• Title/Summary/Keyword: IM240

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Chemical Characteristics of Heavy Metals of PM2.5 in Atmosphere (대기 중 PM2.5의 중금속 성분의 화학적 특성)

  • Jeon, Hye-Li;Choi, Su-Hyeon;Im, Ji-Young;Park, Hee-Jin;Hong, Eun-Ju;Son, Bu-Soon
    • Journal of Environmental Health Sciences
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    • v.38 no.3
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    • pp.233-240
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    • 2012
  • Objectives: The changes in atmospheric $PM_{2.5}$ concentrations were extensively studied in one metropolitan city (Incheon), two small and medium sized cities (Gunsan, Cheonan), and a rural area (Gosan in Jeju). The concentrations of heavy metals (Cr, Mn, Fe, Ni, Cu, Zn, Al, Pb) and the component features of $PM_{2.5}$ were determined for these areas. Methods: This study sampled $PM_{2.5}$ at the designated locations in the metropolitan (Incheon), small and medium sized cities (Gunsan in Jeonbuk and Cheonan in Chungnam), and rural area (Gosan in Jeju) to investigate concentrations with a sampling device (Sequential sampler, APM Eng., Korea). Sampling was undertaken over months, from June 26 to November 26, 2009. Sampling was conducted a total of 44 times, with routine sampling at intervals of six days (24 total times) and intensive sampling (20 total times) during the summer and fall. Mass concentration of $PM_{2.5}$ was evaluated and the concentrations of heavy metals (Cr, Mn, Fe, Ni, Cu, Zn, Al, Pb) were analyzed. Results: The geometric average of concentrations of $PM_{2.5}$ per district was $35.289{\mu}g/m^3$ for Cheonan, $29.955{\mu}g/m^3$ for Incheon, $24.119{\mu}g/m^3$ for Gunsan, and $18.773{\mu}g/m^3$ for Jeju, respectively. The average concentration of $PM_{2.5}$ in Cheonan was the highest. The seasonal concentration distributions per district showed Cheonan $33.387{\mu}g/m^3$, Incheon at $31.550{\mu}g/m^3$, Gunsan $22.900{\mu}g/m^3$, and Jeju $18.900{\mu}g/m^3$ in the summer. For the autumn, the concentrations were $36.873{\mu}g/m^3$ in Cheonan, $28.625{\mu}g/m^3$ in Incheon, $25.227{\mu}g/m^3$ in Gunsan, and $18.667{\mu}g/m^3$ in Jeju. According to the collected data, the concentration showed a tendency to rise during the autumn in all of these regions with the exception of Incheon. For heavy metal distribution per district, Fe showed an elevated concentration during the summer while high concentrations of Pb and Zn occurred during the autumn. Conclusion: These results demonstrated that atmospheric factors affected the concentrations of heavy metals. The results of this study could be used as foundational data for setting environmental air standards focusing on a $PM_{2.5}$ receptor.

Monitoring of Neonicotinoid Pesticide Residues in Fruit Vegetable and Human Exposure Assessment (과채류 중 Neonicotinoid계 농약의 모니터링 및 인체노출평가)

  • Park, Byung-Jun;Son, Kyung-Ae;Paik, Min-Kyoung;Kim, Jin-Bae;Kwon, Hye-Young;Hong, Su-Myeong;Im, Geon-Jae;Hong, Moo-Ki
    • The Korean Journal of Pesticide Science
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    • v.14 no.2
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    • pp.104-109
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    • 2010
  • We investigated five neonicotinoid pesticide residues (acetamiprid, clothianidin, imidacloprid, thiacloprid, thiamethoxam) in fruit vegetables and estimated the exposure of neonicotinoid pesticide residue through fruit vegetable consumption using a deterministic approach. Two hundred forty samples of eight fruit vegetables cultivated in Korea were analyzed for their pesticide residue contents. Acetamiprid had the highest detection frequency and the highest residue level in pepper. However, all pesticide levels detected didn't exceed national MRLs. The results using a deterministic approach showed that for chronic and acute study of all neonicotinoid pesticide residues, the exposure was about 50 times lower than toxicological endpoint values. It is necessary to understand that the exposure assessment in this study using a probabilistic approach should be regarded as a important knowledge in the decision-making process.

