon;Jo Byung-Wook
    • Polymer(Korea)
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    • v.29 no.5
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    • pp.493-500
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    • 2005
  • Polyhydroxyamides(PHAs) having poly(ethylene glycol)methyl ether (MPEG) and/or dimethylphenoxy pendant groups were synthesized by solution polycondensation at low temperature. The inherent viscosities of the PHAs measured at $35^{\circ}C$ in DMAC or DMAc/LiCl solution were in the range of $0.51\~2.31dL/g$. This precursor polymers were studied by FT-IR, $1H-NMR$, DSC, and TGA. Solubility of the precursors with higher MPEG unit was increased, especially the polymer having MPEG $(M_n=1100)$ was soluble or partially soluble in ethanol, methanol, and water as well as aprotic solvents, but the PBOs were nearly insoluble in a variety of solvents. PHAs were converted to polybenzoxazoles (PBOs) by thermal cyclization reaction with heat of endotherm. In case of the precursors having MPEG nit, the precursor polymers with a higher $M_n$ were fully cyclized at a lower temperature than one with a lower $M_n$.

Effect of Ozone Treatment of Carbon Nanotube on PTC/NTC Behaviors of High-Density Polyethylene Matrix Composites (오존처리에 따른 탄소나노튜브 강화 고밀도 폴리에틸렌 기지 복합재료의 PTC/NTC 특성)

  • Park, Soo-Jin;Seok, Su-Ja;Lee, Jae-Rock;Hong, Sung-Kwon
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.32-35
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    • 2005
  • In this paper, the carbon nanotubes (CNTs) were ozonized and the positive temperature coefficient (PTC) behaviors of CNTs-filled high-density polyethylene (HDPE) conductive composites were studied. The results of element analysis (EA) and FT-IR indicate that the oxygen-containing functional groups on the CNTs surfaces, such as O-H, C-O, and C=O groups, were increased with the ozonization. Electrical resistivities of the CNTs/HDPE composites were measured by using a digital multimeter. The resistivity of the composites was increased abruptly near the crystalline melting temperature of the HDPE used as matrix, which could be attributed to the destruction of conductive network by the thermal expansion of HDPE. And, the PTC intensity of the CNTs/HDPE composites was increased with the increase of the ozone treatment time. It was probably due to the growing of maximum volume resistivity of the composites induced by the increased oxygen-containing functional groups in the CNTs surfaces.

Non-Operative Management with Angioembolization of Grade IV and V Renal Injuries in a Hybrid Emergency Room System

  • Ahn, So Ra;Seo, Sang Hyun;Lee, Joo Hyun;Park, Chan Yong
    • Journal of Trauma and Injury
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    • v.34 no.3
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    • pp.191-197
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    • 2021
  • Renal injuries occur in more than 10% of patients who sustain blunt abdominal injuries. Non-operative management (NOM) is the established treatment strategy for lowgrade (I-III) renal injuries. However, despite some evidence that NOM can be successfully applied to high-grade (IV, V) renal injuries, it remains unclear whether NOM is appropriate in such cases. The authors report two cases of high-grade renal injuries that underwent NOM after embolization in a hybrid emergency room (ER) system with a 24/7 in-house interventional radiology (IR) team. A 29-year-old male visited Wonkwang University Hospital Regional Trauma Center complaining of right abdominal pain after being hit by a rope. Computed tomography (CT) was performed 16 minutes after arrival, and the CT scan indicated a grade V right renal injury. Arterial embolization was initiated within 31 minutes of presentation. A 56-year-old male was transferred to Wonkwang University Hospital Regional Trauma Center with a complaint of right flank pain. He had initially presented to a nearby hospital after falling from a 3-m height. Thanks to the key CT images sent from the previous hospital prior to the patient's arrival, angiography was performed within 8 minutes of the patient's arrival and arterial embolization was completed within 25 minutes. Both patients were treated successfully through NOM with angioembolization and preserved kidneys. Hematoma in the first patient and urinoma in the second patient resolved with percutaneous catheter drainage. The authors believe that the hybrid ER system with an in-house IR team could contribute to NOM and kidney preservation even in high-grade renal injuries.

Characteristics of Water Contamination and Precipitates of Acid Mine Drainage, Bongyang Abandoned Coal Mine, Danyang, Chungbuk Province with Emphasis on Fe and Al behaviors (충북 단양 봉양폐탄광 산성광산배수의 수질오염과 침전물의 특성: 철, 알루미늄의 거동을 중심으로)

  • Choo, Chang Oh;Lee, Jin Kook
    • The Journal of Engineering Geology
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    • v.29 no.2
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    • pp.163-183
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    • 2019
  • We investigated acid mine drainage (AMD) of Bongyang abandoned coal mine, Danyang, Chungbuk Province with emphasis on geochemical contaminants in AMD and precipitates using chemical analyses, XRD, SEM, IR, and $^{27}Al$ NMR. Water chemistry changes with pH and oversaturation of chemical species. According to calculation of saturation index, the AMD is saturated with various Fe, Al minerals. Orange or orcher precipitates are composed of schwertmannite and goethite, associated with Leptothrix orchracea bacteria, whereas whitish precipitates are composed mostly of alumimous minerals such as basaluminite with poor crystallinity. The whitish precipitates include trace $Al_{13}$-Tridecamer. It is important to control the precipitation and solubility of aluminous species for ensuring remediation and control for the AMD discharged from the Bongyang abandoned coal mine.

