• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2023-2028
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• 2013

A kinetic study is reported for the nucleophilic substitution reactions of phenyl Y-substituted-phenyl carbonates (5a-5k) with piperidine in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The plots of $k_{obsd}$ vs. [piperidine] for the reactions of substrates possessing a strong electron-withdrawing group (EWG) in the leaving group (i.e., 5a-5i) are linear and pass through the origin. In contrast, the plots for the reactions of substrates bearing a weak EWG or no substituent (i.e., 5j or 5k) curve upward, indicating that the electronic nature of the substituent Y in the leaving group governs the reaction mechanism. Thus, it has been suggested that the reactions of 5a-5i proceed through a stepwise mechanism with a zwitterionic tetrahedral intermediate (i.e., $T^{\pm}$) while those of 5j and 5k proceed through a stepwise mechanism with two intermediates (i.e., $T^{\pm}$ and its deprotonated form $T^-$). The slope of the Br${\o}$nsted-type plot for the second-order rate constants (i.e., $k_N$ or $Kk_2$) changes from -0.41 to -1.89 as the leaving-group basicity increases, indicating that a change in the rate-determining step (RDS) occurs. The reactions of 5a-5k with piperidine result in larger $k_1$ values than the corresponding reactions with ethylamine.

• Journal of Communications and Networks
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• 제17권1호
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• pp.58-66
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• 2015

Aeronautical communication networks (ACN) is an emerging concept in which aeronautical stations (AS) are considered as a part of multi-tier network for the future wireless communication system. An AS could be a commercial plane, helicopter, or any other low orbit station, i.e., Unmanned air vehicle, high altitude platform. The goal of ACN is to provide high throughput and cost effective communication network for aeronautical applications (i.e., Air traffic control (ATC), air traffic management (ATM) communications, and commercial in-flight Internet activities), and terrestrial networks by using aeronautical platforms as a backbone. In this paper, we investigate the issues about connectivity, throughput, and delay in ACN. First, topology of ACN is presented as a simple mobile ad hoc network and connectivity analysis is provided. Then, by using information obtained from connectivity analysis, we investigate two communication models, i.e., single-hop and two-hop, in which each source AS is communicating with its destination AS with or without the help of intermediate relay AS, respectively. In our throughput analysis, we use the method of finding the maximum number of concurrent successful transmissions to derive ACN throughput upper bounds for the two communication models. We conclude that the two-hop model achieves greater throughput scaling than the single-hop model for ACN and multi-hop models cannot achieve better throughput scaling than two-hop model. Furthermore, since delay issue is more salient in two-hop communication, we characterize the delay performance and derive the closed-form average end-to-end delay for the two-hop model. Finally, computer simulations are performed and it is shown that ACN is robust in terms of throughput and delay performances.

• Bulletin of the Korean Chemical Society
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• 제26권12호
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• pp.1981-1985
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• 2005

Kinetic studies have been performed for alkaline hydrolysis of a series of [(methoxy)(p-substituted styryl)carbene]pentacarbonyl chromium(0) complexes ($(CO)_5$Cr=$C(OCH_3)CH=CHC_6H_4X$, X = p-$OCH_3$, p-$CH_3$, H, p-Cl, p-$NO_2$). Second-order rate constants $(k_{{OH}^-})$ for the alkaline hydrolysis in 50% acetonitrile-water(v/v) were determined spectrophotometrically at various temperatures. At a low pH region (pH < 7.5), the observed rate constant $(k_{obs})$ remained constant with a small value, while in a high pH region (pH > 9.5), $k_{obs}$ increases linearly with increasing the pH of the medium. The second-order rate constants $(k_{{OH}^-})$ increase as the substituent X changes from a strong electron donating group to a strong electron withdrawing group. The Hammett plot obtained for the alkaline hydrolysis is consisted of two intersecting straight lines. The nonlinear Hammett plot might be interpreted as a change in the rate-determining step. However, the fact that the corresponding Yukawa-Tsuno plot is linear with $\rho$ and r values of 0.71 and 1.14, respectively indicates that the nonlinear Hammett plot is not due to a change in the rate-determing step but is due to ground-state stabilization through resonance interaction. The positive $\rho$ value suggests that nucleophilic attack by $OH^-$ to form a tetrahedral addition intermediate is the rate-determining step. The large negative ${\Delta}S^\neq$ value determined in the present system is consistent with the proposed mechanism.