Relevance of Health Status and Exercises Patterns in Adults (성인의 운동실천양상과 건강수준간 관련요인분석 - 초등학교 교직원을 중심으로 -)

  • Kim, Young Im
    • Journal of the Korean Society of School Health
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    • v.13 no.2
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    • pp.231-240
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    • 2000
  • The purpose of this study is to analyze the relationship between life style and health status of the staffs of an elementary school to understand exercise practices and life styles and to analyze the self-efficacy and the factors that affect it concerning walking exercise. The subjects were m9 staff member of the 10 elementary school in Seoul and materials were collected through an organized examination table from October, 1999 to May 2000. The people health awareness table was used as a variable for life style, the 13 questionnaires made of a 5 points measure was for the self efficacy concerning walking exercise. The data was analyzed through a statistics package made of a Chisquare-test, t-test, ANOVA and a regression analysis. The major results of this study were as follows; 1) 50% of the staffs were practicing regular exercise, 3/4 of them practiced walking, jogging and mountain climbing that don't need equipment and exercise frequency was 1-2 times per week 64%. of the time and exercise span was under 30 minutes in 38%, the highest 2) The average of self-efficacy concerning walking exercise was 3.6 points but the answers "I can walk enough to be in a sweat", "I can walk according to my exercise plan" were relatively low. 3) The explanation degree of the Model was 14% in a regression analysis between self efficacy concerning walking exercise and as a dependent variable for a regular walking exercise plan, regular health examination, routine health status, and breakfast might serve as an explanation degree. According to the results of this study, the suggestions were as follows: 1) The chronic invalid was not enough in the change of life style after chronic disease, most of all, it need the awareness of change, of active health education and of public information for health promotion action practice through the prohibition of smoking, abstinence from drink, exercise and nutritional balance. 2) Concrete practice program enlargement is needed to enhance related walking exercise or of a type lecture meeting for subjects who have a positive attitude about walking exercise plans. 3) A program that can actively recommend a health promotion life style is needed when we make allowance for those who have an ordinarily healthy life style and show a high walking exercise self-efficacy.

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Awareness and Correlation of Patient Safety Culture and Standard Precautions among Health Care Personnel (의료종사자의 환자안전문화와 표준주의 인식과 상관관계)

  • Kwon, Hye-kyung;Jeong, Jae-sim;Lee, Bok-im;Kim, Jang-han
    • Quality Improvement in Health Care
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    • v.21 no.2
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    • pp.58-72
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    • 2015
  • Objectives: This study was conducted as descriptive correlation research in order to survey healthcare personnel(HCP)'s awareness of patient safety culture and their recognition of standard precautions, and to examine the correlation between the two factors. Methods: The subjects were 400 HCPs including 80 doctors, 240 nurses, and 80 medical technicians from two general hospitals. The questionnaire used in the survey consisted of 9 questions on general characteristics, 44 on the perception of patient safety culture, and 21 on the recognition of standard precautions. Results: According to the subjects' general characteristics, the score was significantly higher in those aged over 40 than in those aged 30-39. In addition, it was significantly higher in managers than in practitioners, in those with work experience of less than a year than in those with 5-9 years. The score was also significantly higher in those working 8 hours a day than in those working over 10 hour a day. The number of medical accident reports according to the subjects' general characteristics was significantly larger in nurses than in doctors, in managers than in practitioners, and in those with 10 years' or longer experiences than in those with less than a year. In the awareness of standard precautions according to the subjects' general characteristics, the score was significantly higher in female workers than in male workers, and in managers than in practitioners. As a whole, the subjects' awareness of patient safety culture and their recognition of standard precautions showed a significant correlation with each other. Conclusion: From the result of this study, sufficient work force and the promotion of organizational culture for safety is needed in order to guarantee patient safety. Likewise, these results suggest that experience, job skill, and adequate working hours have a positive effect on the awareness of patient safety culture and the recognition of standard precautions.

Virulence of Ornithobacterium rhinotracheale Isolates for Embryonated SPF Eggs and Broilers (국내에서 분리한 Ornithobacterium rhinotracheale 균의 종란과 육계에서의 병원성)