Dielectric properties and microstructures of (CaxSr1-x)ZrO3 ceramics

  • Li, Yu-De;Chen, Jian-Ming;Lee, Ying-Chieh
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.461-466
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    • 2018
  • The effects of Ca/Sr ratio and the sintering temperature on the properties of $(Ca_xSr_{(1-x)})ZrO_3$ (CSZ) ceramics were investigated in this study. CSZ ceramics were prepared using solid-state reaction process, which were sintered in air at temperatures ranging from $1350^{\circ}C$ to $1450^{\circ}C$. Their structures were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM). The change in Ca/Sr ratio significantly affected the crystalline phase and the dielectric properties of the $(Ca_xSr_{(1-x)})ZrO_3$ ceramics. The secondary phase, $Ca_{0.15}Zr_{0.85}O_{1.85}$, was observed and increased correspondingly with the rising of sintering temperatures. In order to understand the effects of secondary phase on the dielectric properties of CSZ ceramics, the $Ca_{0.15}Zr_{0.85}O_{1.85}$ phase was prepared individually using solidstate method. The $Ca_{0.15}Zr_{0.85}O_{1.85}$ ceramics sintered at $1500^{\circ}C$ for 2 hours possessed a dielectric constant (${\varepsilon}_r$) of 21.7, a dielectric loss ($tan{\delta}$) of $49.510^{-4}$ and an Insulation Resistance (IR) of $2.1{\times}10^{10}{\Omega}$. The ($Ca_{0.7}Sr_{0.3})ZrO_3$ ceramics exhibited the best dielectric properties, with a permittivity of 29, a dielectric loss ($tan{\delta}$) of $2.7{\times}10^{-4}$, and an Insulation Resistance (IR) of $2.6{\times}10^{12}{\Omega}$.

Studies on the Inheritance of Quantitative Characters in Rice Ⅵ. Differences of Degree of Heterosis and Gene Distributions for Several Agronomic Characters of Rice in 9-parent Diallel Cross $F_1$ and $F_2$ (수도 양적 형질의 유전에 관한 연구 제 6 보. 이면교잡에 의한 주요형질의 유전분석)

  • Jun, Byeong-Tae;Cho, Soo-Yeon;Chang, Kwon-Yeol
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.30 no.3
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    • pp.287-293
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    • 1985
  • Degree of heterosis and gene distributions of several agronomic characters of rice were studied with F$_1$ and F$_2$ generations of 9-parent partial diallel cross in 1983-1984. Degree of heterosis was greater in F$_1$ hybrids than F$_2$ hybrids for culm length, panicle length and number of panicle and the heterobeltiosis could be observed in culm length and number of panicle from several crosses. Incomplete dominance was exhibited by culm length, panicle length and number of panicle in F$_1$ and F$_2$ generations.

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Securitization and the Merger of Great Power Management and Global Governance: The Ebola Crisis

  • Cui, Shunji;Buzan, Barry
    • Analyses & Alternatives
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    • v.3 no.1
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    • pp.29-61
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    • 2019
  • Within the discipline of International Relations (IR), the literatures on global governance (GG) and great power management (GPM) at best ignore each other, and at worst treat the other as a rival or enemy. On the one hand, the GPM literature, like both realism in all its forms, and neoliberalism, takes for granted the ongoing, disproportionate influence of the great powers in the management of the international system/society, and does not look much beyond that. On the other hand, the GG literature emphasizes the roles of smaller states, non-state actors and intergovernmental organizations (IGOs), and tends to see great powers more as part of the problem than as part of the solution. This paper argues that the rise to prominence of a non-traditional security agenda, and particularly of human security, has triggered a de facto merger of GPM and GG that the IR literature usually treated as separate and often opposed theories. We use the Ebola crisis of 2014-15 to show how an issue framed as human security brought about a multi-actor response that combined the key elements of GPM and GG. The security framing overrode many of the usual inhibitions between great powers and non-state actors in humanitarian crises, including even the involvement of great power military forces. Through examining broadly the way in which the Ebola crisis is tackled, we argue that in an age of growing human security challenges, GPM and GG are necessarily and fruitfully merging. The role of great powers in this new human security environment is moving away from the simple means and ends of traditional GPM. Now, great powers require the ability to cooperate and coordinate with multiple-level actors to make the GG/GPM nexus more effective and sustainable. In doing so they can both provide crucial resources quickly, and earn respect and status as responsible great powers. IGOs provide legitimation and coordination to the GPM/GG package, and non-state actors (NSAs) provide information, specialist knowledge and personnel, and links into public engagement. In this way, the unique features of the Ebola crisis provide a model for how the merger of GPM and GG might be taken forward on other shared-fate threats facing global international society.

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