• 한국콘텐츠학회논문지
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• 제9권12호
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• pp.410-417
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• 2009

우리나라는 선진대열 진입 무렵부터 '스포츠'의 긍정적 효과에 대한 유용성을 경험해 왔다. 이를테면 올림픽 등 국제대회 개최는 국가 내외적 발전을 추동하였다. 국가홍보에 기여한 바도 매우 크다. 우리나라의 인지도를 향상시킨 매개체로서 스포츠 이상의 경쟁력 있는 콘텐츠는 드물다. 실제로 스포츠는 국가발전을 리드하는 중요한 역할을 수행해왔다. 그 결과 우리나라에서는 스포츠에 대한 투자확대와 수요증대라는 선순환 구조가 체계화될 수 있었다. 그간 스포츠의 육성과 진흥에 대한 노력은 산업적 부가가치의 창출로 이어지는 경향을 갖추게 되었다고 할 수 있다. 이러한 스포츠 생산성에는 다른 분야들과 구별되는 장점이 있다. 비교적 균형 있게 성과를 국가 전반으로 환원시킨다는 점이다. 이상의 관점에서 본고는 우리나라 스포츠 시설의 안전성 증진을 위한 법제도적 측면의 발전방안을 제언하고자 하였다. 국가는 스포츠 시설을 체계적이고 적극적으로 관리할 책임과 의무가 있다. 여기에는 국가 및 공공의 스포츠 시설만이 아니라 민간 스포츠 시설도 포함된다고 할 수 있다. 스포츠 발전과 국가 발전의 공진화적인 관계는 앞으로 더욱 넓게 확대될 것이므로 그에 대한 철저한 준비가 필요하다.

• 한국주거학회논문집
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• 제13권5호
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• pp.31-42
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• 2002

This comparative study between Korean and German housings aims at understanding different structural systems in the indoor and outdoor spaces, depending upon the user′s perception of the socio-cultural attributes. The analysis starts with four alternative contrary assumptions, that appear in morphological forms of dwelling; 1) linear distribution vs. areal distribution of residential districts, 2) mirror system vs. comb system in the layout of plot plans 3) organization of front vs. back outdoor spaces and 4) opening vs. closing in the indoor spaces. A clear difference is found between Korean and German samples in view of public and private relationships between indoor and outdoor spaces as well as the intermediate space. In the korean housing there always exists a symbolic and psychological territory of a certain sphere. On the other hand, outdoor space passes through various phases only to form a certain hierarchy even in a private space and, thereby, sets a boundary between private and public areas. In the case of Germany, the building itself draws a clear line between private and public outdoor spaces, and therefore the outdoor space has a "front" and "back". Thus, Germany′s private space may face a genuine public space and street, which is rare in the Korean housing. Although the layout of indoor space in the korean housing tends to be open, such an openness may be outstanding in living and dining spaces, kitchen and various accesses to rooms. In the case of Germany, such indoor spaces are usually closed to each other. Thus corridors act to separate these spaces. Such differences are analysed to be due to the different perceptions of interpersonal and socio-cultural attributes as intra-family and inter-neighbor relationships or communications.

• 복식
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• 제52권4호
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• pp.65-73
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• 2002

This research is to reveal an aspect of costume culture interchange in the relationship of the early Chosun Dynasty, by considering the imported goods from Japan, of the trading goods derived by the trade diplomacy between the two countries in the early Korea-Japan relationship in the medieval era. The research results are as follows. A good-neighbor Policy in the early Chosun Dynasty was established by a link of a barbarian ban policy to blockade the frequent intrusion by Japanese barbarians. The exchange was the form of presenting a return present in return for a tribute to the Chosun Dynasty from the Japanese envoy, which has a polycentric characteristic. Pusanpo, Naipo, and Yumpo were designated as the open ports, which played a pivotal role in the Korea-Japan exchange. In trading goods between Korean and Japan. the imported goods from Japan to Korea were a wide variety of items primarily such as dyes, mordant, medicines, steel, spicers, etc. In particular, Somok used as a red mordant, which were intermediate goods to Southeast Asia, was the most heavily-traded items of imported goods from Japan. It had been consumed primarily as a raw material making the costume suit of the royal family and the aristocracy. The increased import of Somok was derived from a thought of preferred red color by our people. As its inflow was increased. the costumes tended to be luxurious In early Chosun Dynasty and resulted in social issues. This active trading from the early Chosun Dynasty caused from the communication of the Japanese envoy. In addition the study of the trading provided an opportunity that can glance at an aspect of the costume culture, though It was fractionary.

• 한국광물학회지
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• 제16권1호
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• pp.107-123
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• 2003

본 연구는 0가 철 (ZVI)의 설치위치와 전극의 배열에 따른 다양한 조합의 전기적 투수성 반응벽을 대상으로 트리클로로에틸렌의 탈염소화 반응에 의한 정화시 ZVI의 부식에 기인하는 광물상침전물에 대해 알아보고, 이에 대한 조절 요소를 알아보고자 한다. 광물학적 연구 결과, 지하수 유입부의 ZVI 시료는 상대적으로 많은 레피도크로사이트, 훼리하이드라이트 혹은 철 수산화물과 (phospho)siderite가 산출되는 반면, 용출부의 ZVI 시료는 아카가나이트, 자철석/마그헤마이트, 그리고 중간 산물인 green rust (CR) I 과 CR II가 산출되었다. 이러한 광물 조합의 변화는 용존 산소 및 pH의 상승에 주로 기인한 것으로 나타났다. 또한 전기적 투수성 반응벽 내에 산출되는 광물상 침전물들의 조절 요소들은 (1) pH, (2) 용존산소, (3) 철의 부식시 중간 산물, (4) 음이온 종류 등으로 밝혀졌다.

