• 제목/요약/키워드: IR spectra

검색결과 851건 처리시간 0.034초

높은 온도에서 Urea와 금속이온과의 반응으로 얻어진 금속 Complexes의 합성과 분광학적 연구 (Synthesis and Spectroscopic Studies of Metal Complexes Formed in the Reaction of Metal Ions with Urea at High Temperature)

  • Gaballa, Akmal S.;Teleb, Said M.;Nour, El-Metwally
    • 대한화학회지
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    • 제51권4호
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    • pp.339-345
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    • 2007
  • Urea는 높은 온도(60~80 °C)의 수용액 상태에서 PtCl2, H2[PtCl6]·6H2O, H2[IrCl6] Ni(CH3CO2)2 와 반응해서 각각 (1)[PtCl2(Urea)]·2H2O, (2)(NH4)2[PtCl6], (3)(NH4)2[IrCl6]·H2O, (4)[Ni2(OH)2(NCO)2(H2O)2]의 complexes를 생성 한다. complexe 1에서 urea는 중성 bidentate 리간드로써 Pt(II)와 배위한다. complexe 2,3,4에서는 높은 온도에서 반 응하는 동안 배위 urea분자들이 분해되고 다양한 반응생성물들을 얻을 수 있다. 모든 complexes은 각각 적당한 수득률 로 dark green(1) yellow(2), pale brown (3) faint green(4)의 침전물로 분리된다. 반응생성물은 열분석, IR, 1H and 13C NMR spectra에 의해 측정 되었다. 이 complexes의 구성을 설명하는 일반적인 매카니즘이 제시되었다.

FT-IR과 FT-Raman 분광계를 이용한 광민감유리의 결정화 과정에 관한 연구 (A study on the crystallization processing of photosensitive glass by FT-IR and FT-Raman spectroscopy)

  • 이명원;강원호
    • E2M - 전기 전자와 첨단 소재
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    • 제10권3호
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    • pp.284-288
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    • 1997
  • FT-IR and FT-Raman spectra were measured for 15Li$_{2}$O.3Al$_{2}$O$_{3}$.78SiO$_{2}$. 4K$_{2}$O glass system after UV irradiations. Optimum UV irradiation time of Li$_{2}$O.SiO$_{2}$ crystalline phase was 60 seconds and crystalline phase of Li$_{2}$O.SiO$_{2}$ was leached out on 5% HF. 977 cm$^{1}$ band of FT-Raman spectra can be attributed to two-non bridging oxygen in unit cell for 1 hour and optimum crystallization was confirmed for 3 hrs, 630.deg. C.

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FT-IR을 이용한 연소가스 정량화에서 농도별 수분스펙트라 확보 및 적용연구 (Study on the application of different water vapor spectra to quantify smoke gases with FT-IR)

  • 이철규;이덕희;박지영;정우성;정종학
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2008년도 춘계학술대회 논문집
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    • pp.2213-2217
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    • 2008
  • The important factor is keeping the temperature condition in quantifying several toxic components in combustion gases. In case of not keeping the temperature as it was in combustion, the change of component and concentration of smoke gases was inevitable. To solve this problem, FT-IR spectroscopy with gas cell was applied. But, there is also a difficulty in quantitative analysis of specific toxic component because of water vapor. Thus, in this study, water vapor FT-IR spectra with different concentrations were obtained and applied them to quantitative analysis.

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Actionspectra for Circadian Melatonin Rhythms in the Avian Pineal In Vitro

  • Kondo, Chieko;Haldar, Chandana;Tamotsu, Satoshi;Oishi, Tadashi
    • Journal of Photoscience
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    • 제9권2호
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    • pp.249-251
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    • 2002
  • The avian pineal as well as the retina has been known to contain several types of photoreceptors with different visual pigments such as rhodopsin, iodopsin and the pineal specific opsin, pinopsin. These organs are also known to have circadian clock to regulate melatonin production. Exposure of animals to light causes a decline of the melatonin level and the phase shifts of melatonin rhythms in the pineal and retina. Therefore, the circadian clock system of these organs seem to consist of three elements, i.e., light input, oscillator and melatonin output systems. In birds, it was suggested that rhodopsin might be involved in the entrainment of pineal melatonin rhythms from the action spectrum experiment for controlling NAT activity rhythms. However, there are much more pinopsin-immunoreactive (Pino-IR) cells than rhodopsin (Rho-IR) and iodopsin (Iodo-IR) cells in the avian pineal. We found that Pino-IR cells appeared earlier embryonic stages than Rho-IR and Iodo-IR cells. So, we tried to identify the visual pigments involved in the circadian melatonin rhythms in the pineal and retina. Organ cultured pineals were exposed to monochromatic light to find out which opsin participates in regulation of melatonin rhythms. The action spectra showed a peak at 475nm, suggesting that pinopsin is the major photopigment to regulate melatonin production in birds.