  • Kwon, Yong-Kuk;Jeon, Woo-Jin;Kang, Min-Soo;Oh, Jae-Young;An, Byung-Ki;Song, Eun-A;Kwon, Jun-Hun;Lee, Cheong-San;Kim, Jae-Hong
    • Korean Journal of Poultry Science
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    • v.37 no.2
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    • pp.159-165
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    • 2010
  • Field strains of Ornithobacterium rhinotracheale (OR) were tested on their virulence in specific pathogen free (SPF) embryonated chicken eggs and 3-week-old broilers. When infected with three different OR isolates (OR-161, OR-240 and OR-295) through yolk sac infection route, all strains appeared to be highly pathogenic with responsible mortality 66% and 100% within 12 days post infection (DPI). To test the virulence of OR in the commercial broilers, 3 week-old broilers were grouped depends on the inoculation route of OR isolate (OR-295) through five different infection routes; group 1 (IT: intratracheal), group 2 (IM: intramuscular), group 3 (IV: intravenous), group 4 (aerosol) and group 5 [Mixed: NDV (LaSota)+OR aerosol]. Within 5 to 7 days after inoculation, only broilers given NDV+OR were slightly depressed and coughing, and had mild facial redness. Grossly, foamy and yellow-white yogurt like exudate in the air sacs, predominantly in the abdominal air sacs was present. In histology, infiltration of the air sac epithelium and lamina propria by macrophage and polymorphonuclear granulocytes was seen with cell debris and inflammatory cells, correlated with the presence of OR antigen, as demonstrated by immunohistochemistry. Field strains of OR were able to induce high mortality in the embryonated chicken eggs, whereas broilers were less susceptible to OR infection. Interestingly, in the absence of NDV infection, the four groups of OR single infection only different route showed minimal and temporary microscopic air sac lesions. Thus, Newcastle disease virus (LaSota strain) showed triggering effects on the OR infection in chickens.

A Basic Study on the Hematology and Serum Chemistry in Rat Treated with Glycerol (Glyceorl 투여에 따른 Rat의 혈액학 및 혈액생화학치에 관한 기초연구)

  • Yun, Wang-Su;Soh, Kyung-Sun;Choi, Jin-Yong;Kang, Im-Sung;Jeong, Chan-Gil
    • Journal of Society of Preventive Korean Medicine
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    • v.10 no.1
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    • pp.141-153
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    • 2006
  • In order to study the changes in hematology and serum chemistry of rats injected with glycerol, Sprague-Dawley albino rats weighing 240 to 260 gm were injected intramuscularly with a 50% solution of glycerol(8ml/kg). We measured the values of hematology and serum chemistry, and compared the measured values of S1 group(passed for 1day after injection of glycerol), S2 group(passed for 2days after injection of glycerol), S3 group(passed for 3days after injection of glycerol), S4 group(passed for 3days after injection of glycerol) and S5 group(passed for 4days after injection of glycerol) with those of Normal group(non-treated group). The results are summarized as follows : 1. In body temperature, S1, S2, S4 groups showed significantly higher compared with Normal group, especially S2 group was higher than S1 group(p<0.05). But S5 group was lower than Normal group(p<0.05). 2. In RBC, S1 group was lower than Normal group(p<0.05). And in Hct, S1, S2, S3 groups were lower than Normal group(p<0.05), in Hb, S1 and S3 groups were lower than Normal group(p<0.05). 3. In WBC, S1, S2 groups were higher than Normal group(p<0.05). and in WBC differential count, S2, S3, S5 groups were higher than N, S1, S4 groups in monocyte(p<0.05). 4. In GOT, S1 group was higher than Normal group(p<0.05), and S2, S3, S4, S5 groups were lower than S1 group(p<0.05). In GPT, S1 group was higher than Normal group(p<0.05), and S2, S3 groups were lower than S1 group(p<0.05), S4, S5 groups were lower than N, S1, S2, S3 groups(p<0.05). 5. In total cholesterol and creatinine, S4 group was higher than Normal group(p<0.05). According to the above experimental results, we could find the anemia, inflamation, damage of renal function for 4 days by intramuscularly injection with a 50% solution of glycerol(8ml/kg) in rat.

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Sensitivity Analysis of the MUSIC Model Parameters (MUSIC모형의 매개변수에 관한 민감도 분석)