• Journal of Communications and Networks
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• 제12권5호
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• pp.433-441
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• 2010

Multihop transmission is a promising technique that helps in achieving broader coverage (excellent network connectivity) and preventing the impairment of wireless channels. This paper proposes a cluster-based multihop wireless network that makes use of the advantages of multihop relaying, i.e., path loss gain, and partial relay selection in each hop, i.e., spatial diversity. In this partial relay selection, the node with the maximum instantaneous channel gain will serve as the sender for the next hop. With the proposed protocol, the transmit power and spectral efficiency can be improved over those in the case of direct transmission and conventional multihop transmission. Moreover, at a high signal-to-noise ratio (SNR), the performance of the system with at least two nodes in each cluster is dependent only on the last hop and not on any of the intermediate hops. For a practically feasible decode-and-forward relay strategy, a compact expression for the probability density function of the end-to-end SNR at the destination is derived. This expression is then used to derive closed-form expressions for the outage probability, average symbol error rate, and average bit error rate for M-ary square quadrature amplitude modulation as well as to determine the spectral efficiency of the system. In addition, the probability of SNR gain over direct transmission is investigated for different environments. The mathematical analysis is verified by various simulation results for demonstrating the accuracy of the theoretical approach.

• 한국정보통신학회논문지
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• 제16권6호
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• pp.1312-1317
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• 2012

ZBrush의 ZSphere는 캔버스에 추가가 가능하며, 무엇보다도 움직임이 자유로운 기하학적 오브젝트로서 ZSphere를 기존의 ZSphere에 추가할 수 있다는 점이다. 예를 들어 중간단계의 구형체에서 뽑아내어 팔 같은 것을 생성할 수 있다. 이러한 방식으로 팔다리가 여러 개인 캐릭터를 쉽게 만들어 낼 수 있는 것이다. 본 논문은 ZSphere를 사용하여 하나의 Sphere로부터 여러 개의 Child Sphere를 만들어내고, 이것이 parent sphere가 되어 이를 기준으로 Child Sphere를 연결해 나가는 형식으로 형태를 만들어 가며 3D 캐릭터 형태를 쉽고 빠르게 잡아가도록 모델링 하였다. 3D 오브젝트를 추가하고 회전시키고 움직일 수 있기에 캔퍼스의 Z-depth와 원활한 상호작용이 이루어질 수 있다. 이러한 오브젝트를 스크린에 놓거나 페인팅을 하고 고정된 퍼스펙티브 이미지를 구축하고 Pixols을 스머지하며 3D오브젝트를 변형시키기 위하여 다양한 변형툴과 조각툴을 사용하였다. 완성된 character를 poly로 변환한 다음 Topology를 이용해 빠르게 면을 재구성 하는 방법으로 캐릭터를 설계하였다.

• Korea-Australia Rheology Journal
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• 제14권4호
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• pp.189-201
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• 2002

The interaction between hydrophobically modified hydroxyethyl cellulose (hmHEC), containing approximately 1 wt% side-alkyl chains of $C_{16}$, and an anionic sodium dodecyl sulphate (SDS) surfactant was investigated. For a semi-dilute solution of 0.5 wt% hmHEC, the previously observed behaviour of a maximum in solution viscosity at intermediate SDS concentrations, followed by a drop at higher SDS concentrations, until above the cmc of surfactant when the solution resembles that of the unsubstituted polymer, was confirmed. Additionally, a two-phase region containing a hydrogel phase and a water-like supernatant was found at low SDS concentrations up to 0.2 wt%, a concentration which is akin to the critical association concentration, cac, of SDS in the presence of hmHEC. Above this concentration, SDS molecules bind strongly to form mixed micellar aggregates with the polymer alkyl side-chains, thus strengthening the network junctions, resulting in the observed increase in viscosity and elastic modulus of the solution. The shear behaviour of this polymer-surfactant complex during steady and step stress experiments was examined In great detail. Between SDS concentrations of 0.2 and 0.25 wt%, the shear viscosity of the hmHEC-polymer complex network undergoes shear-induced thickening, followed by a two-stage shear-induced fracture or break-up of the network. The thickening is thought to be due to structural rearrangement, causing the network of flexible polymers to expand, enabling some polymer hydrophobic groups to be converted from intra- to inter-chain associations. At higher applied stress, a partial local break-up of the network occurs, while at even higher stress, above the critical or network yield stress, a complete fracture of the network into small microgel-like units, Is believed to occur. This second network rupture is progressive with time of shear and no steady state in viscosity was observed even after 300 s. The structure which was reformed after the cessation of shear is found to be significantly different from the original state.