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PbO-Bi2O3-B2O3-SiO2 유리계 열시차분석과 FT-IR 흡수 스펙트럼 (DATA and FT-IR absorption spectra of PbO-Bi2O3-B2O3-SiO2 glasses)

  • 이찬구;이수대
    • 한국안광학회지
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    • 제8권1호
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    • pp.17-22
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    • 2003
  • $PbO-Bi_2O_3-B_2O_3-SiO_2$ 유리계의 DTA 곡선과 FT-IR 스펙트럼을 조사하였다. 유리전이 온도의 조성비 의존성은 60 mol% $Bi_2O_3$에서 유리계의 구조가 변화하는 것으로 나타났다. 높은 비스무스 함량을 가지는 시료의 FT-IR 스펙트럼 조사에서 무거운 양이온 $Bi^{3+}$의 단위구조와 관계되는 결합이 우세했으며 그리고 고함량의 $Bi_2O_3$ 시료에서도 역시 붕소원자의 3배위와 4배위 진동이 있었다. PbO함량이 높은 유리계의 경우, 비가교 산소밴드의 낮은 강도는 PbO의 망목형성제 역할에 기인 한 것으로 생각된다. 유리의 흡수대는 결정화상태에서 강도가 매우 큰 변화를 보였다.

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Streptomyces sp. 가 생산하는 항진균성 항생물질에 관한 연구(제 2 보) 항진균성 항생물질 trans-Cinnamamide의 생성 (Studies on the Antifungal Antibiotics Produced by a Streptomyces sp. (Part 2) The Occurrence of trans-Cinnamamide in Streptomyces No. 297)

  • 배무;고영희;이화석;조진호
    • 한국미생물·생명공학회지
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    • 제10권1호
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    • pp.39-43
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    • 1982
  • 항진균성 항생물질 생산균으로 분리된 Streptomyces균 No. 297 균의 배양액으로부터 항균물질을 분리·정제하여 침상결정을 얻었다. 이 물질은 UV. IR. spectra, NMR, Mass-spectra 및 여러 화학반응시험을 통하여 t-cin-namamide로 동정되었다. 항균 spectra를 조사해본 결과 Pellicularia sasakii, Pyricularia oryzae 기타 및 병원성 진균류에 강한 항균성을 나타내며 세균류에는 항균력이 극히 약한 것이 특징이다.

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Fabrication of Microgratings and their IR Diffraction Spectra

  • Kim, In Cheol;Choi, Eunwoo;Kim, Seong Kyu;Kang, Young Il;Kim, Taeseong;Bae, Hyo-Wook;Park, Do-Hyun
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.908-912
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    • 2014
  • Microgratings whose diffracted field at a fixed angle generate IR spectra of $SF_6$ or $NH_3$ were fabricated by MEMS techniques for the purpose of IR correlation spectroscopy. Each micrograting was composed of 1441 reflecting lines in the area of $19.2{\times}19.2mm^2$. The depth profile of the line elements was determined with a gradient searching method that was described in our previous publication (J. Mod. Opt. 2013, 60, 324-330), and was discretized into 16 levels between 0 and $6.90{\mu}m$. The diffraction field from a given depth profile was calculated with Fraunhofer equation. The fabricated microgratings showed errors in the depth and the width within acceptable ranges. As the result, the diffracted IR spectrum of each micrograting matched well with its target reference spectrum within spectral resolution of our optical setup.

Near-IR Radiative Transfer Process for the Hazy Atmosphere of Titan

  • Kim, Sang-Joon
    • 천문학회보
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    • 제40권2호
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    • pp.44.2-44.2
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    • 2015
  • Radiative transfer programs have been developed to simulate near-IR spectra of Titan. The formalism of the radiative transfer calculations includes the absorption and emission lines of $CH_4$, $C_2H_2$, $C_2H_6$, and HCN, and continua produced by Titanian haze particles. Absorption and scattering of sunlight by haze particles are considered by employing a two-stream approximation and a spherical-shell model for the atmospheric layers of Titan. Various constraints on the radiative transfer calculations for generating synthetic spectra will be discussed and presented. Several examples of comparisons between the synthetic spectra and recent spectral observations of Titan will also be presented.

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