  • Im, Jang-Hyuk;Yeoun, Ji-Woong;Park, Sung-Sik;Song, Jai-Woo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.236-240
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    • 2007
  • 최근 집중호우에 의한 피해가 증가함에 따라 도시화에 따른 불투수 면적이 유출량 증가의 주요한 원인으로 지목되고 있으며 도시의 인구집중으로 인한 지하수의 난개발로 지하수 오염 및 고갈이 빠르게 진행되고 있다. 이에 도시의 지속적이고 건전한 물 관리를 위하여 우수유출저감시설이 고려되고 있으며, 정량적인 저감효과의 분석방법이 요구되고 있다. 따라서, 본 연구에서는 호주에서 물관리 및 우수유출저감을 고려한 도시유역계획을 위해 이용되고 있는 모형에 대한 민감도 분석을 실시하였으며, 이러한 결과를 바탕으로 MUSIC 향후 국내 우수유출저감시설에 관한 수문 해석시 MUSIC의 적용이 가능할 것으로 판단된다. MUSIC의 매개변수 중 불투수율과 토양특성이 매우 중요한 매개변수로 고려되고 있으므로, 본 연구에서는 투수지역의 최대저류깊이, Soil storage(mm), 강우초기 최대저류깊이의 포화정도 Initial storage(%), 지하수위에 도달할 수 있는 Field capacity(mm), 최대 침투율에 영향을 미치는 건조토양상태의 침투율을 정의하는 계수 a와 함수비 증가에 따른 최대 침투율 감소를 정의하는 지수 b 등의 매개변수에 대해 초기값을 중심으로 일정비율로 각 매개변수를 10단계로 구분하여 민감도 분석을 실시하였다. 주요 매개변수의 민감도 분석 결과로부터 MUSIC의 모의를 위해서는 불투수율의 민감도 변화 범위가 가장 넓고 첨두유출량과 총유출량 변화가 함께 일어나므로, 이를 가장 우선적으로 조정하고 이와 함께 토양특성을 반영하는 Soil storage와 Initial storage를 고려한다면 MUSIC을 이용하여 개발에 의한 유출변화와 다양한 우수침투시설 설치에 따른 저감효과를 합리적으로 예측할 수 있을 것으로 판단된다. 물 관리를 요구하게 되었다. 우리나라는 현실적으로 매년 홍수 피해가 발생하고 있지만, 다른 한편 인구밀도가 높고 1인당 가용 수자원이 상대적으로 적기 때문에 국지적 물 부족 문제를 경험하고 있다. 최근 국제적으로도 농업용수의 물 낭비 최소화와 절약 노력 및 타 분야 물 수요 증대에 대한 대응 능력 제고가 매우 중요한 과제로 부각되고 있다. 2006년 3월 멕시코에서 개최된 제4차 세계 물 포럼에서 국제 강 네트워크는 "세계 물 위기의 주범은 농경지", "농민들은 모든 물 위기 논의에서 핵심"이라고 주장하고, 전 프랑스 총리 미셀 로카르는 "...관개시설에 큰 문제점이 있고 덜 조방적 농업을 하도록 농민들을 설득해야 한다. 이는 전체 농경법을 바꾸는 문제..."(segye.com, 2006. 3. 19)라고 주장하는 등 세계 물 문제 해결을 위해서는 농업용수의 효율적 이용 관리가 중요함을 강조하였다. 본 연구는 이러한 국내외 여건 및 정책 환경 변화에 적극적으로 대처하고 물 분쟁에 따른 갈등해소 전략 수립과 효율적인 물 배분 및 이용을 위한 기초연구로서 농업용수 수리권과 관련된 법 및 제도를 분석하였다.. 삼요소의 시용 시험결과 그 적량은 10a당 질소 10kg, 인산 5kg, 및 가리 6kg 정도였으며 질소는 8kg 이상의 경우에는 분시할수록 비효가 높았으며 특히 벼의 후기 중점시비에 의하여 1수영화수와 결실율의 증대가 크게 이루어졌다. 3. 파종기와 파종량에 관한 시험결과는 공시품종선단의 파종적기는 4월 25일부터 5월 10일경까지 인데 이 기간중 일찍 파종하는 경우에 파종적량은 10a당 약 8${\ell}$이고 늦은 경우에는 12${\ell}$ 정도였다. 여기서 늦게 파종한 경우 감수의 가장

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Quantum Confinement Effect Induced by Thermal Treatment of CdSe Adsorbed on $TiO_2$ Nanostructure

  • Lee, Jin-Wook;Im, Jeong-Hyeok;Park, Nam-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.213-213
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    • 2012
  • It has been known that quantum confinement effect of CdSe nanocrystal was observed by increasing the number of deposition cycle using successive ionic layer adsorption and reaction (SILAR) method. Here, we report on thermally-induced quantum confinement effect of CdSe at the given cycle number using spin-coating technology. A cation precursor solution containing $0.3\;M\;Cd(NO_3)_2{\cdot}4H_2O$ is spun onto a $TiO_2$ nanoparticulate film, which is followed by spinning an anion precursor solution containing $0.3\;M\;Na_2\;SeSO_3$ to complete one cycle. The cycle is repeated up to 10 cycles, where the spin-coated $TiO_2$ film at each cycle is heated at temperature ranging from $100^{\circ}C$ to $250^{\circ}C$. The CdSe-sensitized $TiO_2$ nanostructured film is contacted with polysulfide redox electrolyte to construct photoelectrochemical solar cell. Photovoltaic performance is significantly dependent on the heat-treatment temperature. Incident photon-to-current conversion efficiency (IPCE) increases with increasing temperature, where the onset of the absorption increases from 600 nm for the $100^{\circ}C$- to 700 nm for the $150^{\circ}C$- and to 800 nm for the $200^{\circ}C$- and the $250^{\circ}C$-heat treatment. This is an indicative of quantum size effect. According to Tauc plot, the band gap energy decreases from 2.09 eV to 1.93 eV and to 1.76 eV as the temperature increases from $100^{\circ}C$ to $150^{\circ}C$ and to $200^{\circ}C$ (also $250^{\circ}C$), respectively. In addition, the size of CdSe increases gradually from 4.4 nm to 12.8 nm as the temperature increases from $100^{\circ}C$ to $250^{\circ}C$. From the differential thermogravimetric analysis, the increased size in CdSe by increasing the temperature at the same deposition condition is found to be attributed to the increase in energy for crystallization with $dH=240cal/^{\circ}C$. Due to the thermally induced quantum confinement effect, the conversion efficiency is substantially improved from 0.48% to 1.8% with increasing the heat-treatment temperature from $100^{\circ}C$ to $200^{\circ}C$.

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A Study on The Preparation of Poly(alkyl methacrylate-co-maleic anhydride) as Cold Flow Improvers for Biodiesel Fuels (바이오디젤용 저온 유동성 향상제로서의 폴리 (알킬메타크릴레이트-공-무수말레인산) 제조 연구)

  • Hong, Jin-Sook;Chung, Keun-Wo;Kim, Young-Wun;Kim, Nam-Kyun;Im, Dae-Jae
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.232-240
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    • 2012
  • Bio-diesel (BD) is the mono alkyl esters of long chain fatty acids derived from renewable feed stocks like vegetable oils or animal fats. Bio-diesel shows poorer fuel properties than that of diesel fuel in a cold condition. For the diesel fuel, many cold flow improvers have been developed; however, since primary ingredients of bio-diesel are different from those of the diesel fuel, there is a limit to the cold flow improvement when the same cold flow improvers are added to bio diesel. In this study, to improve low temperature properties of bio-diesel, we developed a cold flow improver using an alkyl methacrylate monomer, prepared via ester reaction, and maleic anhydride and also conducted a ring opening reaction using amine. We characterized the products using $^1H-NMR$, FT-IR and GPC methods. In addition, the cold flow improvements of the products in Soybean BD and Palm BD in the concentration rage of 1000~10000 ppm were investigated. It was found that the addition of LMA2SMA6MA2-C8A in Soybean BD improved the pour point by $12.5\;^{\circ}C$.

Preparation and Characterization of Nanofiltration Membrane for Recycling Alcoholic Organic Solvent (알코올성 유기용매 재활용을 위한 나노여과막의 제조와 특성평가)

  • Kim, Seong Heon;Im, Kwang Seop;Kim, Ji Hyeon;Koh, Hyung Chul;Nam, Sang Yong
    • Membrane Journal
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    • v.31 no.3
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    • pp.228-240
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    • 2021
  • The organic solvent robust polybenzimidazole (PBI) membranes were prepared as organic solvent nanofiltration (OSN) membrane for the recycling of alcoholic solvents using non-solvent induced phase separation with different dope solution concentration and coagulant composition of water/ethanol mixtures to control the membrane morphology and permeation performance. Investigation on crosslinking of polybenzimidazole indicated that the membrane crosslinked with dibromoxylene (DBX) had enough mechanical strength and solvent resistance to be applied as a OSN membranes. The crosslinked PBI membrane prepared by more than 20wt% dope concentration coagulated in water showed a rejection of > 90% to Congo Red (MW of 696.66 g/mol) while pure ethanol permeances was more than 22.5 LMH/bar at 5 bar. Investigation on coagulant composition indicated that ethanol permeance through crosslinked PBI OSN membrane increased with increasing of ethanol concentration in water/ethanol mixture coagulants.